45 1001 Markus Jesswein, Tanja Schuck, Andreas Engel Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Altenhoeferallee 1, 60438 Frankfurt/Main, Germany 1|HALO | GhOST-MS | mixing ratios of long-lived and very short-lived tracers measured with an in-situ GC-ECD instrument, integrated under usage of constant baseline PHILEAS 1 1 2023 09 01 2025 11 06 0 Mean sample time in UT seconds past midnight of flight date 4 1 1 1 1 99999 99999 99999 99999 Time_Start [s] Time_End [s] SF6 [ppt] CFC_12 [ppt] 25 ------------------------------------------------------------------------ Please inform the authors about the use of the data These are preliminary data and not for publication. Please adhere in all cases to the PHILEAS data protocol Contact: Andreas Engel (an.engel@iau.uni-frankfurt.de, phone +49 69 798 40259) ------------------------------------------------------------------------ Calibration Scale, Precision, Accuracy and Detection Limit are given separately for each dependent variable Primary calibration reference flasks: TO-Mutter (UEA scales), J-256 (AGAGE network) Calibration Scales SF6 CFC_12 SIO-05 SIO-05 ------------------------------------------------------------------------ Instrument precision in [%] NaN NaN NaN NaN NaN NAN NAN 0.4373 0.1987 Detection limit (S/N 3/1) in [ppt] per 100 mL air at STP NaN NaN NaN NaN NaN Values below detection limit are marked as 0.00 In case no measurements are available, the missing data value is used ------------------------------------------------------------------------ SF6 data non-linearity below measurement precision. no correction applied F12 mixing ratio data has been corrected for detector non-linearity by applying a second order polynom: k = a0 + a1 * mr_F12 + a2 * mr_F12^2 coefficients: a0 = -0.04257; a1 = 1.04244; a2 = 0.00013 ------------------------------------------------------------------------ 2 UTC Time_Start Time_End SF6 CFC_12 [s] [s] [s] [ppt] [ppt] 76615 76615 76615 11.54 484.55 76677 76677 76677 11.49 485.89 76738 76738 76738 11.6 483.99 76800 76800 76800 11.56 486.78 76862 76862 76862 11.7 484.08 76985 76985 76985 11.63 487.13 77046 77046 77046 11.67 485.14 77108 77108 77108 11.7 486.29 77169 77169 77169 11.74 487.75 77231 77231 77231 11.64 486.65 77292 77292 77292 11.74 490.42 77354 77354 77354 11.72 486.77 77415 77415 77415 11.72 487.26 77477 77477 77477 11.66 489.51 77600 77600 77600 11.59 487.17 77661 77661 77661 11.3 469.45 77723 77723 77723 11.13 469.79 77784 77784 77784 11.14 468.7 77846 77846 77846 11.09 470.38 77908 77908 77908 11.1 469.44 77969 77969 77969 11.11 472.64 78031 78031 78031 11.09 467.53 78092 78092 78092 11.04 467.41 78216 78216 78216 11.02 471.78 78277 78277 78277 11.14 472.41 78462 78462 78462 11.23 470.54 78524 78524 78524 11.0 469.54 78585 78585 78585 11.1 471.46 78647 78647 78647 11.06 471.84 78709 78709 78709 11.02 470.85 78832 78832 78832 11.14 470.42 78893 78893 78893 10.99 471.62 78955 78955 78955 11.12 472.26 79017 79017 79017 11.1 470.47 79079 79079 79079 11.12 471.69 79140 79140 79140 11.21 473.96 79202 79202 79202 11.2 471.77 79264 79264 79264 11.12 472.26 79325 79325 79325 