MS45 1001 Markus Jesswein, Tanja Schuck, Andreas Engel Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Altenhoeferallee 1, 60438 Frankfurt/Main, Germany 1|HALO | GhOST-MS | mixing ratios of long-lived and very short-lived tracers measured with an in-situ GC-ECD instrument, integrated under usage of constant baseline PHILEAS 1 1 2023 09 22 2025 11 06 0 Mean sample time in UT seconds past midnight of flight date 4 1 1 1 1 99999 99999 99999 99999 Time_Start [s] Time_End [s] SF6 [ppt] CFC_12 [ppt] 25 ------------------------------------------------------------------------ Please inform the authors about the use of the data These are preliminary data and not for publication. Please adhere in all cases to the PHILEAS data protocol Contact: Andreas Engel (an.engel@iau.uni-frankfurt.de, phone +49 69 798 40259) ------------------------------------------------------------------------ Calibration Scale, Precision, Accuracy and Detection Limit are given separately for each dependent variable Primary calibration reference flasks: TO-Mutter (UEA scales), J-256 (AGAGE network) Calibration Scales SF6 CFC_12 SIO-05 SIO-05 ------------------------------------------------------------------------ Instrument precision in [%] NaN NaN NaN NaN NaN NAN NAN 0.8013 0.2804 Detection limit (S/N 3/1) in [ppt] per 100 mL air at STP NaN NaN NaN NaN NaN Values below detection limit are marked as 0.00 In case no measurements are available, the missing data value is used ------------------------------------------------------------------------ SF6 data non-linearity below measurement precision. no correction applied F12 mixing ratio data has been corrected for detector non-linearity by applying a second order polynom: k = a0 + a1 * mr_F12 + a2 * mr_F12^2 coefficients: a0 = -0.04257; a1 = 1.04244; a2 = 0.00013 ------------------------------------------------------------------------ 2 UTC Time_Start Time_End SF6 CFC_12 [s] [s] [s] [ppt] [ppt] 78808 78808 78808 11.64 485.12 78869 78869 78869 11.63 486.55 78931 78931 78931 11.54 485.44 78992 78992 78992 11.58 485.79 79054 79054 79054 11.66 487.01 79115 79115 79115 11.54 484.64 79177 79177 79177 11.64 486.52 79238 79238 79238 11.68 486.83 79300 79300 79300 11.7 487.39 79423 79423 79423 11.57 487.14 79484 79484 79484 11.68 489.46 79546 79546 79546 11.86 491.84 79607 79607 79607 11.79 491.79 79669 79669 79669 11.76 491.63 79730 79730 79730 11.76 491.16 79792 79792 79792 11.64 489.47 79853 79853 79853 11.56 489.91 79915 79915 79915 11.59 492.48 80038 80038 80038 11.63 489.5 80099 80099 80099 11.58 487.53 80161 80161 80161 11.43 485.79 80222 80222 80222 11.41 485.37 80284 80284 80284 11.29 483.01 80345 80345 80345 11.25 480.1 80407 80407 80407 11.3 476.78 80468 80468 80468 11.21 477.8 80530 80530 80530 11.29 477.72 80653 80653 80653 11.38 481.91 80714 80714 80714 11.33 480.84 80776 80776 80776 11.25 478.78 80837 80837 80837 11.27 476.07 80899 80899 80899 11.22 477.28 80960 80960 80960 11.32 476.37 81022 81022 