45 1001 Markus Jesswein, Tanja Schuck, Andreas Engel Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Altenhoeferallee 1, 60438 Frankfurt/Main, Germany 1|HALO | GhOST-MS | mixing ratios of long-lived and very short-lived tracers measured with an in-situ GC-ECD instrument, integrated under usage of constant baseline PHILEAS 1 1 2023 09 15 2025 11 06 0 Mean sample time in UT seconds past midnight of flight date 4 1 1 1 1 99999 99999 99999 99999 Time_Start [s] Time_End [s] SF6 [ppt] CFC_12 [ppt] 25 ------------------------------------------------------------------------ Please inform the authors about the use of the data These are preliminary data and not for publication. Please adhere in all cases to the PHILEAS data protocol Contact: Andreas Engel (an.engel@iau.uni-frankfurt.de, phone +49 69 798 40259) ------------------------------------------------------------------------ Calibration Scale, Precision, Accuracy and Detection Limit are given separately for each dependent variable Primary calibration reference flasks: TO-Mutter (UEA scales), J-256 (AGAGE network) Calibration Scales SF6 CFC_12 SIO-05 SIO-05 ------------------------------------------------------------------------ Instrument precision in [%] NaN NaN NaN NaN NaN NAN NAN 0.8823 0.2633 Detection limit (S/N 3/1) in [ppt] per 100 mL air at STP NaN NaN NaN NaN NaN Values below detection limit are marked as 0.00 In case no measurements are available, the missing data value is used ------------------------------------------------------------------------ SF6 data non-linearity below measurement precision. no correction applied F12 mixing ratio data has been corrected for detector non-linearity by applying a second order polynom: k = a0 + a1 * mr_F12 + a2 * mr_F12^2 coefficients: a0 = -0.04257; a1 = 1.04244; a2 = 0.00013 ------------------------------------------------------------------------ 2 UTC Time_Start Time_End SF6 CFC_12 [s] [s] [s] [ppt] [ppt] 79131 79131 79131 11.49 485.77 79193 79193 79193 11.5 486.57 79254 79254 79254 11.54 485.03 79377 79377 79377 11.59 484.65 79439 79439 79439 11.62 484.4 79500 79500 79500 11.68 484.57 79562 79562 79562 11.58 484.32 79623 79623 79623 11.47 485.09 79685 79685 79685 11.3 486.5 79746 79746 79746 11.71 486.0 79808 79808 79808 11.52 487.16 79869 79869 79869 11.42 488.19 79992 79992 79992 11.44 486.62 80054 80054 80054 11.41 487.45 80115 80115 80115 11.44 486.61 80177 80177 80177 11.45 485.74 80238 80238 80238 11.39 486.29 80300 80300 80300 11.35 485.66 80361 80361 80361 11.54 487.38 80423 80423 80423 11.41 485.59 80484 80484 80484 11.37 487.19 80607 80607 80607 11.54 486.96 80669 80669 80669 11.39 489.1 80730 80730 80730 11.56 488.43 80792 80792 80792 11.65 490.62 80853 80853 80853 11.55 490.11 80915 80915 80915 11.56 489.62 80976 80976 80976 11.41 488.76 81038 81038 81038 11.46 485.2 81099 81099 81099 11.44 484.94 81222 81222 81222 11.5 487.59 81284 81284 81284 11.5 485.61 81345 81345 81345 11.47 484.12 81407 81407 81407 11.46 485.11 81468 81468 81468 11.48 483.62 81530 81530 81530 11.52 484.31 81591 81591 81591 11.4 477.25 81653 81653 81653 11.16 471.13 81714 81714 81714 11.19 471.14 81837 81837 81837 11.09 468.11 81899 81899 81899 10.99 468.4 81961 81961 81961 11.12 471.76 82022 82022 82022 11.32 474.09 82084 82084 82084 11.24 475.42 82145 82145 82145 11.29 472.53 82207 82207 82207 11.16 473.33 82268 82268 82268 11.24 473.68 82330 82330 82330 11.22 474.71 82453 82453 82453 11.29 473.46 82514 82514 82514 