45 1001 Markus Jesswein, Tanja Schuck, Andreas Engel Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Altenhoeferallee 1, 60438 Frankfurt/Main, Germany 1|HALO | GhOST-MS | mixing ratios of long-lived and very short-lived tracers measured with an in-situ GC-ECD instrument, integrated under usage of constant baseline PHILEAS 1 1 2023 09 09 2025 11 06 0 Mean sample time in UT seconds past midnight of flight date 4 1 1 1 1 99999 99999 99999 99999 Time_Start [s] Time_End [s] SF6 [ppt] CFC_12 [ppt] 25 ------------------------------------------------------------------------ Please inform the authors about the use of the data These are preliminary data and not for publication. Please adhere in all cases to the PHILEAS data protocol Contact: Andreas Engel (an.engel@iau.uni-frankfurt.de, phone +49 69 798 40259) ------------------------------------------------------------------------ Calibration Scale, Precision, Accuracy and Detection Limit are given separately for each dependent variable Primary calibration reference flasks: TO-Mutter (UEA scales), J-256 (AGAGE network) Calibration Scales SF6 CFC_12 SIO-05 SIO-05 ------------------------------------------------------------------------ Instrument precision in [%] NaN NaN NaN NaN NaN NAN NAN 0.8080 0.2570 Detection limit (S/N 3/1) in [ppt] per 100 mL air at STP NaN NaN NaN NaN NaN Values below detection limit are marked as 0.00 In case no measurements are available, the missing data value is used ------------------------------------------------------------------------ SF6 data non-linearity below measurement precision. no correction applied F12 mixing ratio data has been corrected for detector non-linearity by applying a second order polynom: k = a0 + a1 * mr_F12 + a2 * mr_F12^2 coefficients: a0 = -0.04257; a1 = 1.04244; a2 = 0.00013 ------------------------------------------------------------------------ 2 UTC Time_Start Time_End SF6 CFC_12 [s] [s] [s] [ppt] [ppt] 64994 64994 64994 11.58 486.99 65056 65056 65056 11.6 485.76 65117 65117 65117 11.65 484.46 65179 65179 65179 11.49 484.03 65240 65240 65240 11.59 484.78 65363 65363 65363 11.6 487.28 65425 65425 65425 11.47 488.31 65486 65486 65486 11.52 488.19 65548 65548 65548 11.7 488.21 65609 65609 65609 11.62 488.89 65671 65671 65671 11.55 486.64 65732 65732 65732 11.52 480.05 65794 65794 65794 11.18 476.48 65855 65855 65855 11.41 489.0 65978 65978 65978 11.56 489.66 66040 66040 66040 11.54 487.36 66101 66101 66101 11.5 484.13 66163 66163 66163 11.38 485.22 66224 66224 66224 11.28 485.09 66286 66286 66286 11.32 481.77 66347 66347 66347 11.34 479.56 66409 66409 66409 11.16 478.44 66470 66470 66470 11.09 477.35 66593 66593 66593 11.67 485.22 66655 66655 66655 11.53 486.36 66717 66717 66717 11.67 485.86 66778 66778 66778 11.81 487.44 66840 66840 66840 11.59 486.58 66901 66901 66901 11.64 485.41 66963 66963 66963 11.66 486.89 67086 67086 67086 11.74 485.76 67209 67209 67209 11.91 485.58 67271 67271 67271 11.73 485.98 67332 67332 67332 11.85 486.46 67394 67394 67394 11.76 485.02 67455 67455 67455 11.87 487.31 67517 67517 67517 11.92 487.05 67578 67578 67578 11.72 486.95 67640 67640 67640 11.69 486.35 67701 67701 67701 11.59 487.3 67824 67824 67824 11.63 484.25 67886 67886 67886 11.55 485.69 67947 67947 67947 11.46 485.94 68009 68009 68009 11.64 486.15 68070 