11.22 473.86 79448 79448 79448 11.11 471.6 79510 79510 79510 11.15 472.27 79572 79572 79572 11.14 469.9 79633 79633 79633 11.12 471.7 79695 79695 79695 11.13 473.89 79756 79756 79756 11.17 472.81 79818 79818 79818 11.28 472.4 79879 79879 79879 11.07 472.59 79941 79941 79941 11.09 471.94 80064 80064 80064 11.17 471.9 80126 80126 80126 11.23 471.39 80187 80187 80187 11.17 467.84 80249 80249 80249 11.1 468.22 80310 80310 80310 11.09 471.96 80372 80372 80372 11.17 469.89 80433 80433 80433 11.06 470.79 80495 80495 80495 11.11 470.44 80556 80556 80556 11.13 468.99 80679 80679 80679 11.1 470.31 80741 80741 80741 11.22 469.86 80802 80802 80802 11.23 469.64 80864 80864 80864 11.29 470.15 80925 80925 80925 11.2 470.0 80987 80987 80987 11.03 470.44 81048 81048 81048 11.13 471.55 81110 81110 81110 11.1 469.6 81171 81171 81171 11.16 469.14 81294 81294 81294 11.04 470.79 81356 81356 81356 11.27 470.84 81417 81417 81417 11.22 472.34 81479 81479 81479 11.15 471.31 81540 81540 81540 11.11 470.3 81602 81602 81602 11.19 471.95 81663 81663 81663 11.22 470.83 81725 81725 81725 10.95 463.72 81786 81786 81786 11.18 469.82 81910 81910 81910 11.15 469.46 81971 81971 81971 11.18 470.63 82033 82033 82033 11.2 471.26 82095 82095 82095 11.05 470.33 82156 82156 82156 11.11 472.32 82218 82218 82218 11.07 470.14 82279 82279 82279 11.04 469.6 82341 82341 82341 11.01 468.43 82402 82402 82402 11.14 472.69 82525 82525 82525 11.17 472.52 82587 82587 82587 11.18 472.63 82648 82648 82648 11.14 470.88 82710 82710 82710 11.17 470.42 82772 82772 82772 11.24 473.98 82833 82833 82833 11.16 468.29 82895 82895 82895 11.11 466.11 82956 82956 82956 10.96 466.25 83018 83018 83018 11.09 464.1 83141 83141 83141 11.1 464.53 83202 83202 83202 11.0 465.61 83264 83264 83264 11.1 467.86 83325 83325 83325 11.03 463.77 83387 83387 83387 10.96 462.47 83449 83449 83449 11.2 461.9 83510 83510 83510 10.94 463.14 83572 83572 83572 11.03 462.25 83634 83634 83634 11.15 462.06 83757 83757 83757 10.88 462.68 83819 83819 83819 10.93 463.64 83880 83880 83880 11.04 462.84 83942 83942 83942 10.96 465.42 84003 84003 84003 10.97 468.41 84065 84065 84065 11.06 468.27 84126 84126 84126 11.14 468.92 84188 84188 84188 11.09 469.69 84249 84249 84249 10.98 471.02 84372 84372 84372 11.1 471.1 84434 84434 84434 11.1 472.36 84495 84495 84495 11.18 472.06 84557 84557 84557 11.2 473.09 84618 84618 84618 11.09 473.25 84680 84680 84680 11.21 475.38 84741 84741 84741 11.19 473.52 84803 84803 84803 11.43 474.76 84864 84864 84864 11.2 478.33 84987 84987 84987 11.21 477.52 85049 85049 85049 11.36 480.26 85110 85110 85110 11.22 480.56 85172 85172 85172 11.41 483.45 85233 85233 85233 11.22 482.97 85295 85295 85295 11.31 483.0 85356 85356 85356 11.37 482.85 85418 85418 85418 11.3 483.22 85479 85479 85479 11.32 482.99 85603 85603 85603 11.53 484.67 85664 85664 85664 11.48 484.52 85726 85726 85726 11.41 486.54 85788 85788 85788 11.41 486.3 85849 85849 85849 11.46 486.42 85911 85911 85911 11.27 483.96 85972 85972 85972 11.35 485.76 86034 86034 86034 11.58 486.07 86095 86095 86095 11.42 487.88 86218 86218 86218 11.38 487.41 86280 86280 86280 11.55 487.43 86341 86341 