81022 11.34 477.56 81083 81083 81083 11.24 475.85 81145 81145 81145 11.16 476.61 81268 81268 81268 11.24 475.66 81329 81329 81329 11.32 475.74 81391 81391 81391 11.18 475.61 81452 81452 81452 11.16 476.85 81514 81514 81514 11.24 475.56 81575 81575 81575 11.29 477.77 81637 81637 81637 11.24 476.92 81698 81698 81698 11.32 476.33 81760 81760 81760 11.27 476.02 81883 81883 81883 11.13 474.23 81944 81944 81944 11.3 476.5 82006 82006 82006 11.25 476.46 82067 82067 82067 11.34 479.07 82129 82129 82129 11.15 476.28 82190 82190 82190 11.02 473.52 82252 82252 82252 10.92 474.69 82313 82313 82313 11.1 471.6 82375 82375 82375 10.94 472.54 82498 82498 82498 10.91 472.97 82559 82559 82559 10.97 473.05 82621 82621 82621 10.99 469.44 82682 82682 82682 10.96 470.73 82744 82744 82744 10.98 469.46 82805 82805 82805 11.1 469.43 82867 82867 82867 11.2 465.41 82928 82928 82928 11.01 462.42 82990 82990 82990 11.04 463.7 83113 83113 83113 11.15 464.19 83174 83174 83174 11.2 467.02 83236 83236 83236 11.19 467.4 83297 83297 83297 11.06 467.35 83359 83359 83359 11.35 467.77 83420 83420 83420 11.2 468.2 83482 83482 83482 11.11 466.25 83543 83543 83543 11.04 465.72 83605 83605 83605 11.03 463.03 83728 83728 83728 11.04 463.53 83789 83789 83789 11.09 468.82 83851 83851 83851 11.19 471.63 83912 83912 83912 11.44 476.05 83974 83974 83974 11.09 466.74 84035 84035 84035 11.35 468.86 84097 84097 84097 11.51 475.66 84158 84158 84158 11.33 478.52 84220 84220 84220 11.45 479.94 84343 84343 84343 11.46 484.69 84404 84404 84404 11.39 483.56 84466 84466 84466 11.32 484.25 84527 84527 84527 11.24 485.36 84589 84589 84589 11.36 482.63 84650 84650 84650 11.28 480.92 84712 84712 84712 11.14 478.11 84773 84773 84773 10.94 463.98 84835 84835 84835 11.03 471.52 84958 84958 84958 11.1 471.78 85020 85020 85020 11.16 483.66 85081 85081 85081 11.17 475.38 85143 85143 85143 11.16 473.26 85204 85204 85204 11.08 476.43 85266 85266 85266 11.04 475.73 85327 85327 85327 11.29 473.43 85389 85389 85389 11.05 469.47 85450 85450 85450 10.98 469.54 85574 85574 85574 11.07 465.38 85635 85635 85635 11.18 469.65 85697 85697 85697 11.25 471.36 85758 85758 85758 10.98 471.74 85820 85820 85820 11.05 468.89 85881 85881 85881 11.03 469.65 85943 85943 85943 11.08 469.34 86004 86004 86004 11.14 469.6 86066 86066 86066 11.03 470.96 86189 86189 86189 11.07 469.68 86250 86250 86250 11.1 468.25 86312 86312 86312 11.23 471.46 86373 86373 86373 11.11 472.3 86435 86435 86435 11.21 472.05 86496 86496 86496 11.16 473.01 86558 86558 86558 11.04 472.38 86619 86619 86619 11.12 471.86 86681 86681 86681 11.25 473.13 86804 86804 86804 11.29 476.79 86865 86865 86865 11.27 476.98 86927 86927 86927 11.09 477.79 86988 86988 86988 11.18 475.33 87050 87050 87050 11.28 478.35 87111 87111 87111 11.11 477.33 87173 87173 87173 11.24 475.8 87234 87234 87234 11.14 473.35 87296 87296 87296 11.13 471.46 87419 87419 87419 11.31 475.55 87480 87480 87480 11.23 476.1 87542 87542 87542 11.28 477.84 87603 87603 87603 11.51 