11.37 472.4 82576 82576 82576 11.23 473.59 82637 82637 82637 11.22 471.91 82699 82699 82699 11.45 479.59 82760 82760 82760 11.54 486.77 82822 82822 82822 11.49 482.06 82883 82883 82883 11.63 481.42 82945 82945 82945 11.71 491.59 83068 83068 83068 11.84 492.18 83129 83129 83129 11.97 492.28 83191 83191 83191 12.15 491.54 83252 83252 83252 12.32 491.16 83314 83314 83314 12.17 494.26 83375 83375 83375 11.96 492.92 83437 83437 83437 11.81 491.76 83498 83498 83498 11.75 491.58 83560 83560 83560 11.84 491.07 83683 83683 83683 11.68 490.86 83745 83745 83745 11.61 490.58 83806 83806 83806 11.74 491.02 83868 83868 83868 11.57 490.48 83929 83929 83929 11.66 491.43 83991 83991 83991 11.73 490.38 84052 84052 84052 11.64 490.41 84114 84114 84114 11.66 490.57 84175 84175 84175 11.76 491.26 84298 84298 84298 11.71 491.0 84360 84360 84360 11.56 491.72 84422 84422 84422 11.56 491.96 84483 84483 84483 11.56 490.91 84545 84545 84545 11.62 491.66 84606 84606 84606 11.52 491.42 84668 84668 84668 11.64 491.83 84729 84729 84729 11.59 491.03 84791 84791 84791 11.73 491.31 84914 84914 84914 11.61 490.67 84975 84975 84975 11.69 491.95 85037 85037 85037 11.54 491.34 85098 85098 85098 11.49 491.24 85160 85160 85160 11.68 492.05 85221 85221 85221 11.65 491.34 85283 85283 85283 11.6 491.76 85344 85344 85344 11.63 493.24 85406 85406 85406 11.69 490.9 85529 85529 85529 11.62 492.12 85590 85590 85590 11.57 491.35 85652 85652 85652 11.53 490.96 85713 85713 85713 11.57 491.2 85775 85775 85775 11.54 491.66 85836 85836 85836 11.86 491.29 85898 85898 85898 11.74 491.89 85959 85959 85959 11.71 492.22 86021 86021 86021 11.57 491.15 86144 86144 86144 11.79 490.73 86205 86205 86205 11.62 489.71 86267 86267 86267 11.65 490.18 86328 86328 86328 11.63 490.92 86390 86390 86390 11.55 490.46 86451 86451 86451 11.61 490.17 86513 86513 86513 11.59 491.52 86574 86574 86574 11.63 489.25 86636 86636 86636 11.52 490.94 86759 86759 86759 11.77 492.01 86820 86820 86820 11.6 491.45 86882 86882 86882 11.55 491.02 86943 86943 86943 11.58 492.26 87005 87005 87005 11.47 491.82 87066 87066 87066 11.66 492.22 87128 87128 87128 11.66 491.09 87189 87189 87189 11.73 492.52 87251 87251 87251 11.71 493.6 87374 87374 87374 11.59 492.5 87435 87435 87435 11.58 491.81 87497 87497 87497 11.63 492.44 87558 87558 87558 11.58 491.71 87620 87620 87620 11.52 491.35 87681 87681 87681 11.58 492.19 87743 87743 87743 11.69 492.19 87804 87804 87804 11.6 492.35 87866 87866 87866 11.61 492.8 87989 87989 87989 11.58 492.75 88050 88050 88050 11.93 492.01 88112 88112 88112 12.05 491.47 88173 88173 88173 11.89 490.04 88235 88235 88235 11.93 491.54 88296 88296 88296 11.91 491.16 88358 88358 88358 12.01 491.31 88419 88419 88419 11.96 491.33 88481 88481 88481 11.94 491.24 88604 88604 88604 11.83 491.49 88665 88665 88665 11.91 489.34 88727 88727 88727 11.85 490.88 88788 88788 88788 11.74 491.48 88850 88850 88850 11.73 491.11 88911 88911 88911 11.88 491.03 88973 88973 88973 11.92 490.1 89034 89034 89034 11.96 491.1 89096 89096 89096 11.97 491.14 89219 89219 89219 12.22 492.3 89280 89280 89280 12.2 491.77 89342 89342 89342 12.07 489.23 89403 89403 89403 12.52 491.85 89465 89465 89465 12.35 490.74 89526 89526 89526 12.21 492.19 89588 89588 89588 12.15 490.02 89649 89649 89649 12.25 489.23 89711 89711 89711 12.23 491.18 89834 89834 89834 12.12 492.15 89895 89895 89895 12.25 490.45 89957 89957 89957 12.2 492.11 90018 90018 90018 12.23 492.06 90080 90080 90080 12.22 491.72 90141 90141 90141 12.32 491.94 