45 1001 Markus Jesswein, Tanja Schuck, Andreas Engel Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Altenhoeferallee 1, 60438 Frankfurt/Main, Germany 1|HALO | GhOST-MS | mixing ratios of long-lived and very short-lived tracers measured with an in-situ GC-ECD instrument, integrated under usage of constant baseline PHILEAS 1 1 2023 09 16 2025 11 06 0 Mean sample time in UT seconds past midnight of flight date 4 1 1 1 1 99999 99999 99999 99999 Time_Start [s] Time_End [s] SF6 [ppt] CFC_12 [ppt] 25 ------------------------------------------------------------------------ Please inform the authors about the use of the data These are preliminary data and not for publication. Please adhere in all cases to the PHILEAS data protocol Contact: Andreas Engel (an.engel@iau.uni-frankfurt.de, phone +49 69 798 40259) ------------------------------------------------------------------------ Calibration Scale, Precision, Accuracy and Detection Limit are given separately for each dependent variable Primary calibration reference flasks: TO-Mutter (UEA scales), J-256 (AGAGE network) Calibration Scales SF6 CFC_12 SIO-05 SIO-05 ------------------------------------------------------------------------ Instrument precision in [%] NaN NaN NaN NaN NaN NAN NAN 0.9970 0.3128 Detection limit (S/N 3/1) in [ppt] per 100 mL air at STP NaN NaN NaN NaN NaN Values below detection limit are marked as 0.00 In case no measurements are available, the missing data value is used ------------------------------------------------------------------------ SF6 data non-linearity below measurement precision. no correction applied F12 mixing ratio data has been corrected for detector non-linearity by applying a second order polynom: k = a0 + a1 * mr_F12 + a2 * mr_F12^2 coefficients: a0 = -0.04257; a1 = 1.04244; a2 = 0.00013 ------------------------------------------------------------------------ 2 UTC Time_Start Time_End SF6 CFC_12 [s] [s] [s] [ppt] [ppt] 79656 79656 79656 11.29 485.96 79717 79717 79717 11.41 485.19 79779 79779 79779 11.42 483.61 79840 79840 79840 11.25 480.17 79902 79902 79902 11.31 483.29 79963 79963 79963 11.57 484.33 80025 80025 80025 11.69 487.05 80086 80086 80086 11.69 486.49 80148 80148 80148 11.69 488.75 80271 80271 80271 11.7 491.02 80332 80332 80332 11.65 490.96 80394 80394 80394 11.6 490.77 80455 80455 80455 11.73 491.87 80517 80517 80517 11.75 492.98 80578 80578 80578 11.67 491.66 80640 80640 80640 11.55 492.52 80701 80701 80701 11.57 490.66 80763 80763 80763 11.43 488.91 80886 80886 80886 11.33 487.48 80947 80947 80947 11.38 484.7 81009 81009 81009 11.31 482.96 81070 81070 81070 11.26 481.6 81132 81132 81132 11.45 483.94 81193 81193 81193 11.33 481.52 81255 81255 81255 11.37 483.09 81316 81316 81316 11.46 483.29 81378 81378 81378 11.51 481.29 81501 81501 81501 11.48 483.77 81562 81562 81562 11.44 485.0 81624 81624 81624 11.51 484.08 81685 81685 81685 11.43 483.36 81747 81747 81747 11.61 485.42 81808 81808 81808 11.57 487.14 81870 81870 81870 11.61 487.65 81931 81931 81931 11.44 488.36 81993 81993 81993 11.45 487.9 82116 82116 82116 11.5 490.02 82177 82177 82177 11.5 488.15 82239 82239 82239 11.34 487.86 82300 82300 82300 