479.06 87665 87665 87665 11.57 481.67 87726 87726 87726 11.48 482.79 87788 87788 87788 11.44 484.87 87849 87849 87849 11.44 483.94 87911 87911 87911 11.4 480.9 88034 88034 88034 11.37 482.83 88095 88095 88095 11.4 481.07 88157 88157 88157 11.45 477.98 88218 88218 88218 11.28 477.88 88280 88280 88280 11.25 475.63 88341 88341 88341 11.23 475.86 88403 88403 88403 11.22 477.76 88464 88464 88464 11.17 476.02 88526 88526 88526 11.13 472.56 88649 88649 88649 11.1 473.52 88710 88710 88710 11.15 470.54 88772 88772 88772 11.21 472.95 88833 88833 88833 11.23 480.71 88895 88895 88895 11.11 481.69 88956 88956 88956 11.25 477.53 89018 89018 89018 11.09 477.5 89079 89079 89079 11.31 476.61 89141 89141 89141 11.1 473.0 89264 89264 89264 11.05 473.61 89325 89325 89325 11.27 474.99 89387 89387 89387 11.01 470.87 89448 89448 89448 11.07 469.68 89510 89510 89510 11.14 476.61 89571 89571 89571 11.38 480.3 89633 89633 89633 11.4 476.54 89694 89694 89694 11.15 474.89 89756 89756 89756 11.35 476.52 89879 89879 89879 11.35 478.26 89940 89940 89940 11.35 478.11 90002 90002 90002 11.3 475.37 90064 90064 90064 11.33 476.98 90125 90125 90125 11.25 474.39 90187 90187 90187 11.2 476.21 90248 90248 90248 11.44 476.48 90310 90310 90310 11.14 476.64 90371 90371 90371 11.12 476.65 90494 90494 90494 11.07 474.89 90556 90556 90556 11.06 474.89 90617 90617 90617 11.22 476.39 90679 90679 90679 11.33 474.95 90740 90740 90740 11.06 476.39 90802 90802 90802 11.22 477.62 90863 90863 90863 11.25 477.0 90925 90925 90925 11.31 476.11 90986 90986 90986 11.3 476.52 91109 91109 91109 11.23 476.47 91171 91171 91171 11.27 476.56 91232 91232 91232 11.35 475.97 91294 91294 91294 11.45 475.83 91355 91355 91355 11.19 475.4 91417 91417 91417 11.19 476.92 91478 91478 91478 11.27 477.48 91540 91540 91540 11.26 478.37 91601 91601 91601 11.4 478.23 91724 91724 91724 11.09 467.4 91786 91786 91786 11.29 473.88 91847 91847 91847 11.24 466.87 91909 91909 91909 11.19 467.78 91970 91970 91970 11.34 471.06 92032 92032 92032 11.15 469.65 92093 92093 92093 11.18 467.13 92155 92155 92155 11.06 462.97 92216 92216 92216 11.06 464.12 92339 92339 92339 11.13 468.93 92401 92401 92401 11.2 469.31 92462 92462 92462 11.32 469.88 92524 92524 92524 11.24 472.56 92585 92585 92585 11.26 474.3 92647 92647 92647 11.4 472.82 92708 92708 92708 11.26 472.26 92770 92770 92770 11.03 467.01 92831 92831 92831 11.04 465.29 92954 92954 92954 11.1 464.0 93016 93016 93016 11.11 463.18 93077 93077 93077 11.0 461.36 93139 93139 93139 11.06 460.38 93200 93200 93200 10.99 460.4 93262 93262 93262 11.05 460.39 93323 93323 93323 11.02 460.12 93385 93385 93385 11.1 466.56 93446 93446 93446 11.02 466.52 93569 93569 93569 10.93 459.99 93631 93631 93631 11.11 458.52 93692 93692 93692 10.99 459.06 93754 93754 93754 11.18 459.61 93815 93815 93815 11.13 461.44 93877 93877 93877 11.04 462.56 93938 93938 93938 10.85 461.91 94000 94000 94000 10.98 462.52 94061 94061 94061 10.99 463.46 94184 94184 94184 11.04 467.51 94246 94246 