90203 90203 90203 12.22 491.78 90264 90264 90264 12.03 491.27 90326 90326 90326 12.14 491.58 90449 90449 90449 12.27 492.08 90510 90510 90510 12.2 493.15 90572 90572 90572 12.09 491.69 90633 90633 90633 12.06 492.58 90695 90695 90695 12.15 489.48 90818 90818 90818 11.98 490.7 90880 90880 90880 11.94 491.78 90941 90941 90941 12.08 492.7 91064 91064 91064 12.03 491.29 91126 91126 91126 12.07 491.29 91187 91187 91187 13.0 491.31 91249 91249 91249 12.0 490.07 91310 91310 91310 12.12 490.65 91372 91372 91372 11.95 489.72 91433 91433 91433 11.95 491.53 91495 91495 91495 12.12 490.12 91556 91556 91556 12.12 487.76 91679 91679 91679 12.22 488.94 91741 91741 91741 12.28 490.8 91802 91802 91802 12.11 489.96 91864 91864 91864 12.05 490.58 91925 91925 91925 12.23 490.61 91987 91987 91987 12.08 490.57 92048 92048 92048 11.9 490.22 92110 92110 92110 12.17 490.36 92171 92171 92171 11.88 492.39 92294 92294 92294 11.7 491.58 92356 92356 92356 11.96 490.54 92417 92417 92417 12.17 492.51 92479 92479 92479 11.84 490.61 92540 92540 92540 11.87 493.35 92602 92602 92602 11.7 493.36 92663 92663 92663 11.74 492.65 92725 92725 92725 11.71 492.07 92786 92786 92786 11.58 494.0 92909 92909 92909 11.73 492.21 92971 92971 92971 11.63 492.84 93032 93032 93032 11.54 491.39 93094 93094 93094 11.72 491.07 93155 93155 93155 11.89 491.16 93217 93217 93217 11.98 491.21 93278 93278 93278 11.91 491.47 93340 93340 93340 11.94 489.94 93401 93401 93401 11.6 490.52 93524 93524 93524 11.77 490.46 93586 93586 93586 11.58 489.51 93647 93647 93647 11.45 489.8 93709 93709 93709 11.74 490.76 93770 93770 93770 11.68 491.9 93832 93832 93832 11.79 491.71 93893 93893 93893 11.78 491.85 93955 93955 93955 11.69 491.98 94016 94016 94016 11.61 491.07 94139 94139 94139 11.95 491.22 94201 94201 94201 11.84 492.14 94262 94262 94262 11.71 491.27 94324 94324 94324 11.89 492.6 94385 94385 94385 11.73 491.78 94447 94447 94447 11.98 492.6 94508 94508 94508 11.64 492.24 94570 94570 94570 11.82 492.4 94631 94631 94631 11.84 492.4 94754 94754 94754 12.11 491.9 94816 94816 94816 11.88 491.08 94877 94877 94877 11.81 492.03 94939 94939 94939 11.87 493.08 95000 95000 95000 11.73 492.4 95062 95062 95062 11.66 492.11 95123 95123 95123 11.76 492.27 95185 95185 95185 11.79 491.34 95246 95246 95246 11.86 491.48 95369 95369 95369 11.78 491.46 95431 95431 95431 11.68 489.84 95492 95492 95492 11.98 490.49 95554 95554 95554 11.8 490.29 95615 95615 95615 11.78 490.06 95677 95677 95677 11.73 491.54 95738 95738 95738 11.89 489.17 95800 95800 95800 11.6 490.37 95861 95861 95861 11.65 490.63 95984 95984 95984 11.7 490.17 96046 96046 96046 11.64 489.84 96107 96107 96107 11.68 489.34 96169 96169 96169 11.58 488.06 96230 96230 96230 11.59 485.47 96292 96292 96292 11.67 483.78 96353 96353 96353 11.36 481.64 96415 96415 96415 11.35 482.27 96476 96476 96476 11.51 482.09 96599 96599 96599 11.34 480.19 96661 96661 96661 11.46 483.25 96722 96722 96722 11.42 483.25 96784 96784 96784 11.41 485.57 96845 96845 96845 11.42 481.81 96907 96907 96907 11.28 480.53 96968 96968 96968 11.45 482.36 97030 97030 97030 11.34 482.87 97091 97091 97091 11.37 483.62 97214 97214 97214 11.3 484.17 97276 97276 97276 11.43 483.51 97337 97337 97337 11.45 484.43 97399 97399 97399 11.38 486.06 97460 97460 97460 11.32 485.58 97522 97522 97522 11.38 486.32 97583 97583 97583 11.27 484.25 97645 97645 97645 11.18 487.27 97706 97706 97706 11.34 486.13 97829 97829 97829 11.31 485.94 97891 97891 97891 11.44 486.73 97952 97952 97952 11.39 