45 1001 Markus Jesswein, Tanja Schuck, Andreas Engel Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Altenhoeferallee 1, 60438 Frankfurt/Main, Germany 1|HALO | GhOST-MS | mixing ratios of long-lived and very short-lived tracers measured with an in-situ GC-ECD instrument, integrated under usage of constant baseline PHILEAS 1 1 2023 09 10 2025 11 06 0 Mean sample time in UT seconds past midnight of flight date 4 1 1 1 1 99999 99999 99999 99999 Time_Start [s] Time_End [s] SF6 [ppt] CFC_12 [ppt] 25 ------------------------------------------------------------------------ Please inform the authors about the use of the data These are preliminary data and not for publication. Please adhere in all cases to the PHILEAS data protocol Contact: Andreas Engel (an.engel@iau.uni-frankfurt.de, phone +49 69 798 40259) ------------------------------------------------------------------------ Calibration Scale, Precision, Accuracy and Detection Limit are given separately for each dependent variable Primary calibration reference flasks: TO-Mutter (UEA scales), J-256 (AGAGE network) Calibration Scales SF6 CFC_12 SIO-05 SIO-05 ------------------------------------------------------------------------ Instrument precision in [%] NaN NaN NaN NaN NaN NAN NAN 0.9820 0.4140 Detection limit (S/N 3/1) in [ppt] per 100 mL air at STP NaN NaN NaN NaN NaN Values below detection limit are marked as 0.00 In case no measurements are available, the missing data value is used ------------------------------------------------------------------------ SF6 data non-linearity below measurement precision. no correction applied F12 mixing ratio data has been corrected for detector non-linearity by applying a second order polynom: k = a0 + a1 * mr_F12 + a2 * mr_F12^2 coefficients: a0 = -0.04257; a1 = 1.04244; a2 = 0.00013 ------------------------------------------------------------------------ 2 UTC Time_Start Time_End SF6 CFC_12 [s] [s] [s] [ppt] [ppt] 71970 71970 71970 11.58 488.22 72031 72031 72031 11.69 487.3 72093 72093 72093 11.84 487.77 72154 72154 72154 11.62 486.42 72216 72216 72216 11.62 485.36 72277 72277 72277 11.87 489.25 72339 72339 72339 11.92 489.52 72401 72401 72401 11.85 472.38 72524 72524 72524 12.03 493.02 72585 72585 72585 11.89 493.0 72647 72647 72647 12.01 491.93 72708 72708 72708 11.82 494.33 72770 72770 72770 11.9 489.24 72831 72831 72831 11.35 474.95 72893 72893 72893 11.2 467.97 72954 72954 72954 11.22 470.79 73016 73016 73016 11.15 468.22 73139 73139 73139 11.31 467.62 73200 73200 73200 11.09 468.78 73262 73262 73262 11.12 473.08 73323 73323 73323 11.43 482.02 73385 73385 73385 11.32 476.35 73446 73446 73446 11.17 467.41 73508 73508 73508 11.17 470.03 73569 73569 73569 11.23 475.96 73631 73631 73631 11.42 480.47 73754 73754 73754 11.48 484.06 73815 73815 73815 11.52 485.0 73877 73877 73877 11.66 489.64 73938 73938 73938 11.72 490.84 74000 74000 74000 11.57 492.14 74061 74061 74061 11.61 489.66 74123 74123 74123 11.6 489.78 74184 74184 74184 11.7 489.99 74246 74246 74246 11.55 491.26 74369 74369 74369 11.53 491.26 74430 74430 74430 11.49 488.63 74492 74492 74492 11.4 488.96 74553 74553 74553 11.46 490.12 74615 74615 74615 11.51 490.53 74676 74676 74676 11.59 489.93 74738 74738 74738 11.49 490.18 74799 74799 74799 11.49 488.29 74861 74861 74861 11.48 490.05 74984 74984 74984 11.63 490.04 75045 75045 75045 11.49 492.03 75107 