94246 10.96 468.0 94307 94307 94307 11.13 470.53 94369 94369 94369 11.14 468.5 94430 94430 94430 11.1 468.6 94492 94492 94492 11.04 467.12 94553 94553 94553 11.01 466.59 94615 94615 94615 10.92 467.21 94676 94676 94676 10.99 467.04 94799 94799 94799 11.26 469.53 94861 94861 94861 11.03 468.06 94922 94922 94922 11.07 467.7 94984 94984 94984 11.14 463.11 95045 95045 95045 10.98 466.52 95107 95107 95107 11.04 466.57 95168 95168 95168 11.0 462.38 95230 95230 95230 11.01 463.13 95291 95291 95291 11.12 461.98 95414 95414 95414 11.02 459.97 95476 95476 95476 10.95 459.52 95537 95537 95537 11.07 461.85 95599 95599 95599 11.11 461.67 95660 95660 95660 10.89 463.13 95722 95722 95722 11.04 465.61 95783 95783 95783 10.92 463.1 95845 95845 95845 11.02 463.94 95906 95906 95906 11.14 464.97 96029 96029 96029 11.21 465.32 96091 96091 96091 11.09 463.32 96152 96152 96152 11.04 462.5 96214 96214 96214 11.09 465.33 96275 96275 96275 10.95 463.51 96337 96337 96337 11.01 463.02 96398 96398 96398 10.98 466.78 96460 96460 96460 11.07 467.65 96521 96521 96521 11.28 478.82 96644 96644 96644 11.04 472.98 96706 96706 96706 11.09 471.5 96767 96767 96767 11.18 469.49 96829 96829 96829 11.19 468.77 96890 96890 96890 10.98 469.8 96952 96952 96952 11.07 462.62 97013 97013 97013 11.26 476.29 97075 97075 97075 11.06 468.68 97136 97136 97136 11.16 464.35 97259 97259 97259 11.33 471.84 97321 97321 97321 11.24 470.41 97382 97382 97382 11.14 470.31 97444 97444 97444 11.1 468.1 97505 97505 97505 11.2 468.99 97567 97567 97567 11.15 467.74 97628 97628 97628 11.18 466.09 97690 97690 97690 11.17 466.27 97751 97751 97751 11.32 468.51 97874 97874 97874 11.21 472.55 97936 97936 97936 11.49 476.91 97997 97997 97997 11.31 475.79 98059 98059 98059 11.31 475.74 98120 98120 98120 11.4 477.45 98182 98182 98182 11.26 475.99 98243 98243 98243 11.25 475.1 98305 98305 98305 11.37 476.51 98366 98366 98366 11.3 475.87 98489 98489 98489 11.25 472.4 98551 98551 98551 11.25 477.14 98612 98612 98612 11.33 474.8 98674 98674 98674 11.17 472.46 98735 98735 98735 11.15 469.8 98797 98797 98797 11.13 468.38 98858 98858 98858 11.19 468.57 98920 98920 98920 10.75 453.2 98981 98981 98981 10.92 452.35 99104 99104 99104 10.86 454.81 99166 99166 99166 10.83 456.71 99227 99227 99227 10.85 454.47 99289 99289 99289 10.91 453.74 99350 99350 99350 11.0 457.7 99412 99412 99412 11.04 459.59 99473 99473 99473 11.07 454.78 99535 99535 99535 10.89 453.26 99596 99596 99596 11.1 454.57 99719 99719 99719 11.06 453.45 99781 99781 99781 10.98 453.23 99842 99842 99842 11.11 457.33 99904 99904 99904 11.05 455.53 99965 99965 99965 11.03 454.7 100027 100027 100027 10.99 456.82 100088 100088 100088 11.04 456.58 100150 100150 100150 11.02 457.0 100211 100211 100211 10.87 455.23 100334 100334 100334 10.88 456.49 100396 100396 100396 10.86 456.88 100457 100457 100457 10.88 457.81 100519 100519 100519 10.86 457.45 100580 100580 100580 11.12 455.1 100642 100642 100642 10.93 453.66 100703 100703 100703 10.83 452.23 