86341 11.47 488.12 86403 86403 86403 11.59 489.29 86465 86465 86465 11.64 488.77 86526 86526 86526 11.6 490.19 86588 86588 86588 11.63 488.24 86649 86649 86649 11.35 487.7 86711 86711 86711 11.55 488.78 86834 86834 86834 11.36 489.89 86896 86896 86896 11.57 485.27 86957 86957 86957 11.49 488.41 87019 87019 87019 11.57 487.59 87080 87080 87080 11.54 486.66 87142 87142 87142 11.43 485.74 87204 87204 87204 11.37 487.19 87265 87265 87265 11.45 486.24 87327 87327 87327 11.35 486.97 87450 87450 87450 11.37 487.05 87512 87512 87512 11.52 489.21 87574 87574 87574 11.36 488.51 87636 87636 87636 11.51 490.82 87697 87697 87697 11.55 491.07 87759 87759 87759 11.55 489.93 87821 87821 87821 11.67 491.19 87882 87882 87882 11.62 491.87 87944 87944 87944 11.78 490.26 88067 88067 88067 11.63 490.02 88128 88128 88128 11.5 492.03 88190 88190 88190 11.61 491.3 88251 88251 88251 11.71 491.63 88313 88313 88313 11.62 489.59 88374 88374 88374 11.76 489.78 88436 88436 88436 11.62 489.71 88497 88497 88497 11.59 490.23 88559 88559 88559 11.57 489.09 88682 88682 88682 11.43 489.67 88743 88743 88743 11.7 488.36 88805 88805 88805 11.48 488.53 88866 88866 88866 11.49 488.64 88928 88928 88928 11.54 489.05 88989 88989 88989 11.66 490.0 89051 89051 89051 11.72 491.22 89112 89112 89112 11.76 491.29 89174 89174 89174 11.64 491.35 89297 89297 89297 11.66 491.25 89358 89358 89358 11.62 490.9 89420 89420 89420 11.54 492.59 89481 89481 89481 11.66 490.51 89543 89543 89543 11.63 492.06 89605 89605 89605 11.6 491.97 89666 89666 89666 11.55 492.6 89728 89728 89728 11.54 492.83 89789 89789 89789 11.43 490.48 89912 89912 89912 11.5 489.96 89974 89974 89974 11.5 490.23 90036 90036 90036 11.51 488.93 90097 90097 90097 11.44 489.09 90159 90159 90159 11.51 489.12 90220 90220 90220 11.49 487.42 90282 90282 90282 11.52 487.83 90344 90344 90344 11.63 484.71 90405 90405 90405 11.49 487.17 90529 90529 90529 11.54 486.18 90591 90591 90591 11.45 486.74 90652 90652 90652 11.39 485.72 90714 90714 90714 11.65 488.75 90776 90776 90776 11.57 486.46 90838 90838 90838 11.39 486.96 90899 90899 90899 11.41 486.63 90961 90961 90961 11.54 488.41 91023 91023 91023 11.59 487.81 91146 91146 91146 11.54 490.62 91208 91208 91208 11.44 490.62 91270 91270 91270 11.65 490.17 91331 91331 91331 11.62 490.26 91393 91393 91393 11.74 490.24 91454 91454 91454 11.65 491.17 91516 91516 91516 11.75 492.42 91577 91577 91577 11.74 491.03 91639 91639 91639 11.67 491.17 91762 91762 91762 11.61 490.82 91824 91824 91824 11.76 490.39 91886 91886 91886 11.56 492.25 91947 91947 91947 11.59 491.79 92009 92009 92009 11.72 491.66 92070 92070 92070 11.69 489.92 92132 92132 92132 11.61 491.28 92193 92193 92193 11.59 490.19 92255 92255 92255 11.54 490.92 92378 92378 92378 11.45 490.69 92439 92439 92439 11.7 492.27 92501 92501 92501 11.55 488.73 92562 92562 92562 11.71 489.74 92624 92624 92624 11.57 488.88 92686 92686 92686 11.55 490.02 92747 92747 92747 11.48 487.85 92809 92809 92809 11.48 487.37 92871 92871 92871 11.54 489.54 92994 92994 92994 11.6 490.73 93056 93056 93056 11.58 490.23 93117 93117 93117 11.47 489.44 93179 93179 93179 11.47 490.67 93240 93240 93240 11.61 