486.05 98014 98014 98014 11.4 484.94 98075 98075 98075 11.47 485.66 98137 98137 98137 11.57 485.35 98198 98198 98198 11.5 486.21 98260 98260 98260 11.54 485.84 98321 98321 98321 11.42 486.79 98444 98444 98444 11.48 488.9 98506 98506 98506 11.66 491.12 98567 98567 98567 11.72 491.8 98629 98629 98629 11.6 492.13 98690 98690 98690 11.64 491.47 98752 98752 98752 11.84 491.93 98813 98813 98813 11.79 490.51 98875 98875 98875 11.71 490.98 98936 98936 98936 11.53 490.76 99059 99059 99059 11.71 492.38 99121 99121 99121 11.56 490.29 99182 99182 99182 11.81 490.76 99244 99244 99244 11.7 490.0 99305 99305 99305 11.64 490.44 99367 99367 99367 11.7 489.88 99428 99428 99428 11.62 490.45 99490 99490 99490 11.7 490.85 99551 99551 99551 11.54 490.99 99674 99674 99674 11.61 491.8 99736 99736 99736 11.52 490.11 99797 99797 99797 11.41 491.01 99859 99859 99859 11.66 490.23 99920 99920 99920 11.63 490.85 99982 99982 99982 11.78 490.2 100043 100043 100043 11.7 489.37 100105 100105 100105 11.84 490.92 100166 100166 100166 11.58 491.44 100289 100289 100289 11.8 490.14 100351 100351 100351 11.74 489.7 100412 100412 100412 11.76 489.02 100474 100474 100474 11.88 490.21 100535 100535 100535 11.84 489.59 100597 100597 100597 11.79 492.13 100658 100658 100658 11.76 491.76 100720 100720 100720 11.84 491.66 100781 100781 100781 11.87 492.23 100904 100904 100904 11.87 492.36 100966 100966 100966 11.83 492.16 101027 101027 101027 11.75 490.99 101089 101089 101089 11.83 490.81 101150 101150 101150 11.85 493.06 101212 101212 101212 11.78 493.96 101273 101273 101273 11.99 493.64 101335 101335 101335 11.77 493.2 101396 101396 101396 11.78 491.31 101519 101519 101519 11.77 492.99 101581 101581 101581 11.73 491.98 101642 101642 101642 11.68 493.02 101704 101704 101704 11.81 492.64 101765 101765 101765 12.01 492.08 101827 101827 101827 11.85 493.9 101888 101888 101888 11.74 491.77 101950 101950 101950 11.74 493.04 102011 102011 102011 11.91 493.31 102134 102134 102134 11.75 493.92 102196 102196 102196 11.81 493.36 102257 102257 102257 11.79 492.37 102319 102319 102319 11.85 492.61 102380 102380 102380 11.81 492.81 102442 102442 102442 11.67 491.56 102503 102503 102503 11.68 491.91 102565 102565 102565 11.71 492.11 102626 102626 102626 11.8 491.2 102749 102749 102749 11.94 492.36 102811 102811 102811 11.9 492.0 102872 102872 102872 11.93 493.52 102934 102934 102934 11.72 491.93 102995 102995 102995 11.73 493.12 103057 103057 103057 11.54 491.86 103118 103118 103118 11.46 491.45 103180 103180 103180 11.51 491.55 103241 103241 103241 11.67 492.09 103364 103364 103364 11.46 491.25 103426 103426 103426 11.47 490.48 103487 103487 103487 11.44 491.02 103549 103549 103549 11.56 491.68 103610 103610 103610 11.46 490.63 103672 103672 103672 11.55 491.07 103733 103733 103733 11.55 492.0 103795 103795 103795 11.61 493.17 103856 103856 103856 11.65 490.67 103979 103979 103979 11.63 491.59 104041 104041 104041 11.49 491.14 104102 104102 104102 11.52 491.77 104164 104164 104164 11.49 490.42 104225 104225 104225 11.5 490.8 104287 104287 104287 11.46 490.25 104348 104348 104348 11.39 488.81 104410 104410 104410 11.58 488.84 104471 104471 104471 11.66 490.54 104594 104594 104594 11.67 491.35 104656 104656 104656 11.64 492.0 104717 104717 104717 11.66 490.66 104779 104779 104779 11.61 491.22 104840 104840 104840 11.44 491.76 104902 104902 104902 11.68 491.59 104963 104963 104963 11.68 491.76 105025 105025 105025 11.6 491.3 105086 105086 105086 11.5 490.41 105209 