45 1001 Markus Jesswein, Tanja Schuck, Andreas Engel Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Altenhoeferallee 1, 60438 Frankfurt/Main, Germany 1|HALO | GhOST-MS | mixing ratios of long-lived and very short-lived tracers measured with an in-situ GC-ECD instrument, integrated under usage of constant baseline PHILEAS 1 1 2023 09 19 2025 11 06 0 Mean sample time in UT seconds past midnight of flight date 4 1 1 1 1 99999 99999 99999 99999 Time_Start [s] Time_End [s] SF6 [ppt] CFC_12 [ppt] 25 ------------------------------------------------------------------------ Please inform the authors about the use of the data These are preliminary data and not for publication. Please adhere in all cases to the PHILEAS data protocol Contact: Andreas Engel (an.engel@iau.uni-frankfurt.de, phone +49 69 798 40259) ------------------------------------------------------------------------ Calibration Scale, Precision, Accuracy and Detection Limit are given separately for each dependent variable Primary calibration reference flasks: TO-Mutter (UEA scales), J-256 (AGAGE network) Calibration Scales SF6 CFC_12 SIO-05 SIO-05 ------------------------------------------------------------------------ Instrument precision in [%] NaN NaN NaN NaN NaN NAN NAN 0.6865 0.2608 Detection limit (S/N 3/1) in [ppt] per 100 mL air at STP NaN NaN NaN NaN NaN Values below detection limit are marked as 0.00 In case no measurements are available, the missing data value is used ------------------------------------------------------------------------ SF6 data non-linearity below measurement precision. no correction applied F12 mixing ratio data has been corrected for detector non-linearity by applying a second order polynom: k = a0 + a1 * mr_F12 + a2 * mr_F12^2 coefficients: a0 = -0.04257; a1 = 1.04244; a2 = 0.00013 ------------------------------------------------------------------------ 2 UTC Time_Start Time_End SF6 CFC_12 [s] [s] [s] [ppt] [ppt] 64511 64511 64511 11.85 485.57 64573 64573 64573 11.62 487.81 64696 64696 64696 11.6 484.94 64757 64757 64757 11.55 487.18 64819 64819 64819 11.53 484.35 64880 64880 64880 11.67 485.07 64942 64942 64942 11.55 485.33 65003 65003 65003 11.68 487.42 65065 65065 65065 11.72 488.1 65126 65126 65126 11.8 488.62 65188 65188 65188 11.66 489.93 65311 65311 65311 11.74 491.88 65372 65372 65372 11.95 490.89 65434 65434 65434 12.02 491.46 65495 65495 65495 12.04 491.66 65557 65557 65557 11.7 488.06 65618 65618 65618 11.67 488.77 65680 65680 65680 11.61 488.59 65741 65741 65741 11.63 487.34 65803 65803 65803 11.53 486.38 65926 65926 65926 11.62 488.53 65987 65987 65987 11.52 487.83 66049 66049 66049 11.56 488.09 66110 66110 66110 11.56 488.68 66172 66172 66172 11.47 487.14 66233 66233 66233 11.4 487.24 66295 66295 66295 11.43 484.99 66356 66356 66356 11.31 484.15 66418 66418 66418 11.32 483.04 66541 66541 66541 11.32 483.31 66602 66602 66602 11.48 484.55 66664 66664 66664 11.48 486.06 66725 66725 66725 11.49 485.36 66787 66787 66787 11.41 487.67 66848 66848 66848 11.47 484.99 66910 66910 66910 11.54 483.95 66971 66971 66971 11.54 484.05 67033 67033 67033 11.47 482.49 67156 67156 67156 11.43 479.84 67217 67217 67217 11.35 476.59 67279 67279 67279 11.35 472.59 67340 67340 67340 11.35 