68070 68070 11.78 488.22 68132 68132 68132 11.92 486.6 68193 68193 68193 11.83 488.53 68255 68255 68255 11.83 487.88 68316 68316 68316 12.0 487.71 68439 68439 68439 12.13 487.45 68501 68501 68501 11.76 489.03 68562 68562 68562 11.8 488.52 68624 68624 68624 11.9 488.33 68685 68685 68685 11.92 487.77 68747 68747 68747 11.99 488.72 68808 68808 68808 12.03 489.9 68870 68870 68870 11.99 489.67 68931 68931 68931 11.83 489.53 69054 69054 69054 11.96 489.1 69116 69116 69116 12.13 490.38 69177 69177 69177 11.95 489.84 69239 69239 69239 11.9 489.37 69300 69300 69300 11.94 489.87 69362 69362 69362 12.03 488.89 69423 69423 69423 11.86 488.67 69485 69485 69485 11.9 488.76 69546 69546 69546 11.89 488.0 69669 69669 69669 11.75 488.86 69731 69731 69731 11.73 487.55 69792 69792 69792 11.63 487.3 69854 69854 69854 11.53 488.71 69915 69915 69915 11.61 489.63 69977 69977 69977 11.67 487.64 70038 70038 70038 11.45 488.3 70100 70100 70100 11.69 488.98 70161 70161 70161 11.67 490.02 70284 70284 70284 11.46 487.54 70346 70346 70346 11.48 487.78 70407 70407 70407 11.5 488.38 70469 70469 70469 11.71 487.08 70530 70530 70530 11.49 487.66 70592 70592 70592 11.58 487.52 70653 70653 70653 11.5 487.28 70715 70715 70715 11.54 486.76 70776 70776 70776 11.44 487.09 70899 70899 70899 11.54 488.94 70961 70961 70961 11.63 485.58 71022 71022 71022 11.48 487.18 71084 71084 71084 11.49 489.59 71145 71145 71145 11.48 488.36 71207 71207 71207 11.53 489.2 71268 71268 71268 11.52 489.72 71330 71330 71330 11.46 488.48 71391 71391 71391 11.52 490.57 71514 71514 71514 11.61 489.7 71576 71576 71576 11.6 491.3 71637 71637 71637 11.45 489.49 71699 71699 71699 11.54 488.8 71760 71760 71760 11.5 490.93 71822 71822 71822 11.45 489.37 71883 71883 71883 11.46 490.2 71945 71945 71945 11.53 489.28 72006 72006 72006 11.45 488.66 72129 72129 72129 11.52 490.55 72191 72191 72191 11.58 489.64 72252 72252 72252 11.55 491.93 72314 72314 72314 11.58 491.54 72375 72375 72375 11.52 491.78 72437 72437 72437 11.68 489.33 72499 72499 72499 11.58 488.6 72560 72560 72560 11.57 488.77 72622 72622 72622 11.64 489.44 72745 72745 72745 11.6 490.11 72806 72806 72806 11.69 490.79 72868 72868 72868 11.78 491.35 72929 72929 72929 11.66 489.92 72991 72991 72991 11.64 490.43 73052 73052 73052 11.57 489.7 73114 73114 73114 11.56 491.61 73175 73175 73175 11.77 490.18 73237 73237 73237 11.79 490.08 73360 73360 73360 11.78 489.25 73421 73421 73421 11.61 489.4 73483 73483 73483 11.77 488.85 73544 73544 73544 11.54 488.96 73606 73606 73606 11.61 488.56 73667 73667 73667 11.62 490.99 73729 73729 73729 11.54 489.15 73790 73790 73790 11.59 490.41 73852 73852 73852 11.63 489.76 73975 73975 73975 11.49 483.95 74036 74036 74036 11.43 486.86 74098 74098 74098 11.5 488.87 74159 74159 74159 11.5 490.65 74221 74221 74221 11.52 489.91 74282 74282 74282 11.64 491.32 74344 74344 74344 11.61 489.77 74405 74405 74405 11.48 490.02 74467 74467 74467 11.48 490.13 74590 74590 74590 11.7 491.08 74651 74651 74651 11.61 490.34 74713 74713 74713 11.52 490.79 74774 74774 74774 11.53 490.99 74836 74836 74836 11.52 490.23 74897 74897 74897 11.47 489.47 74959 74959 74959 11.52 490.6 75020 75020 75020 11.4 488.93 75082 75082 75082 11.58 490.8 75205 75205 75205 11.51 490.67 75266 75266 75266 11.66 490.4 75328 75328 75328 11.59 490.83 75389 75389 75389 11.47 