105209 105209 11.6 491.14 105271 105271 105271 11.56 490.02 105332 105332 105332 11.63 491.03 105394 105394 105394 11.66 491.49 105455 105455 105455 11.53 492.1 105517 105517 105517 11.72 490.92 105578 105578 105578 11.63 490.6 105640 105640 105640 11.45 490.73 105701 105701 105701 11.57 490.69 105824 105824 105824 11.56 491.52 105886 105886 105886 11.64 489.87 105947 105947 105947 11.45 490.43 106009 106009 106009 11.64 490.01 106070 106070 106070 11.45 491.19 106132 106132 106132 11.46 490.91 106193 106193 106193 11.42 490.36 106255 106255 106255 11.5 490.23 106316 106316 106316 11.44 490.71 106439 106439 106439 11.54 490.79 106501 106501 106501 11.52 490.52 106562 106562 106562 11.44 490.71 106624 106624 106624 11.46 491.23 106685 106685 106685 11.63 492.48 106747 106747 106747 11.66 492.05 106808 106808 106808 11.65 491.33 106870 106870 106870 11.59 491.5 106931 106931 106931 11.58 491.31 107054 107054 107054 11.57 489.41 107116 107116 107116 11.61 490.6 107177 107177 107177 11.68 491.23 107239 107239 107239 11.66 490.27 107300 107300 107300 11.59 490.01 107362 107362 107362 11.53 491.45 107423 107423 107423 11.52 488.65 107485 107485 107485 11.53 489.27 107546 107546 107546 11.7 488.92 107669 107669 107669 11.58 487.53 107731 107731 107731 11.47 486.42 107792 107792 107792 11.41 486.76 107854 107854 107854 11.6 487.12 107915 107915 107915 11.49 486.31 107977 107977 107977 11.39 485.42 108038 108038 108038 11.24 484.16 108100 108100 108100 11.33 483.39 108161 108161 108161 11.29 482.33 108284 108284 108284 11.21 480.31 108346 108346 108346 11.28 480.27 108407 108407 108407 11.11 478.9 108469 108469 108469 11.13 480.6 108530 108530 108530 11.37 482.59 108592 108592 108592 11.23 478.21 108653 108653 108653 11.29 485.81 108715 108715 108715 11.49 485.3 108776 108776 108776 11.33 484.89 108899 108899 108899 11.21 481.72 108961 108961 108961 11.33 479.53 109022 109022 109022 11.35 483.19 109084 109084 109084 11.26 480.53 109145 109145 109145 11.26 482.5 109207 109207 109207 11.18 481.8 109268 109268 109268 11.39 481.92 109330 109330 109330 11.22 478.26 109391 109391 109391 11.28 480.89 109514 109514 109514 11.11 480.91 109576 109576 109576 11.16 479.92 109637 109637 109637 11.23 481.61 109699 109699 109699 11.11 481.59 109760 109760 109760 11.14 480.37 109822 109822 109822 11.14 481.96 109883 109883 109883 11.12 484.14 109945 109945 109945 11.28 485.31 110006 110006 110006 11.26 485.42 110129 110129 110129 11.2 485.14 110191 110191 110191 11.11 481.0 110252 110252 110252 11.27 486.39 110314 110314 110314 11.44 487.58 110375 110375 110375 11.42 484.65 110498 110498 110498 11.64 490.2 110560 110560 110560 11.52 484.49 110621 110621 110621 11.48 483.79 110744 110744 110744 11.41 479.62 110806 110806 110806 11.78 488.73 110867 110867 110867 11.8 488.44 110929 110929 110929 11.9 489.78 110990 110990 110990 11.68 489.57 111052 111052 111052 11.59 489.5 111113 111113 111113 11.65 491.25 111175 111175 111175 11.73 491.51 111236 111236 111236 11.75 488.98 111359 111359 111359 11.61 487.45 111421 111421 111421 11.73 486.74 111482 111482 111482 11.5 485.76 111544 111544 111544 11.56 487.81 111605 111605 111605 11.5 485.9 111667 111667 111667 11.49 485.58 111728 111728 111728 11.56 486.67 111790 111790 111790 11.38 486.31 111851 111851 111851 11.33 482.76 111974 111974 111974 11.36 485.59 112036 112036 112036 11.33 485.98 112097 112097 112097 11.54 487.21 112159 112159 112159 11.41 486.43 112220 112220 112220 11.49 485.33