11.43 487.34 82362 82362 82362 11.45 487.98 82423 82423 82423 11.49 489.92 82485 82485 82485 11.44 488.27 82546 82546 82546 11.27 488.33 82608 82608 82608 11.41 488.47 82731 82731 82731 11.48 489.74 82792 82792 82792 11.29 489.42 82854 82854 82854 11.52 488.73 82915 82915 82915 11.34 487.98 82977 82977 82977 11.54 487.21 83038 83038 83038 11.35 486.29 83100 83100 83100 11.48 487.57 83161 83161 83161 11.52 489.13 83223 83223 83223 11.45 490.16 83346 83346 83346 11.58 489.18 83407 83407 83407 11.63 489.94 83469 83469 83469 11.59 489.89 83530 83530 83530 11.57 491.16 83592 83592 83592 11.62 491.79 83653 83653 83653 11.59 488.65 83715 83715 83715 11.44 490.75 83776 83776 83776 11.65 492.61 83838 83838 83838 11.62 490.93 83961 83961 83961 11.6 491.55 84022 84022 84022 11.61 492.37 84084 84084 84084 11.56 491.97 84145 84145 84145 11.69 490.64 84207 84207 84207 11.59 491.39 84268 84268 84268 11.57 493.35 84330 84330 84330 11.51 491.83 84391 84391 84391 11.56 491.61 84453 84453 84453 11.61 491.87 84576 84576 84576 11.5 492.57 84637 84637 84637 11.52 491.59 84699 84699 84699 11.49 491.07 84760 84760 84760 11.58 490.37 84822 84822 84822 11.4 491.15 84883 84883 84883 11.57 491.74 84945 84945 84945 11.59 492.33 85006 85006 85006 11.55 490.51 85068 85068 85068 11.66 492.12 85191 85191 85191 11.59 491.43 85252 85252 85252 11.73 488.66 85314 85314 85314 11.59 490.2 85375 85375 85375 11.66 490.6 85437 85437 85437 11.51 489.87 85498 85498 85498 11.61 489.93 85560 85560 85560 11.54 489.19 85621 85621 85621 11.52 490.11 85683 85683 85683 11.52 489.48 85806 85806 85806 11.68 491.13 85867 85867 85867 11.71 491.32 85929 85929 85929 11.52 489.4 85990 85990 85990 11.71 492.3 86052 86052 86052 11.63 491.61 86113 86113 86113 11.64 490.16 86175 86175 86175 11.83 490.03 86236 86236 86236 11.62 491.1 86298 86298 86298 11.75 491.63 86421 86421 86421 11.6 491.67 86482 86482 86482 11.64 490.62 86544 86544 86544 11.86 491.82 86605 86605 86605 11.74 493.22 86667 86667 86667 11.67 491.79 86728 86728 86728 11.7 491.76 86790 86790 86790 11.7 492.87 86851 86851 86851 11.72 491.32 86913 86913 86913 11.76 491.11 87036 87036 87036 11.78 492.84 87097 87097 87097 11.73 490.7 87159 87159 87159 11.71 491.91 87220 87220 87220 11.64 491.31 87282 87282 87282 11.61 491.89 87343 87343 87343 11.65 491.97 87405 87405 87405 11.76 492.27 87466 87466 87466 11.61 491.75 87528 87528 87528 11.54 490.36 87651 87651 87651 11.51 491.5 87712 87712 87712 11.51 492.36 87774 87774 87774 11.71 492.0 87835 87835 87835 11.58 492.88 87897 87897 87897 11.58 491.65 87958 87958 87958 11.79 491.05 88020 88020 88020 11.73 492.14 88081 88081 88081 11.69 491.71 88143 88143 88143 11.71 492.35 88266 88266 88266 11.66 492.32 88327 88327 88327 11.68 491.95 88389 88389 88389 11.84 492.43 88450 88450 88450 11.56 491.77 88512 88512 88512 11.72 492.2 88573 88573 88573 11.65 490.61 88635 88635 88635 11.62 492.16 88696 88696 88696 11.77 489.76 88758 88758 88758 11.7 491.43 88881 88881 88881 11.67 492.87 88942 88942 88942 11.61 490.97 89004 89004 89004 11.67 492.16 89065 89065 89065 11.59 491.86 89127 89127 89127 11.52 491.45 89188 89188 89188 11.67 491.01 89250 89250 89250 11.51 492.12 