490.45 75451 75451 75451 11.49 490.52 75512 75512 75512 11.66 491.62 75574 75574 75574 11.57 492.46 75635 75635 75635 11.53 492.29 75697 75697 75697 11.5 491.55 75820 75820 75820 11.72 491.83 75881 75881 75881 11.6 492.55 75943 75943 75943 11.51 492.15 76004 76004 76004 11.63 490.69 76066 76066 76066 11.6 491.27 76127 76127 76127 11.62 493.41 76189 76189 76189 11.53 492.1 76250 76250 76250 11.68 492.3 76312 76312 76312 11.53 492.76 76435 76435 76435 11.61 492.96 76496 76496 76496 11.62 493.39 76558 76558 76558 11.62 492.18 76619 76619 76619 11.69 493.87 76681 76681 76681 11.68 493.43 76742 76742 76742 11.76 493.27 76804 76804 76804 11.62 492.79 76865 76865 76865 11.58 493.03 76927 76927 76927 11.65 492.92 77050 77050 77050 11.71 494.06 77111 77111 77111 11.69 491.35 77173 77173 77173 11.64 491.99 77234 77234 77234 11.7 491.2 77296 77296 77296 11.61 491.2 77357 77357 77357 11.61 489.11 77419 77419 77419 11.65 490.35 77480 77480 77480 11.66 490.97 77542 77542 77542 11.7 489.74 77665 77665 77665 11.74 491.21 77726 77726 77726 11.63 490.86 77788 77788 77788 11.6 491.56 77849 77849 77849 11.63 490.93 77911 77911 77911 11.62 493.71 77972 77972 77972 11.65 491.61 78034 78034 78034 11.54 493.03 78095 78095 78095 11.66 492.5 78157 78157 78157 11.81 491.38 78280 78280 78280 11.63 493.28 78341 78341 78341 11.68 493.28 78403 78403 78403 11.59 493.6 78464 78464 78464 11.66 493.36 78526 78526 78526 11.6 492.39 78587 78587 78587 11.56 493.77 78649 78649 78649 11.65 494.07 78710 78710 78710 11.63 493.64 78772 78772 78772 11.61 493.24 78895 78895 78895 11.53 494.08 78956 78956 78956 11.73 492.76 79018 79018 79018 11.59 494.02 79079 79079 79079 11.53 492.67 79141 79141 79141 11.59 494.01 79202 79202 79202 11.57 493.54 79264 79264 79264 11.53 493.83 79325 79325 79325 11.47 493.8 79387 79387 79387 11.53 493.97 79510 79510 79510 11.56 492.96 79571 79571 79571 11.67 492.64 79633 79633 79633 11.56 491.98 79694 79694 79694 11.5 492.39 79756 79756 79756 11.5 492.68 79817 79817 79817 11.66 493.96 79879 79879 79879 11.51 493.76 79940 79940 79940 11.6 492.1 80002 80002 80002 11.42 490.5 80125 80125 80125 11.52 491.13 80186 80186 80186 11.58 491.47 80248 80248 80248 11.54 492.26 80309 80309 80309 11.56 491.1 80371 80371 80371 11.38 492.26 80432 80432 80432 11.51 492.2 80494 80494 80494 11.7 492.03 80555 80555 80555 11.65 490.03 80617 80617 80617 11.69 490.65 80740 80740 80740 11.63 494.05 80801 80801 80801 11.56 490.77 80863 80863 80863 11.6 491.82 80924 80924 80924 11.64 491.43 80986 80986 80986 11.57 490.33 81047 81047 81047 11.66 490.82 81109 81109 81109 11.5 491.87 81170 81170 81170 11.38 481.46 81232 81232 81232 11.53 484.74 81355 81355 81355 11.55 489.38 81417 81417 81417 11.51 489.63 81478 81478 81478 11.7 491.47 81540 81540 81540 11.51 489.64 81601 81601 81601 11.55 491.03 81663 81663 81663 11.54 492.97 81724 81724 81724 11.55 492.97 81786 81786 81786 11.62 491.75 81847 81847 81847 11.47 492.12 81970 81970 81970 11.72 493.72 82032 82032 82032 11.67 493.86 82093 82093 82093 11.68 492.27 82155 82155 82155 11.6 492.75 82216 82216 82216 11.68 492.08 82278 82278 82278 11.81 492.37 82339 82339 82339 11.57 492.23 82401 82401 82401 11.62 491.53 82462 82462 82462 11.8 492.52 82585 82585 82585 11.74 490.85 82647 82647 82647 11.51 490.74 82708 82708 82708 11.74 491.86 82770 