472.26 67402 67402 67402 11.1 472.99 67463 67463 67463 11.11 473.42 67525 67525 67525 11.23 472.36 67586 67586 67586 11.26 473.53 67648 67648 67648 11.21 470.24 67771 67771 67771 11.25 472.03 67832 67832 67832 11.33 471.78 67894 67894 67894 11.32 472.34 67955 67955 67955 11.23 473.05 68017 68017 68017 11.48 481.51 68078 68078 68078 11.3 474.71 68140 68140 68140 11.45 472.18 68201 68201 68201 11.32 471.15 68263 68263 68263 11.36 475.84 68386 68386 68386 11.31 476.08 68447 68447 68447 11.37 475.29 68509 68509 68509 11.4 482.81 68570 68570 68570 11.54 484.78 68632 68632 68632 11.58 487.66 68693 68693 68693 11.59 487.76 68755 68755 68755 11.64 486.96 68816 68816 68816 11.48 487.57 68878 68878 68878 11.41 484.65 69001 69001 69001 11.3 485.53 69062 69062 69062 11.32 485.42 69124 69124 69124 11.49 486.84 69185 69185 69185 11.41 488.27 69247 69247 69247 11.37 485.75 69308 69308 69308 11.4 487.54 69370 69370 69370 11.54 487.75 69431 69431 69431 11.44 487.2 69493 69493 69493 11.51 487.57 69616 69616 69616 11.51 487.32 69677 69677 69677 11.44 486.5 69739 69739 69739 11.53 486.66 69800 69800 69800 11.42 482.61 69862 69862 69862 11.4 482.79 69923 69923 69923 11.34 475.16 69985 69985 69985 11.25 474.92 70046 70046 70046 11.51 478.24 70108 70108 70108 11.32 478.62 70231 70231 70231 11.21 472.61 70292 70292 70292 11.3 473.77 70354 70354 70354 11.41 472.6 70415 70415 70415 11.2 472.52 70477 70477 70477 11.27 473.37 70538 70538 70538 11.37 475.08 70600 70600 70600 11.32 476.2 70661 70661 70661 11.2 474.71 70723 70723 70723 11.33 479.65 70846 70846 70846 11.2 473.93 70907 70907 70907 11.2 473.14 70969 70969 70969 11.25 472.9 71030 71030 71030 11.24 474.82 71092 71092 71092 11.22 474.58 71153 71153 71153 11.07 473.23 71215 71215 71215 10.96 471.64 71276 71276 71276 11.17 474.88 71338 71338 71338 11.06 472.43 71461 71461 71461 11.12 474.39 71522 71522 71522 11.03 474.32 71584 71584 71584 11.21 479.05 71645 71645 71645 11.13 476.6 71707 71707 71707 11.29 478.29 71768 71768 71768 11.28 479.15 71830 71830 71830 11.23 477.3 71891 71891 71891 11.33 477.32 71953 71953 71953 11.35 479.34 72076 72076 72076 11.26 478.96 72137 72137 72137 11.41 476.77 72199 72199 72199 11.28 476.56 72260 72260 72260 11.05 474.68 72322 72322 72322 11.15 473.98 72383 72383 72383 11.16 474.38 72445 72445 72445 11.25 474.1 72506 72506 72506 11.36 474.72 72568 72568 72568 11.1 475.63 72691 72691 72691 11.19 477.53 72752 72752 72752 11.16 475.59 72814 72814 72814 11.16 474.82 72875 72875 72875 11.37 473.41 72937 72937 72937 11.25 473.06 72998 72998 72998 11.28 473.51 73060 73060 73060 11.16 473.91 73121 73121 73121 11.2 472.83 73183 73183 73183 11.2 473.66 73306 73306 73306 11.36 471.6 73367 73367 73367 11.16 474.02 73429 73429 73429 11.33 474.87 73490 73490 73490 11.34 476.66 73552 73552 73552 11.38 474.99 73613 73613 73613 11.31 478.04 73675 73675 73675 11.32 476.59 73736 73736 73736 11.3 476.83 73798 73798 73798 11.37 477.22 73921 73921 73921 11.18 478.41 73982 73982 73982 11.38 477.97 74044 74044 74044 11.22 477.31 74105 74105 74105 11.28 477.39 74167 74167 74167 11.25 478.2 74228 74228 74228 11.24 476.62 74290 74290 74290 11.36 475.56 74352 74352 74352 11.21 474.5 74413 74413 74413 11.2 474.91 74536 74536 74536 11.28 476.76 