75107 75107 11.38 491.79 75168 75168 75168 11.51 491.47 75230 75230 75230 11.64 491.32 75291 75291 75291 11.5 490.88 75353 75353 75353 11.53 492.04 75414 75414 75414 11.52 491.55 75476 75476 75476 11.57 490.79 75599 75599 75599 11.65 492.02 75660 75660 75660 11.53 490.77 75722 75722 75722 11.7 490.09 75783 75783 75783 11.58 493.48 75845 75845 75845 11.72 490.58 75906 75906 75906 11.5 489.21 75968 75968 75968 11.6 490.51 76029 76029 76029 11.61 488.76 76091 76091 76091 11.34 489.36 76214 76214 76214 11.44 488.8 76275 76275 76275 11.57 487.6 76337 76337 76337 11.42 487.0 76398 76398 76398 11.5 490.21 76460 76460 76460 11.63 490.57 76521 76521 76521 11.84 490.04 76583 76583 76583 11.49 489.35 76644 76644 76644 11.61 490.56 76706 76706 76706 11.61 489.82 76829 76829 76829 11.5 490.02 76890 76890 76890 11.55 488.15 76952 76952 76952 11.41 488.76 77013 77013 77013 11.39 488.86 77075 77075 77075 11.38 487.91 77136 77136 77136 11.42 489.23 77198 77198 77198 11.5 489.46 77259 77259 77259 11.51 489.07 77321 77321 77321 11.31 489.27 77444 77444 77444 11.36 488.43 77505 77505 77505 11.43 487.75 77567 77567 77567 11.37 487.33 77628 77628 77628 11.39 487.32 77690 77690 77690 11.3 487.78 77751 77751 77751 11.42 486.92 77813 77813 77813 11.52 488.42 77874 77874 77874 11.43 487.5 77936 77936 77936 11.47 487.18 78059 78059 78059 11.45 487.74 78120 78120 78120 11.49 488.77 78182 78182 78182 11.43 489.1 78243 78243 78243 11.43 487.27 78305 78305 78305 11.51 489.08 78366 78366 78366 11.55 488.62 78428 78428 78428 11.35 488.77 78489 78489 78489 11.49 488.26 78551 78551 78551 11.41 488.13 78674 78674 78674 11.52 489.76 78735 78735 78735 11.53 489.98 78797 78797 78797 11.45 490.45 78858 78858 78858 11.5 488.16 78920 78920 78920 11.47 486.79 78981 78981 78981 11.48 488.78 79043 79043 79043 11.47 488.17 79104 79104 79104 11.63 487.18 79166 79166 79166 11.49 489.35 79289 79289 79289 11.49 488.51 79350 79350 79350 11.44 487.27 79412 79412 79412 11.37 486.26 79473 79473 79473 11.47 488.5 79535 79535 79535 11.29 486.92 79596 79596 79596 11.35 486.78 79658 79658 79658 11.32 487.46 79719 79719 79719 11.34 487.66 79781 79781 79781 11.31 487.25 79904 79904 79904 11.33 489.01 79965 79965 79965 11.31 487.14 80027 80027 80027 11.23 488.12 80088 80088 80088 11.31 487.06 80150 80150 80150 11.42 487.27 80211 80211 80211 11.38 489.75 80273 80273 80273 11.45 488.45 80334 80334 80334 11.4 491.09 80396 80396 80396 11.44 491.56 80519 80519 80519 11.45 490.41 80580 80580 80580 11.54 491.54 80642 80642 80642 11.49 490.82 80703 80703 80703 11.57 489.86 80765 80765 80765 11.56 490.47 80826 80826 80826 11.56 490.21 80888 80888 80888 11.49 491.43 80949 80949 80949 11.54 490.04 81011 81011 81011 11.49 490.64 81134 81134 81134 11.54 489.14 81195 81195 81195 11.48 488.71 81257 81257 81257 11.46 489.1 81318 81318 81318 11.52 489.01 81380 81380 81380 11.58 487.69 81441 81441 81441 11.53 488.4 81503 81503 81503 11.48 488.71 81564 81564 81564 11.42 488.61 81626 81626 81626 11.38 488.05 81749 81749 81749 11.4 489.94 81810 81810 81810 11.37 490.72 81872 81872 81872 11.51 489.59 81933 81933 81933 11.37 488.11 81995 81995 81995 11.4 487.55 82056 82056 82056 11.43 489.48 82118 82118 82118 11.38 489.97 82179 82179 82179 11.42 492.68 82241 82241 82241 11.63 492.72 82364 82364 82364 11.39 490.84 82425 82425 82425 11.67 490.84 82487 82487 82487 11.43 492.09 82548 82548 