82770 82770 11.77 491.91 82831 82831 82831 11.66 491.17 82893 82893 82893 11.72 492.17 82954 82954 82954 11.49 490.55 83016 83016 83016 11.54 492.13 83077 83077 83077 11.77 490.79 83200 83200 83200 11.59 492.94 83262 83262 83262 11.42 491.98 83323 83323 83323 11.5 491.64 83385 83385 83385 11.62 493.38 83446 83446 83446 11.49 491.31 83508 83508 83508 11.46 492.09 83569 83569 83569 11.57 491.01 83631 83631 83631 11.44 490.8 83692 83692 83692 11.56 491.57 83815 83815 83815 11.44 490.44 83877 83877 83877 11.5 490.96 83938 83938 83938 11.44 490.31 84000 84000 84000 11.75 490.58 84061 84061 84061 11.32 490.15 84123 84123 84123 11.43 491.16 84184 84184 84184 11.49 491.23 84246 84246 84246 11.35 490.72 84307 84307 84307 11.38 491.5 84430 84430 84430 11.35 491.68 84492 84492 84492 11.26 491.37 84553 84553 84553 11.32 490.48 84615 84615 84615 11.37 489.77 84676 84676 84676 11.54 491.77 84738 84738 84738 11.56 490.0 84799 84799 84799 11.37 488.3 84861 84861 84861 11.32 490.05 84922 84922 84922 11.55 489.5 85045 85045 85045 11.38 490.23 85107 85107 85107 11.42 490.7 85168 85168 85168 11.38 490.44 85230 85230 85230 11.47 491.05 85291 85291 85291 11.44 489.39 85353 85353 85353 11.49 491.74 85414 85414 85414 11.44 492.62 85476 85476 85476 11.46 489.91 85537 85537 85537 11.45 490.9 85660 85660 85660 11.56 491.28 85722 85722 85722 11.49 489.52 85783 85783 85783 11.45 489.19 85845 85845 85845 11.62 488.5 85906 85906 85906 11.37 487.64 85968 85968 85968 11.52 488.74 86029 86029 86029 11.38 485.98 86091 86091 86091 11.37 487.11 86152 86152 86152 11.48 485.22 86275 86275 86275 11.48 484.88 86337 86337 86337 11.42 484.22 86398 86398 86398 11.38 486.98 86460 86460 86460 11.39 485.8 86521 86521 86521 11.38 483.26 86583 86583 86583 11.23 480.56 86644 86644 86644 11.19 475.97 86706 86706 86706 11.47 487.64 86767 86767 86767 11.35 486.25 86890 86890 86890 11.34 482.9 86952 86952 86952 11.33 481.64 87013 87013 87013 11.2 482.88 87075 87075 87075 11.38 483.36 87136 87136 87136 11.17 484.48 87198 87198 87198 11.35 484.0 87259 87259 87259 11.34 484.3 87321 87321 87321 11.37 485.48 87382 87382 87382 11.5 486.72 87505 87505 87505 11.29 477.37 87567 87567 87567 11.36 482.74 87628 87628 87628 11.37 482.57 87690 87690 87690 11.42 483.89 87751 87751 87751 11.5 484.86 87813 87813 87813 11.33 485.16 87874 87874 87874 11.56 487.39 87936 87936 87936 11.46 489.82 87997 87997 87997 11.44 488.32 88120 88120 88120 11.54 489.17 88182 88182 88182 11.72 491.75 88243 88243 88243 11.62 489.83 88305 88305 88305 11.52 489.73 88366 88366 88366 11.53 489.99 88428 88428 88428 11.53 489.8 88489 88489 88489 11.55 490.49 88551 88551 88551 11.36 491.49 88612 88612 88612 11.49 489.95 88735 88735 88735 11.5 491.57 88797 88797 88797 11.52 490.54 88858 88858 88858 11.53 490.62 88920 88920 88920 11.47 489.36 88981 88981 88981 11.44 488.61 89043 89043 89043 11.45 490.49 89104 89104 89104 11.51 490.95 89166 89166 89166 11.51 489.61 89227 89227 89227 11.44 490.28 89350 89350 89350 11.51 490.85 89412 89412 89412 11.46 491.63 89473 89473 89473 11.54 489.69 89535 89535 89535 11.5 490.75 89596 89596 89596 11.44 489.93 89658 89658 89658 11.55 491.24 89719 89719 89719 11.48 491.6 89781 89781 89781 11.58 491.09 89842 89842 89842 11.51 491.72 89965 89965 89965 11.67 491.32 90027 90027 90027 11.62 490.19 90088 90088 90088 