490.15 93302 93302 93302 11.63 490.11 93363 93363 93363 11.51 493.54 93425 93425 93425 11.49 492.68 93486 93486 93486 11.63 491.83 93609 93609 93609 11.6 490.64 93671 93671 93671 11.56 490.32 93732 93732 93732 11.61 489.99 93794 93794 93794 11.48 489.78 93855 93855 93855 11.6 487.36 93917 93917 93917 11.49 489.56 93979 93979 93979 11.54 490.05 94040 94040 94040 11.7 489.89 94102 94102 94102 11.67 490.58 94226 94226 94226 11.62 490.45 94287 94287 94287 11.68 490.32 94349 94349 94349 11.78 489.6 94410 94410 94410 11.67 490.51 94472 94472 94472 11.58 489.3 94533 94533 94533 11.45 485.17 94595 94595 94595 11.44 488.82 94657 94657 94657 11.55 487.79 94718 94718 94718 11.68 490.84 94842 94842 94842 11.58 489.62 94903 94903 94903 11.54 489.66 94965 94965 94965 11.42 488.03 95027 95027 95027 11.54 486.26 95088 95088 95088 11.56 489.3 95150 95150 95150 11.7 491.66 95211 95211 95211 11.63 491.1 95273 95273 95273 11.66 493.2 95334 95334 95334 11.61 491.79 95457 95457 95457 11.59 491.88 95519 95519 95519 11.56 491.67 95580 95580 95580 11.64 491.27 95642 95642 95642 11.59 489.97 95703 95703 95703 11.59 492.38 95765 95765 95765 11.57 489.36 95826 95826 95826 11.32 483.25 95888 95888 95888 11.36 482.84 95950 95950 95950 11.45 484.97 96073 96073 96073 11.53 490.36 96134 96134 96134 11.49 488.41 96196 96196 96196 11.44 489.1 96258 96258 96258 11.45 488.42 96319 96319 96319 11.52 489.81 96381 96381 96381 11.52 489.03 96443 96443 96443 11.47 488.75 96504 96504 96504 11.51 487.86 96566 96566 96566 11.56 488.46 96689 96689 96689 11.55 489.28 96751 96751 96751 11.5 489.61 96812 96812 96812 11.65 490.3 96874 96874 96874 11.56 488.49 96935 96935 96935 11.59 487.37 96997 96997 96997 11.5 485.94 97058 97058 97058 11.41 483.46 97120 97120 97120 11.34 482.68 97181 97181 97181 11.37 484.69 97304 97304 97304 11.42 485.97 97366 97366 97366 11.32 485.54 97427 97427 97427 11.25 477.0 97489 97489 97489 11.07 472.41 97550 97550 97550 11.26 476.26 97612 97612 97612 11.21 473.62 97673 97673 97673 11.15 472.15 97735 97735 97735 11.2 466.64 97796 97796 97796 11.33 466.69 97919 97919 97919 10.97 465.52 97981 97981 97981 11.2 462.65 98043 98043 98043 11.13 460.26 98104 98104 98104 11.26 465.27 98166 98166 98166 11.28 469.59 98228 98228 98228 11.2 473.73 98290 98290 98290 11.32 474.08 98351 98351 98351 11.16 464.65 98598 98598 98598 11.48 480.85 98660 98660 98660 11.66 490.55 98722 98722 98722 11.65 490.04 98783 98783 98783 11.66 490.51 98845 98845 98845 11.61 489.92 98907 98907 98907 11.65 490.57 98968 98968 98968 11.43 490.6 99030 99030 99030 11.59 491.18 99153 99153 99153 11.5 489.41 99215 99215 99215 11.5 489.18 99277 99277 99277 11.64 490.41 99338 99338 99338 11.62 488.74 99400 99400 99400 11.6 490.88 99462 99462 99462 11.83 489.38 99523 99523 99523 11.58 489.95 99585 99585 99585 11.53 487.48 99646 99646 99646 11.48 488.08 99770 99770 99770 11.65 486.49 99831 99831 99831 11.49 487.69 99893 99893 99893 11.47 485.0 99955 99955 99955 11.46 486.52 100016 100016 100016 11.54 485.59 100078 100078 100078 11.51 485.94 100140 100140 100140 11.41 484.76 100202 100202 100202 11.49 485.29 100263 100263 100263 11.42 484.18