74598 74598 74598 11.06 477.65 74659 74659 74659 11.41 477.85 74721 74721 74721 11.27 477.99 74782 74782 74782 11.27 480.07 74844 74844 74844 11.33 482.03 74905 74905 74905 11.43 485.06 74967 74967 74967 11.39 485.31 75028 75028 75028 11.38 484.98 75151 75151 75151 11.57 489.81 75213 75213 75213 11.61 489.94 75274 75274 75274 11.56 490.39 75336 75336 75336 11.54 492.48 75397 75397 75397 11.62 492.22 75459 75459 75459 11.57 492.51 75520 75520 75520 11.52 490.95 75582 75582 75582 11.53 490.55 75643 75643 75643 11.68 490.21 75766 75766 75766 11.72 489.8 75828 75828 75828 11.65 489.58 75889 75889 75889 11.72 489.85 75951 75951 75951 11.66 489.75 76012 76012 76012 11.59 490.36 76074 76074 76074 11.55 490.6 76135 76135 76135 11.57 491.19 76197 76197 76197 11.64 490.93 76258 76258 76258 11.58 491.35 76381 76381 76381 11.64 490.75 76443 76443 76443 11.53 491.31 76504 76504 76504 11.5 490.67 76566 76566 76566 11.61 489.78 76627 76627 76627 11.53 490.09 76689 76689 76689 11.59 490.1 76750 76750 76750 11.48 490.46 76812 76812 76812 11.76 490.4 76873 76873 76873 11.57 490.05 76996 76996 76996 11.53 490.61 77058 77058 77058 11.63 489.99 77119 77119 77119 11.65 490.46 77181 77181 77181 11.61 490.18 77242 77242 77242 11.65 489.97 77304 77304 77304 11.68 490.06 77365 77365 77365 11.57 490.1 77427 77427 77427 11.49 489.46 77488 77488 77488 11.53 489.44 77611 77611 77611 11.6 489.98 77673 77673 77673 11.54 490.75 77734 77734 77734 11.71 490.5 77796 77796 77796 11.53 491.36 77857 77857 77857 11.63 491.23 77919 77919 77919 11.41 489.95 77980 77980 77980 11.43 482.27 78042 78042 78042 11.44 487.69 78103 78103 78103 11.39 488.96 78226 78226 78226 11.52 487.46 78288 78288 78288 11.42 486.28 78349 78349 78349 11.34 483.28 78411 78411 78411 11.38 487.24 78472 78472 78472 11.54 489.01 78534 78534 78534 11.49 489.13 78595 78595 78595 11.58 489.22 78657 78657 78657 11.49 489.5 78718 78718 78718 11.48 487.41 78841 78841 78841 11.46 488.69 78903 78903 78903 11.44 489.19 78964 78964 78964 11.61 489.57 79026 79026 79026 11.58 489.19 79087 79087 79087 11.56 489.43 79149 79149 79149 11.63 490.11 79210 79210 79210 11.63 489.5 79272 79272 79272 11.56 488.99 79333 79333 79333 11.65 489.28 79456 79456 79456 11.59 489.85 79518 79518 79518 11.7 489.88 79579 79579 79579 11.57 487.77 79641 79641 79641 11.58 489.3 79702 79702 79702 11.57 488.93 79764 79764 79764 11.61 488.89 79825 79825 79825 11.38 489.98 79887 79887 79887 11.54 487.87 79948 79948 79948 11.44 487.62 80071 80071 80071 11.44 486.19 80133 80133 80133 11.43 485.86 80194 80194 80194 11.48 487.45 80256 80256 80256 11.58 487.76 80317 80317 80317 11.44 487.32 80379 80379 80379 11.57 487.79 80440 80440 80440 11.39 487.93 80502 80502 80502 11.45 488.5 80563 80563 80563 11.58 488.12 80686 80686 80686 11.47 489.67 80748 80748 80748 11.43 489.01 80809 80809 80809 11.45 487.81 80871 80871 80871 11.48 488.97 80932 80932 80932 11.47 488.16 80994 80994 80994 11.48 489.31 81055 81055 81055 11.48 489.12 81117 81117 81117 11.41 488.22 81178 81178 81178 11.31 485.33 81301 81301 81301 11.28 484.42 81363 81363 81363 11.41 483.25 81424 81424 81424 11.21 482.77 81486 81486 81486 11.12 478.96 81547 81547 81547 11.28 478.39 81609 81609 81609 11.18 477.63 81670 81670 81670 11.4 