82548 11.45 491.48 82610 82610 82610 11.55 490.84 82671 82671 82671 11.52 491.21 82733 82733 82733 11.5 491.57 82794 82794 82794 11.68 490.67 82856 82856 82856 11.5 491.54 82979 82979 82979 11.59 490.85 83040 83040 83040 11.54 490.31 83102 83102 83102 11.54 490.86 83163 83163 83163 11.54 489.64 83225 83225 83225 11.63 489.11 83286 83286 83286 11.61 490.81 83348 83348 83348 11.52 490.89 83409 83409 83409 11.53 490.35 83471 83471 83471 11.5 490.35 83594 83594 83594 11.6 492.24 83655 83655 83655 11.52 491.83 83717 83717 83717 11.44 491.14 83778 83778 83778 11.49 490.42 83840 83840 83840 11.46 492.0 83901 83901 83901 11.38 490.45 83963 83963 83963 11.62 491.41 84024 84024 84024 11.53 490.1 84086 84086 84086 11.58 489.91 84209 84209 84209 11.64 491.48 84270 84270 84270 11.57 492.33 84332 84332 84332 11.63 491.85 84393 84393 84393 11.5 493.86 84455 84455 84455 11.64 491.41 84516 84516 84516 11.62 491.98 84578 84578 84578 11.61 492.01 84639 84639 84639 11.69 491.13 84701 84701 84701 11.7 490.91 84824 84824 84824 11.53 491.38 84885 84885 84885 11.65 489.85 84947 84947 84947 11.49 489.83 85008 85008 85008 11.51 489.94 85070 85070 85070 11.71 489.11 85131 85131 85131 11.5 489.25 85193 85193 85193 11.44 488.58 85254 85254 85254 11.5 489.57 85316 85316 85316 11.5 491.57 85439 85439 85439 11.55 490.33 85500 85500 85500 11.52 490.13 85562 85562 85562 11.67 490.32 85623 85623 85623 11.56 491.82 85685 85685 85685 11.72 490.67 85746 85746 85746 11.6 488.74 85808 85808 85808 11.55 490.73 85869 85869 85869 11.54 489.77 85931 85931 85931 11.64 491.27 86054 86054 86054 11.56 490.7 86115 86115 86115 11.75 491.49 86177 86177 86177 11.6 490.88 86238 86238 86238 11.67 491.25 86300 86300 86300 11.7 492.18 86361 86361 86361 11.7 490.45 86423 86423 86423 11.59 491.97 86484 86484 86484 11.53 490.23 86546 86546 86546 11.64 490.74 86669 86669 86669 11.51 491.18 86730 86730 86730 11.74 491.87 86792 86792 86792 11.75 492.25 86853 86853 86853 11.66 490.63 86915 86915 86915 11.56 490.64 86976 86976 86976 11.6 489.25 87038 87038 87038 11.65 488.97 87099 87099 87099 11.66 490.86 87161 87161 87161 11.63 489.6 87284 87284 87284 11.75 488.56 87345 87345 87345 11.47 487.22 87407 87407 87407 11.44 488.0 87468 87468 87468 11.54 488.52 87530 87530 87530 11.54 487.74 87591 87591 87591 11.45 488.76 87653 87653 87653 11.44 487.65 87714 87714 87714 11.41 482.93 87776 87776 87776 11.3 482.78 87899 87899 87899 11.5 484.44 87960 87960 87960 11.44 485.32 88022 88022 88022 11.39 485.62 88083 88083 88083 11.53 488.81 88145 88145 88145 11.44 488.66 88206 88206 88206 11.57 487.73 88268 88268 88268 11.54 487.8 88329 88329 88329 11.56 485.92 88391 88391 88391 11.58 486.79 88514 88514 88514 11.58 486.62 88575 88575 88575 11.35 485.97 88637 88637 88637 11.45 484.59 88698 88698 88698 11.31 482.31 88760 88760 88760 11.26 478.48 88821 88821 88821 11.23 481.01 88883 88883 88883 11.33 478.8 88944 88944 88944 11.28 479.79 89006 89006 89006 11.27 480.04 89129 89129 89129 11.31 481.51 89190 89190 89190 11.32 479.99 89252 89252 89252 11.36 480.51 89313 89313 89313 11.16 479.15 89375 89375 89375 11.3 479.43 89436 89436 89436 11.24 479.05 89498 89498 89498 11.33 480.56 89559 89559 89559 11.25 479.94 89621 89621 89621 11.27 478.63 89744 89744 89744 11.26 478.65 89805 89805 89805 11.22 480.56 89867 89867 89867 11.49 481.18 89928 89928 89928 11.24 484.03 89990 89990 89990 11.38 