89311 89311 89311 11.62 491.22 89373 89373 89373 11.68 490.59 89496 89496 89496 11.6 492.51 89557 89557 89557 11.56 492.05 89619 89619 89619 11.6 492.02 89680 89680 89680 11.58 491.05 89742 89742 89742 11.74 489.7 89803 89803 89803 11.5 491.16 89865 89865 89865 11.67 492.19 89926 89926 89926 11.7 491.4 89988 89988 89988 11.58 491.53 90111 90111 90111 11.58 492.42 90172 90172 90172 11.65 491.92 90234 90234 90234 11.66 490.99 90295 90295 90295 11.54 488.96 90357 90357 90357 11.61 490.25 90418 90418 90418 11.58 491.01 90480 90480 90480 11.78 491.1 90541 90541 90541 11.67 490.6 90603 90603 90603 11.72 490.57 90726 90726 90726 11.81 491.2 90787 90787 90787 11.67 489.58 90849 90849 90849 11.59 490.76 90910 90910 90910 11.84 490.01 90972 90972 90972 11.88 490.74 91033 91033 91033 11.7 490.55 91095 91095 91095 11.7 491.31 91156 91156 91156 11.76 490.03 91218 91218 91218 11.75 490.85 91341 91341 91341 11.82 492.47 91402 91402 91402 11.74 490.94 91464 91464 91464 11.7 490.97 91525 91525 91525 11.68 490.06 91587 91587 91587 11.66 488.48 91648 91648 91648 11.54 491.64 91710 91710 91710 11.52 489.24 91771 91771 91771 11.53 490.52 91833 91833 91833 11.44 490.05 91956 91956 91956 11.43 492.39 92017 92017 92017 11.48 492.26 92079 92079 92079 11.57 492.08 92140 92140 92140 11.58 492.08 92202 92202 92202 11.51 490.67 92263 92263 92263 11.52 489.97 92325 92325 92325 11.53 491.23 92386 92386 92386 11.66 491.66 92448 92448 92448 11.51 490.49 92571 92571 92571 11.6 490.86 92632 92632 92632 11.38 493.02 92694 92694 92694 11.63 492.84 92755 92755 92755 11.51 490.73 92817 92817 92817 11.47 491.54 92878 92878 92878 11.68 491.71 92940 92940 92940 11.59 490.71 93001 93001 93001 11.71 490.69 93063 93063 93063 11.69 490.51 93186 93186 93186 11.95 490.8 93247 93247 93247 11.91 490.92 93309 93309 93309 11.93 491.04 93370 93370 93370 12.09 492.11 93432 93432 93432 11.96 490.91 93493 93493 93493 12.19 491.9 93555 93555 93555 12.13 492.06 93616 93616 93616 12.23 491.97 93678 93678 93678 12.22 493.07 93801 93801 93801 12.46 492.26 93862 93862 93862 12.11 493.22 93924 93924 93924 12.16 492.44 93985 93985 93985 12.19 491.12 94047 94047 94047 12.09 492.85 94108 94108 94108 12.1 492.88 94170 94170 94170 12.03 492.62 94231 94231 94231 12.05 492.01 94293 94293 94293 12.15 491.39 94416 94416 94416 12.09 491.78 94477 94477 94477 12.13 491.77 94539 94539 94539 12.17 493.38 94600 94600 94600 12.1 491.95 94662 94662 94662 12.18 490.85 94723 94723 94723 12.08 494.04 94785 94785 94785 12.11 492.42 94846 94846 94846 12.03 494.02 94908 94908 94908 12.01 492.93 95031 95031 95031 12.19 491.91 95092 95092 95092 11.98 492.56 95154 95154 95154 11.97 491.03 95215 95215 95215 12.01 490.94 95277 95277 95277 12.08 491.1 95338 95338 95338 12.12 490.14 95400 95400 95400 12.11 491.88 95461 95461 95461 12.3 491.79 95523 95523 95523 12.14 492.52 95646 95646 95646 12.11 491.28 95707 95707 95707 12.11 489.8 95769 95769 95769 12.05 493.12 95830 95830 95830 12.16 491.51 95892 95892 95892 12.17 492.26 95953 95953 95953 12.04 492.06 96015 96015 96015 12.22 491.53 96076 96076 96076 12.22 491.31 96138 96138 96138 12.01 492.22 96261 96261 96261 12.05 492.81 96322 96322 