100765 100765 100765 10.67 452.34 100826 100826 100826 10.67 452.85 100949 100949 100949 10.88 457.65 101011 101011 101011 10.99 463.89 101072 101072 101072 11.25 482.44 101134 101134 101134 11.2 480.59 101195 101195 101195 11.23 481.91 101257 101257 101257 11.28 479.36 101318 101318 101318 11.27 484.83 101380 101380 101380 11.42 487.41 101441 101441 101441 11.57 489.76 101564 101564 101564 11.51 487.0 101626 101626 101626 11.52 486.53 101687 101687 101687 11.44 485.27 101749 101749 101749 11.43 486.47 101810 101810 101810 11.46 485.27 101872 101872 101872 11.42 487.04 101933 101933 101933 11.51 486.51 101995 101995 101995 11.37 481.94 102056 102056 102056 11.38 480.08 102179 102179 102179 11.4 479.99 102241 102241 102241 11.34 477.89 102302 102302 102302 11.29 476.12 102364 102364 102364 11.43 475.87 102425 102425 102425 11.26 475.37 102487 102487 102487 11.21 478.29 102548 102548 102548 11.16 477.19 102610 102610 102610 11.11 480.7 102671 102671 102671 11.33 480.7 102794 102794 102794 11.21 478.34 102856 102856 102856 11.05 476.6 102917 102917 102917 11.2 476.06 102979 102979 102979 11.19 478.17 103040 103040 103040 11.27 478.52 103102 103102 103102 11.05 477.56 103163 103163 103163 11.22 477.66 103225 103225 103225 11.17 477.81 103286 103286 103286 11.16 477.75 103409 103409 103409 11.31 479.8 103471 103471 103471 11.34 484.42 103532 103532 103532 11.23 480.73 103594 103594 103594 11.24 478.53 103655 103655 103655 11.35 476.38 103717 103717 103717 11.27 479.69 103778 103778 103778 11.27 476.4 103840 103840 103840 11.15 475.97 103901 103901 103901 11.29 475.47 104024 104024 104024 11.19 476.29 104086 104086 104086 11.29 477.38 104147 104147 104147 11.29 484.16 104209 104209 104209 11.39 485.35 104270 104270 104270 11.58 484.85 104332 104332 104332 11.47 482.81 104393 104393 104393 11.47 483.37 104455 104455 104455 11.3 484.46 104516 104516 104516 11.39 483.67 104639 104639 104639 11.6 484.71 104701 104701 104701 11.6 485.47 104762 104762 104762 11.4 487.19 104824 104824 104824 11.57 485.28 104885 104885 104885 11.52 485.6 104947 104947 104947 11.43 484.87 105008 105008 105008 11.33 485.83 105070 105070 105070 11.49 484.87 105131 105131 105131 11.56 483.6 105254 105254 105254 11.44 479.95 105316 105316 105316 11.3 478.6 105377 105377 105377 11.13 479.37 105439 105439 105439 11.48 477.13 105500 105500 105500 11.38 478.06 105562 105562 105562 11.3 472.27 105623 105623 105623 11.26 474.44 105685 105685 105685 11.31 472.37 105746 105746 105746 11.22 474.68 105869 105869 105869 11.17 474.83 105931 105931 105931 11.34 474.48 105992 105992 105992 11.02 475.56 106054 106054 106054 11.3 475.81 106115 106115 106115 11.22 477.89 106177 106177 106177 11.28 479.27 106238 106238 106238 11.57 477.39 106300 106300 106300 11.07 477.32 106361 106361 106361 11.16 476.24 106484 106484 106484 10.96 467.37 106546 106546 106546 11.08 475.08 106607 106607 106607 10.96 473.84 106669 106669 106669 11.13 476.54 106730 106730 106730 11.01 472.13 