483.92 90051 90051 90051 11.42 484.58 90113 90113 90113 11.24 485.91 90174 90174 90174 11.43 487.18 90236 90236 90236 11.42 489.28 90359 90359 90359 11.43 491.41 90420 90420 90420 11.51 490.66 90482 90482 90482 11.48 492.88 90543 90543 90543 11.46 491.77 90605 90605 90605 11.52 488.82 90666 90666 90666 11.58 489.65 90728 90728 90728 11.51 489.34 90789 90789 90789 11.55 489.28 90851 90851 90851 11.56 488.19 90974 90974 90974 11.54 487.1 91035 91035 91035 11.47 485.52 91097 91097 91097 11.39 484.25 91158 91158 91158 11.42 485.77 91220 91220 91220 11.41 489.73 91281 91281 91281 11.48 488.86 91343 91343 91343 11.49 489.79 91404 91404 91404 11.41 491.15 91466 91466 91466 11.51 490.42 91589 91589 91589 11.4 489.74 91650 91650 91650 11.42 488.47 91712 91712 91712 11.47 490.81 91773 91773 91773 11.38 490.72 91835 91835 91835 11.35 490.12 91896 91896 91896 11.5 489.77 91958 91958 91958 11.43 490.22 92019 92019 92019 11.55 491.88 92081 92081 92081 11.52 491.14 92204 92204 92204 11.53 489.49 92265 92265 92265 11.39 488.92 92327 92327 92327 11.52 489.86 92388 92388 92388 11.61 487.35 92450 92450 92450 11.4 488.57 92511 92511 92511 11.43 488.39 92573 92573 92573 11.43 486.67 92634 92634 92634 11.42 486.27 92696 92696 92696 11.24 485.33 92819 92819 92819 11.33 485.48 92880 92880 92880 11.36 485.11 92942 92942 92942 11.42 487.68 93003 93003 93003 11.42 486.97 93065 93065 93065 11.4 483.81 93126 93126 93126 11.27 485.05 93188 93188 93188 11.27 485.9 93249 93249 93249 11.44 485.9 93311 93311 93311 11.31 486.18 93434 93434 93434 11.33 485.32 93495 93495 93495 11.23 485.48 93557 93557 93557 11.18 486.46 93618 93618 93618 11.24 485.46 93680 93680 93680 11.28 481.7 93741 93741 93741 11.32 484.17 93803 93803 93803 11.4 482.74 93864 93864 93864 11.38 481.29 93926 93926 93926 11.34 480.72 94049 94049 94049 11.26 479.79 94110 94110 94110 11.34 478.67 94172 94172 94172 11.2 480.12 94233 94233 94233 11.32 479.32 94295 94295 94295 11.31 481.37 94356 94356 94356 11.21 479.29 94418 94418 94418 11.29 481.26 94479 94479 94479 11.4 481.34 94541 94541 94541 11.25 480.45 94664 94664 94664 11.34 480.03 94725 94725 94725 11.28 480.73 94787 94787 94787 11.35 482.69 94848 94848 94848 11.32 482.22 94910 94910 94910 11.24 481.73 94971 94971 94971 11.3 479.53 95033 95033 95033 11.16 477.11 95094 95094 95094 11.09 473.68 95156 95156 95156 11.17 471.85 95279 95279 95279 11.15 472.14 95340 95340 95340 11.02 471.22 95402 95402 95402 11.03 473.86 95463 95463 95463 11.04 473.14 95525 95525 95525 11.11 473.28 95586 95586 95586 11.11 472.24 95648 95648 95648 11.07 474.52 95709 95709 95709 11.17 473.27 95771 95771 95771 11.15 470.98 95894 95894 95894 10.98 465.1 95955 95955 95955 10.93 462.96 96017 96017 96017 10.97 463.99 96078 96078 96078 11.01 463.24 96140 96140 96140 11.01 465.9 96201 96201 96201 11.02 465.41 96263 96263 96263 10.97 466.78 96324 96324 96324 11.04 467.58 96386 96386 96386 11.01 464.63 96509 96509 96509 11.07 462.43 96570 96570 96570 11.09 462.05 96632 96632 96632 11.04 461.9 96693 96693 96693 10.99 465.19 96755 96755 96755 11.16 466.25 96816 96816 96816 11.2 467.44 96878 96878 96878 11.18 465.53 96939 96939 96939 11.27 464.07 97001 97001 97001 11.13 462.38 97124 97124 97124 11.15 464.0 97185 97185 97185 11.21 465.68 97247 97247 97247 11.22 464.38 97308 97308 97308 10.97 463.46 97370 97370 97370 11.06 462.55 97431 97431 97431 11.11 462.74 