96322 12.14 492.85 96384 96384 96384 12.4 493.75 96445 96445 96445 12.27 492.43 96507 96507 96507 12.37 492.65 96568 96568 96568 12.3 492.06 96630 96630 96630 12.26 491.17 96691 96691 96691 12.2 492.57 96753 96753 96753 12.24 491.62 96876 96876 96876 12.16 491.21 96937 96937 96937 12.1 490.95 96999 96999 96999 12.02 491.52 97060 97060 97060 11.65 491.72 97122 97122 97122 11.7 489.48 97183 97183 97183 11.7 489.79 97245 97245 97245 11.83 488.56 97306 97306 97306 11.73 489.97 97368 97368 97368 11.61 489.27 97491 97491 97491 11.54 489.82 97552 97552 97552 11.67 491.57 97614 97614 97614 11.57 492.56 97675 97675 97675 11.62 493.65 97737 97737 97737 11.46 492.56 97798 97798 97798 11.59 491.77 97860 97860 97860 11.45 492.29 97921 97921 97921 11.49 491.23 97983 97983 97983 11.56 491.15 98106 98106 98106 11.48 490.99 98167 98167 98167 11.4 490.65 98229 98229 98229 11.33 490.5 98290 98290 98290 11.43 491.02 98352 98352 98352 11.47 491.2 98413 98413 98413 11.5 490.54 98475 98475 98475 11.6 490.29 98536 98536 98536 11.56 489.97 98598 98598 98598 11.52 485.72 98721 98721 98721 11.55 491.64 98782 98782 98782 11.47 489.76 98844 98844 98844 11.65 490.37 98905 98905 98905 11.69 490.67 98967 98967 98967 11.62 490.11 99028 99028 99028 11.38 490.18 99090 99090 99090 11.65 491.3 99151 99151 99151 11.45 491.59 99213 99213 99213 11.44 493.68 99336 99336 99336 11.39 491.61 99397 99397 99397 11.49 491.61 99459 99459 99459 11.54 489.86 99520 99520 99520 11.48 489.38 99582 99582 99582 11.52 490.27 99643 99643 99643 11.67 489.67 99705 99705 99705 11.58 489.7 99766 99766 99766 11.55 489.9 99828 99828 99828 11.54 491.04 99951 99951 99951 11.55 490.34 100012 100012 100012 11.42 490.42 100074 100074 100074 11.54 491.08 100135 100135 100135 11.46 490.39 100197 100197 100197 11.46 490.48 100258 100258 100258 11.62 490.75 100320 100320 100320 11.38 490.34 100381 100381 100381 11.48 490.06 100443 100443 100443 11.45 492.25 100566 100566 100566 11.55 490.98 100627 100627 100627 11.57 492.01 100689 100689 100689 11.51 489.65 100750 100750 100750 11.44 490.47 100812 100812 100812 11.51 489.89 100873 100873 100873 11.32 489.59 100935 100935 100935 11.38 489.42 100996 100996 100996 11.45 490.96 101058 101058 101058 11.46 490.77 101181 101181 101181 11.47 489.97 101242 101242 101242 11.46 491.24 101304 101304 101304 11.62 491.14 101365 101365 101365 11.63 490.5 101427 101427 101427 11.58 490.7 101488 101488 101488 11.58 490.78 101550 101550 101550 11.4 490.13 101611 101611 101611 11.47 490.57 101673 101673 101673 11.43 491.32 101796 101796 101796 11.55 491.17 101857 101857 101857 11.46 490.92 101919 101919 101919 11.62 490.39 101980 101980 101980 11.47 488.63 102042 102042 102042 11.44 488.53 102103 102103 102103 11.62 489.85 102165 102165 102165 11.53 489.68 102226 102226 102226 11.63 489.74 102288 102288 102288 11.55 490.31 102411 102411 102411 11.56 490.93 102472 102472 102472 11.46 490.99 102534 102534 102534 11.56 490.45 102595 102595 102595 11.63 490.77 102657 102657 102657 11.49 488.69 102718 102718 102718 11.61 490.17 102780 102780 102780 11.66 489.77 102841 102841 102841 11.54 488.1 102903 102903 102903 11.64 488.95 103026 103026 103026 