11.72 491.4 90150 90150 90150 11.57 489.87 90211 90211 90211 11.64 489.77 90273 90273 90273 11.6 490.73 90334 90334 90334 11.73 491.24 90396 90396 90396 11.55 490.35 90457 90457 90457 11.63 491.6 90581 90581 90581 11.68 489.76 90642 90642 90642 11.64 489.56 90704 90704 90704 11.52 490.0 90765 90765 90765 11.57 490.1 90827 90827 90827 11.68 490.9 90888 90888 90888 11.64 488.48 90950 90950 90950 11.55 490.64 91012 91012 91012 11.68 489.61 91073 91073 91073 11.58 488.91 91196 91196 91196 11.59 490.01 91258 91258 91258 11.58 489.5 91319 91319 91319 11.45 490.99 91381 91381 91381 11.67 492.09 91442 91442 91442 11.59 491.09 91504 91504 91504 11.56 491.59 91565 91565 91565 11.56 491.03 91627 91627 91627 11.5 490.48 91689 91689 91689 11.51 490.52 91812 91812 91812 11.36 486.96 91873 91873 91873 11.43 485.24 91935 91935 91935 11.45 486.75 91996 91996 91996 11.36 485.31 92058 92058 92058 11.4 484.55 92119 92119 92119 11.22 481.43 92181 92181 92181 11.25 473.95 92242 92242 92242 11.32 480.27 92304 92304 92304 11.46 487.79 92427 92427 92427 11.36 480.19 92488 92488 92488 11.25 471.86 92550 92550 92550 11.28 471.67 92611 92611 92611 11.35 471.3 92673 92673 92673 11.13 467.83 92734 92734 92734 11.02 464.56 92796 92796 92796 11.16 465.08 92857 92857 92857 11.06 461.16 92919 92919 92919 10.99 459.11 93042 93042 93042 11.12 461.03 93103 93103 93103 11.08 458.5 93165 93165 93165 11.01 458.6 93226 93226 93226 11.02 456.13 93288 93288 93288 11.15 464.42 93349 93349 93349 10.96 461.96 93411 93411 93411 11.12 460.81 93472 93472 93472 11.02 466.02 93534 93534 93534 11.41 464.04 93657 93657 93657 11.15 465.6 93718 93718 93718 11.03 462.66 93780 93780 93780 11.06 461.43 93841 93841 93841 11.04 460.8 93903 93903 93903 11.1 464.26 93964 93964 93964 11.25 461.91 94026 94026 94026 11.05 462.22 94087 94087 94087 11.08 455.92 94149 94149 94149 11.03 451.41 94272 94272 94272 11.02 449.7 94333 94333 94333 10.97 449.79 94395 94395 94395 11.09 449.24 94456 94456 94456 11.1 448.77 94518 94518 94518 10.84 449.08 94579 94579 94579 10.9 448.62 94641 94641 94641 10.89 448.41 94703 94703 94703 10.86 448.01 94764 94764 94764 10.9 449.89 94887 94887 94887 10.82 450.39 94949 94949 94949 10.92 452.44 95010 95010 95010 10.78 451.14 95072 95072 95072 11.02 462.73 95133 95133 95133 11.14 472.69 95195 95195 95195 11.18 470.19 95257 95257 95257 11.13 467.2 95318 95318 95318 11.12 467.1 95380 95380 95380 11.01 469.53 95503 95503 95503 11.48 474.4 95564 95564 95564 11.7 487.81 95687 95687 95687 11.55 489.75 95749 95749 95749 11.68 491.39 95811 95811 95811 11.56 490.01 95872 95872 95872 11.65 485.96 95934 95934 95934 11.79 488.56 95995 95995 95995 11.54 489.71 96118 96118 96118 11.61 488.74 96180 96180 96180 11.53 488.15 96241 96241 96241 11.57 489.45 96303 96303 96303 11.6 488.3 96364 96364 96364 11.5 484.71 96426 96426 96426 11.44 487.36 96487 96487 96487 11.68 485.16 96549 96549 96549 11.48 485.73 96610 96610 96610 11.44 483.59 96734 96734 96734 11.44 483.13 96795 96795 96795 11.36 483.42 96857 96857 96857 11.4 484.85 96918 96918 96918 11.45 481.98 96980 96980 96980 11.81 482.76 97042 97042 97042 11.56 484.57 97103 97103 97103 11.54 485.38 97165 97165 97165 11.63 486.29 97226 97226 97226 11.51 484.74 97350 97350 97350 11.51 484.53 97411 97411 97411 11.48 487.56 97473 97473 97473 11.53 487.28