97493 97493 97493 11.02 463.78 97554 97554 97554 10.99 461.74 97616 97616 97616 10.87 461.95 97739 97739 97739 10.94 465.24 97800 97800 97800 10.91 464.68 97862 97862 97862 10.96 465.09 97923 97923 97923 10.97 466.06 97985 97985 97985 11.02 465.55 98046 98046 98046 11.12 465.03 98108 98108 98108 11.03 466.39 98169 98169 98169 10.96 465.91 98231 98231 98231 10.93 465.03 98354 98354 98354 11.0 463.98 98415 98415 98415 10.93 463.14 98477 98477 98477 11.01 463.15 98538 98538 98538 11.11 464.99 98600 98600 98600 10.99 464.33 98661 98661 98661 11.05 463.89 98723 98723 98723 11.03 464.59 98784 98784 98784 11.05 460.56 98846 98846 98846 11.04 459.07 98969 98969 98969 11.03 459.14 99030 99030 99030 11.01 457.98 99092 99092 99092 11.08 461.89 99153 99153 99153 11.04 462.46 99215 99215 99215 11.03 462.88 99276 99276 99276 11.03 462.86 99338 99338 99338 10.89 462.89 99399 99399 99399 11.03 463.14 99461 99461 99461 10.9 461.54 99584 99584 99584 11.01 460.14 99645 99645 99645 11.1 461.52 99707 99707 99707 11.0 461.56 99768 99768 99768 11.05 462.37 99830 99830 99830 11.17 463.86 99891 99891 99891 11.2 463.21 99953 99953 99953 11.2 463.58 100014 100014 100014 11.11 462.69 100076 100076 100076 11.17 462.43 100199 100199 100199 11.04 463.58 100260 100260 100260 10.95 462.03 100322 100322 100322 11.02 465.34 100383 100383 100383 11.09 467.23 100445 100445 100445 11.14 467.12 100506 100506 100506 11.07 463.16 100568 100568 100568 11.05 460.92 100629 100629 100629 11.24 478.0 100691 100691 100691 11.13 468.86 100814 100814 100814 11.28 478.3 100875 100875 100875 11.31 477.97 100937 100937 100937 11.3 476.8 100998 100998 100998 11.19 474.71 101060 101060 101060 11.44 477.4 101121 101121 101121 11.37 478.4 101183 101183 101183 11.35 476.66 101244 101244 101244 11.24 478.98 101306 101306 101306 11.52 479.57 101429 101429 101429 11.48 483.15 101490 101490 101490 11.4 484.62 101552 101552 101552 11.43 484.27 101613 101613 101613 11.45 483.28 101675 101675 101675 11.53 484.3 101736 101736 101736 11.42 484.81 101798 101798 101798 11.47 483.13 101860 101860 101860 11.46 482.61 101921 101921 101921 11.38 482.79 102044 102044 102044 11.42 483.75 102106 102106 102106 11.37 483.62 102167 102167 102167 11.4 484.56 102229 102229 102229 11.39 483.7 102290 102290 102290 11.48 482.73 102352 102352 102352 11.44 484.12 102413 102413 102413 11.43 484.24 102475 102475 102475 11.31 482.36 102536 102536 102536 11.28 483.96 102659 102659 102659 11.37 484.79 102721 102721 102721 11.4 487.89 102782 102782 102782 11.57 490.51 102844 102844 102844 11.41 490.76 102905 102905 102905 11.49 490.26 102967 102967 102967 11.61 489.78 103028 103028 103028 11.26 486.3 103090 103090 103090 11.47 488.5 103151 103151 103151 11.41 486.91 103274 103274 103274 11.42 485.81 103336 103336 103336 11.47 484.68 103397 103397 103397 11.69 486.45 103459 103459 103459 11.6 487.69 103520 103520 103520 11.54 481.85 103582 103582 103582 11.58 485.53 103643 103643 103643 11.56 486.22 103705 103705 103705 11.55 486.68 103766 103766 103766 11.57 488.25 103889 103889 103889 11.48 488.2 103951 103951 103951 11.59 484.92 104012 104012 104012 11.62 485.69 104074 104074 104074 11.59 485.41 104135 104135 104135 11.74 483.92 104197 104197 104197 11.5 485.36 104258 104258 104258 11.54 486.81 104320 104320 104320 11.7 486.72 104381 104381 104381 11.63 486.28 104504 104504 104504 11.6 485.27