479.22 81732 81732 81732 11.12 476.83 81793 81793 81793 11.16 476.77 81916 81916 81916 11.2 474.88 81978 81978 81978 11.18 476.42 82039 82039 82039 11.17 474.86 82101 82101 82101 11.03 475.39 82162 82162 82162 11.2 475.68 82224 82224 82224 11.26 475.68 82285 82285 82285 11.14 474.49 82347 82347 82347 11.19 473.97 82408 82408 82408 11.11 473.89 82531 82531 82531 11.09 473.56 82593 82593 82593 11.05 471.49 82654 82654 82654 11.04 471.95 82716 82716 82716 10.96 471.24 82777 82777 82777 11.05 471.12 82839 82839 82839 10.98 473.02 82900 82900 82900 11.11 473.74 82962 82962 82962 11.1 471.31 83023 83023 83023 11.02 470.38 83146 83146 83146 11.13 472.02 83208 83208 83208 11.1 473.29 83269 83269 83269 11.18 473.32 83331 83331 83331 11.18 472.86 83392 83392 83392 11.13 473.92 83454 83454 83454 11.15 470.96 83515 83515 83515 11.12 473.28 83577 83577 83577 11.1 472.27 83638 83638 83638 11.1 471.28 83761 83761 83761 11.19 474.94 83823 83823 83823 11.22 476.19 83884 83884 83884 11.21 476.79 83946 83946 83946 11.33 479.28 84007 84007 84007 11.36 478.7 84069 84069 84069 11.32 479.51 84130 84130 84130 11.32 484.09 84192 84192 84192 11.4 485.43 84253 84253 84253 11.56 486.89 84376 84376 84376 11.49 489.67 84438 84438 84438 11.51 488.17 84499 84499 84499 11.41 486.39 84561 84561 84561 11.42 484.98 84622 84622 84622 11.4 484.83 84684 84684 84684 11.31 481.49 84745 84745 84745 11.46 481.23 84807 84807 84807 11.47 479.85 84868 84868 84868 11.31 477.74 84991 84991 84991 11.31 477.67 85053 85053 85053 11.18 476.31 85114 85114 85114 11.19 477.64 85176 85176 85176 11.33 477.77 85237 85237 85237 11.27 479.16 85299 85299 85299 11.31 479.39 85360 85360 85360 11.28 479.92 85422 85422 85422 11.38 481.73 85483 85483 85483 11.46 483.03 85606 85606 85606 11.36 483.62 85668 85668 85668 11.32 485.3 85729 85729 85729 11.41 485.2 85791 85791 85791 11.37 485.44 85852 85852 85852 11.35 485.38 85914 85914 85914 11.45 486.35 85975 85975 85975 11.37 483.22 86037 86037 86037 11.35 479.82 86098 86098 86098 11.25 480.26 86221 86221 86221 11.33 481.34 86283 86283 86283 11.24 480.16 86344 86344 86344 11.41 479.82 86406 86406 86406 11.43 477.78 86467 86467 86467 11.24 475.32 86529 86529 86529 11.2 475.1 86590 86590 86590 11.36 477.76 86652 86652 86652 11.43 476.75 86713 86713 86713 11.35 476.6 86836 86836 86836 11.27 476.22 86898 86898 86898 11.38 478.48 86959 86959 86959 11.31 477.69 87021 87021 87021 11.44 480.68 87082 87082 87082 11.51 480.07 87144 87144 87144 11.33 480.36 87205 87205 87205 11.52 479.9 87267 87267 87267 11.28 482.53 87328 87328 87328 11.28 480.32 87451 87451 87451 11.21 476.1 87513 87513 87513 11.11 475.92 87574 87574 87574 11.13 473.74 87636 87636 87636 11.04 471.98 87697 87697 87697 11.16 471.09 87759 87759 87759 10.92 469.97 87820 87820 87820 11.09 474.29 87882 87882 87882 11.0 472.86 87943 87943 87943 10.98 473.01 88066 88066 88066 11.13 471.5 88128 88128 88128 11.11 468.06 88189 88189 88189 11.02 467.77 88251 88251 88251 10.91 466.5 88312 88312 88312 11.09 465.55 88374 88374 88374 10.92 463.4 88435 88435 88435 10.91 463.62 88497 88497 88497 11.1 464.77 88558 88558 88558 11.05 466.17 88681 88681 88681 11.02 469.81 88743 88743 88743 11.16 468.63 88804 88804 88804 11.08 469.79 88866 88866 88866 11.31 