11.66 488.76 103087 103087 103087 11.78 488.68 103149 103149 103149 11.58 487.82 103210 103210 103210 11.59 488.93 103272 103272 103272 11.55 487.52 103333 103333 103333 11.77 486.93 103395 103395 103395 11.58 486.79 103456 103456 103456 11.58 488.6 103518 103518 103518 11.47 488.13 103641 103641 103641 11.56 487.16 103702 103702 103702 11.44 487.78 103764 103764 103764 11.37 485.0 103825 103825 103825 11.44 486.92 103887 103887 103887 11.72 486.33 103948 103948 103948 11.6 487.47 104010 104010 104010 11.57 489.11 104071 104071 104071 11.43 487.7 104133 104133 104133 11.43 485.57 104256 104256 104256 11.3 480.5 104317 104317 104317 11.29 476.31 104379 104379 104379 11.37 478.98 104440 104440 104440 11.37 481.04 104502 104502 104502 11.4 482.55 104563 104563 104563 11.33 471.34 104625 104625 104625 11.35 474.31 104686 104686 104686 11.28 479.27 104748 104748 104748 11.53 483.36 104871 104871 104871 11.42 483.31 104932 104932 104932 11.32 480.87 104994 104994 104994 11.24 480.22 105055 105055 105055 11.25 475.36 105117 105117 105117 11.21 476.07 105178 105178 105178 11.1 477.25 105240 105240 105240 11.14 475.81 105301 105301 105301 11.35 475.79 105363 105363 105363 11.37 479.86 105486 105486 105486 11.33 478.77 105547 105547 105547 11.35 479.41 105609 105609 105609 11.32 480.11 105670 105670 105670 11.33 479.03 105732 105732 105732 11.3 479.04 105793 105793 105793 11.37 481.95 105855 105855 105855 11.39 481.17 105916 105916 105916 11.33 480.85 105978 105978 105978 11.24 481.23 106101 106101 106101 11.3 480.29 106162 106162 106162 11.17 475.3 106224 106224 106224 11.21 473.51 106285 106285 106285 11.12 473.51 106347 106347 106347 11.09 474.68 106409 106409 106409 11.38 476.23 106470 106470 106470 11.22 475.52 106532 106532 106532 11.19 474.43 106593 106593 106593 11.15 474.64 106716 106716 106716 11.14 474.18 106778 106778 106778 11.07 474.74 106839 106839 106839 11.14 475.4 106901 106901 106901 11.29 475.7 106962 106962 106962 11.31 476.59 107024 107024 107024 11.29 473.25 107085 107085 107085 11.33 474.04 107147 107147 107147 11.2 473.99 107208 107208 107208 11.12 473.32 107331 107331 107331 11.27 474.24 107393 107393 107393 11.32 477.36 107454 107454 107454 11.19 475.76 107516 107516 107516 11.15 474.97 107577 107577 107577 11.14 473.43 107639 107639 107639 11.17 477.15 107700 107700 107700 11.03 473.31 107762 107762 107762 11.29 483.74 107823 107823 107823 11.34 483.45 107946 107946 107946 11.45 483.64 108008 108008 108008 11.47 484.38 108069 108069 108069 11.77 490.42 108131 108131 108131 11.69 490.34 108192 108192 108192 11.67 489.96 108254 108254 108254 11.66 490.94 108315 108315 108315 11.75 490.74 108377 108377 108377 11.86 489.99 108438 108438 108438 11.81 489.1 108561 108561 108561 11.66 488.4 108623 108623 108623 11.82 488.24 108684 108684 108684 11.85 488.73 108746 108746 108746 11.67 488.44 108807 108807 108807 11.63 487.92 108869 108869 108869 11.65 488.57 108930 108930 108930 11.63 488.56 108992 108992 108992 11.66 487.93 109053 109053 109053 11.67 486.45 109176 109176 109176 11.58 485.91 109238 109238 109238 11.5 484.97 109299 109299 109299 11.63 487.03 109361 109361 109361 11.38 485.58