106792 106792 106792 11.09 472.95 106853 106853 106853 10.94 474.39 106915 106915 106915 10.93 470.06 106976 106976 106976 10.97 472.04 107099 107099 107099 10.92 470.55 107161 107161 107161 10.97 471.05 107222 107222 107222 11.11 471.5 107284 107284 107284 10.93 472.55 107345 107345 107345 11.22 470.21 107407 107407 107407 11.23 471.41 107468 107468 107468 11.1 469.44 107530 107530 107530 11.41 480.36 107591 107591 107591 11.1 472.99 107714 107714 107714 11.2 473.85 107776 107776 107776 11.33 475.93 107837 107837 107837 11.49 476.9 107899 107899 107899 11.32 478.07 107960 107960 107960 11.29 479.01 108022 108022 108022 11.18 479.38 108083 108083 108083 11.27 480.94 108145 108145 108145 11.27 478.49 108206 108206 108206 11.37 480.06 108329 108329 108329 11.37 479.86 108391 108391 108391 11.3 483.72 108452 108452 108452 11.43 482.83 108514 108514 108514 11.5 485.22 108575 108575 108575 11.31 481.63 108637 108637 108637 11.22 479.85 108698 108698 108698 11.27 479.65 108760 108760 108760 11.18 477.76 108821 108821 108821 11.17 478.02 108945 108945 108945 11.1 477.44 109006 109006 109006 11.24 477.09 109068 109068 109068 11.34 477.34 109129 109129 109129 11.21 486.12 109191 109191 109191 11.12 479.72 109252 109252 109252 99999 99999 109314 109314 109314 99999 99999 109375 109375 109375 99999 99999 109437 109437 109437 99999 99999 109560 109560 109560 10.94 469.3 109621 109621 109621 11.22 481.59 109683 109683 109683 11.24 482.6 109744 109744 109744 11.11 473.21 109806 109806 109806 11.14 472.84 109867 109867 109867 11.17 472.33 109929 109929 109929 11.14 473.15 109990 109990 109990 11.23 476.59 110052 110052 110052 11.35 480.61 110175 110175 110175 11.57 489.02 110236 110236 110236 11.68 490.97 110298 110298 110298 11.64 489.6 110359 110359 110359 11.77 490.53 110421 110421 110421 11.57 490.66 110482 110482 110482 11.77 491.89 110544 110544 110544 11.82 490.26 110605 110605 110605 11.61 489.07 110667 110667 110667 11.7 489.24 110790 110790 110790 11.63 489.38 110852 110852 110852 11.85 488.66 110913 110913 110913 11.87 487.26 110975 110975 110975 11.87 485.06 111036 111036 111036 11.7 487.25 111098 111098 111098 11.52 483.18 111159 111159 111159 11.75 488.72 111221 111221 111221 11.59 488.28 111282 111282 111282 11.55 489.07 111405 111405 111405 11.56 486.55 111467 111467 111467 11.79 487.61 111528 111528 111528 11.52 487.13 111590 111590 111590 11.58 486.74 111651 111651 111651 11.61 487.72 111713 111713 111713 11.62 487.12 111774 111774 111774 11.53 487.58 111836 111836 111836 11.56 488.28 111897 111897 111897 11.62 488.82 112020 112020 112020 11.63 486.47 112082 112082 112082 11.6 486.65 112143 112143 112143 11.62 485.88 112205 112205 112205 11.54 486.26 112266 112266 112266 11.71 485.19 112328 112328 112328 11.49 486.0 112389 112389 112389 11.63 482.89 112451 112451 112451 11.65 484.68 112512 112512 112512 11.49 483.83 112635 112635 112635 11.43 484.12 112697 112697 112697 11.46 486.44 112758 112758 112758 11.47 485.11