476.0 88927 88927 88927 11.28 474.56 88989 88989 88989 11.06 469.3 89050 89050 89050 11.02 469.2 89112 89112 89112 11.04 469.5 89173 89173 89173 11.15 469.77 89296 89296 89296 10.92 455.95 89358 89358 89358 10.94 454.62 89419 89419 89419 10.8 455.72 89481 89481 89481 10.77 452.95 89542 89542 89542 10.92 453.05 89604 89604 89604 10.84 448.99 89665 89665 89665 10.83 449.46 89727 89727 89727 10.86 453.94 89788 89788 89788 10.91 455.97 89911 89911 89911 10.84 458.34 89973 89973 89973 10.97 458.85 90034 90034 90034 11.0 458.21 90096 90096 90096 10.98 456.51 90157 90157 90157 11.09 454.07 90219 90219 90219 10.95 451.45 90280 90280 90280 11.12 459.31 90342 90342 90342 11.01 458.89 90403 90403 90403 11.43 460.54 90526 90526 90526 10.94 461.59 90588 90588 90588 11.19 458.86 90649 90649 90649 11.11 457.03 90711 90711 90711 11.21 461.65 90772 90772 90772 11.25 465.88 90834 90834 90834 11.22 464.57 90895 90895 90895 11.22 464.73 90957 90957 90957 11.1 462.64 91018 91018 91018 11.26 464.4 91141 91141 91141 11.05 461.87 91203 91203 91203 11.03 460.01 91264 91264 91264 11.22 462.09 91326 91326 91326 11.1 457.08 91387 91387 91387 10.93 461.27 91449 91449 91449 11.07 463.11 91510 91510 91510 11.09 463.29 91572 91572 91572 10.96 461.85 91633 91633 91633 11.06 470.58 91756 91756 91756 11.18 476.24 91818 91818 91818 11.4 477.51 91879 91879 91879 11.07 476.54 91941 91941 91941 11.35 478.41 92002 92002 92002 11.28 478.16 92064 92064 92064 11.27 477.25 92125 92125 92125 11.28 478.68 92187 92187 92187 11.05 478.79 92248 92248 92248 11.1 476.8 92371 92371 92371 11.13 478.59 92433 92433 92433 11.08 477.55 92494 92494 92494 11.09 476.73 92556 92556 92556 11.28 480.13 92617 92617 92617 11.1 480.28 92679 92679 92679 11.24 480.73 92740 92740 92740 11.22 475.61 92802 92802 92802 11.05 470.11 92863 92863 92863 10.96 469.5 92986 92986 92986 11.25 472.36 93048 93048 93048 11.16 473.45 93109 93109 93109 11.12 474.21 93171 93171 93171 11.31 476.31 93232 93232 93232 11.32 476.49 93294 93294 93294 11.23 481.37 93355 93355 93355 11.32 481.68 93417 93417 93417 11.4 481.93 93478 93478 93478 11.38 482.0 93601 93601 93601 11.24 483.08 93663 93663 93663 11.36 482.18 93724 93724 93724 11.39 483.18 93786 93786 93786 11.39 484.05 93847 93847 93847 11.54 483.97 93909 93909 93909 11.39 483.41 93970 93970 93970 11.29 483.9 94032 94032 94032 11.37 480.57 94093 94093 94093 11.32 479.7 94216 94216 94216 11.27 476.44 94278 94278 94278 11.18 475.37 94339 94339 94339 11.3 476.14 94401 94401 94401 11.36 477.83 94462 94462 94462 11.58 481.35 94524 94524 94524 11.51 483.65 94585 94585 94585 11.47 484.41 94647 94647 94647 11.68 490.13 94708 94708 94708 11.64 489.61 94831 94831 94831 11.79 491.84 94893 94893 94893 11.89 491.63 94954 94954 94954 11.7 493.18 95016 95016 95016 11.86 492.29 95077 95077 95077 11.75 489.15 95139 95139 95139 11.61 489.15 95200 95200 95200 11.75 489.77 95262 95262 95262 11.87 489.7 95323 95323 95323 11.67 486.85 95446 95446 95446 11.61 489.62 95508 95508 95508 11.6 488.24 95569 95569 95569 11.58 486.89 95631 95631 95631 11.79 488.3 95692 95692 95692 11.56 489.26 95754 95754 95754 11.68 486.67 95815 95815 95815 11.69 487.65 95877 95877 95877 11.69 486.2 95938 95938 95938 11.64 486.75 96061 96061 96061 11.53 487.91