45 1001 Markus Jesswein, Tanja Schuck, Andreas Engel Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Altenhoeferallee 1, 60438 Frankfurt/Main, Germany 1|HALO | GhOST-MS | mixing ratios of long-lived and very short-lived tracers measured with an in-situ GC-ECD instrument, integrated under usage of constant baseline PHILEAS 1 1 2023 08 28 2025 11 06 0 Mean sample time in UT seconds past midnight of flight date 4 1 1 1 1 99999 99999 99999 99999 Time_Start [s] Time_End [s] SF6 [ppt] CFC_12 [ppt] 25 ------------------------------------------------------------------------ Please inform the authors about the use of the data These are preliminary data and not for publication. Please adhere in all cases to the PHILEAS data protocol Contact: Andreas Engel (an.engel@iau.uni-frankfurt.de, phone +49 69 798 40259) ------------------------------------------------------------------------ Calibration Scale, Precision, Accuracy and Detection Limit are given separately for each dependent variable Primary calibration reference flasks: TO-Mutter (UEA scales), J-256 (AGAGE network) Calibration Scales SF6 CFC_12 SIO-05 SIO-05 ------------------------------------------------------------------------ Instrument precision in [%] NaN NaN NaN NaN NaN NAN NAN 0.6775 0.3312 Detection limit (S/N 3/1) in [ppt] per 100 mL air at STP NaN NaN NaN NaN NaN Values below detection limit are marked as 0.00 In case no measurements are available, the missing data value is used ------------------------------------------------------------------------ SF6 data non-linearity below measurement precision. no correction applied F12 mixing ratio data has been corrected for detector non-linearity by applying a second order polynom: k = a0 + a1 * mr_F12 + a2 * mr_F12^2 coefficients: a0 = -0.04257; a1 = 1.04244; a2 = 0.00013 ------------------------------------------------------------------------ 2 UTC Time_Start Time_End SF6 CFC_12 [s] [s] [s] [ppt] [ppt] 65989 65989 65989 11.51 484.22 66051 66051 66051 11.37 482.73 66112 66112 66112 11.33 483.02 66235 66235 66235 11.41 487.22 66297 66297 66297 11.48 485.58 66358 66358 66358 11.55 486.13 66420 66420 66420 11.48 485.65 66481 66481 66481 11.5 487.57 66543 66543 66543 11.58 486.51 66604 66604 66604 11.65 488.01 66666 66666 66666 11.78 490.09 66727 66727 66727 11.95 489.64 66850 66850 66850 11.79 488.14 66912 66912 66912 11.87 488.98 66973 66973 66973 11.71 489.21 67035 67035 67035 12.11 488.99 67096 67096 67096 11.95 490.02 67158 67158 67158 11.78 488.57 67219 67219 67219 12.0 489.17 67281 67281 67281 12.04 489.85 67343 67343 67343 11.98 490.95 67466 67466 67466 11.99 491.01 67527 67527 67527 12.02 491.24 67589 67589 67589 11.95 491.16 67651 67651 67651 12.11 491.66 68082 68082 68082 11.81 490.03 68144 68144 68144 11.87 488.75 68206 68206 68206 12.0 490.69 68267 68267 68267 11.93 490.24 68329 68329 68329 11.99 489.24 68390 68390 68390 12.03 490.39 68452 68452 68452 12.12 491.03 68513 68513 68513 12.21 491.95 68575 68575 68575 12.15 490.66 68698 68698 68698 12.24 491.03 68759 68759 68759 12.34 489.61 68821 68821 68821 12.25 488.57 68882 68882 68882 11.96 489.22 68944 68944 68944 12.03 489.44 69005 69005 69005 12.05 490.31 69067 69067 69067 12.02 489.94 69128 69128 69128 11.9 491.18 69190 69190 69190 12.02 491.48 69313 69313 69313 11.85 491.53 69374 69374 69374 11.93 491.39 69436 69436 69436 11.76 490.41 69497 69497 69497 11.88 489.68 69559 69559 69559 12.11 489.86 69620 69620 69620 11.87 491.7 69682 69682 69682 11.86 489.14 69743 69743 69743 12.03 491.93 69805 69805 69805 12.07 491.63 69928 69928 69928 11.88 493.35 69990 69990 69990 11.97 493.85 70051 70051 70051 11.91 492.74 70113 70113 70113 11.98 492.21 70174 70174 70174 11.9 491.66 70236 70236 70236 12.01 493.06 70297 70297 70297 12.12 492.67 70359 70359 70359 12.02 491.82 70420 70420 70420 12.17 491.45 70544 70544 70544 12.25 492.29 70605 70605 70605 12.05 491.05 70667 70667 70667 12.07 491.17 70728 70728 70728 11.99 492.64 70790 70790 70790 11.86 491.52 70851 70851 70851 11.8 491.52 70913 70913 70913 11.73 491.96 70974 70974 70974 11.69 490.73 71036 71036 71036 12.02 489.78 71159 71159 71159 11.55 491.81 71220 71220 71220 11.47 486.3 71282 71282 71282 11.48 486.93 71343 71343 71343 11.48 487.43 71405 71405 71405 11.51 487.76 71466 71466 71466 11.46 488.35 71528 71528 71528 11.3 485.97 71589 71589 71589 11.21 482.2 71651 71651 71651 11.4 484.79 71774 71774 71774 11.22 478.76 71835 71835 71835 11.28 478.63 71897 71897 71897 11.18 476.41 71958 71958 71958 11.04 466.13 72020 72020 72020 11.03 466.81 72081 72081 72081 11.07 464.56 72143 72143 72143 11.06 465.11 72204 72204 72204 11.14 464.37 72266 72266 72266 11.1 462.63 72389 72389 72389 11.12 467.47 72450 72450 72450 11.07 466.36 72512 72512 72512 11.08 466.68 72573 72573 72573 11.08 465.88 72635 72635 72635 11.07 463.82 72696 72696 72696 11.03 467.37 72758 72758 72758 11.15 466.23 72819 72819 72819 11.01 471.47 72881 72881 72881 11.01 467.58 73004 73004 73004 11.1 471.65 73065 73065 73065 11.12 476.15 73127 73127 73127 11.18 477.04 73188 73188 73188 11.45 487.58 73250 73250 73250 11.41 488.29 73311 73311 73311 11.55 486.05 73373 73373 73373 11.41 487.14 73434 73434 73434 11.46 486.93 73496 73496 73496 11.31 485.65 73619 73619 73619 11.2 489.32 73680 73680 73680 11.42 489.75 73742 73742 73742 11.42 488.5 73803 73803 73803 11.47 492.86 73865 73865 73865 11.37 491.72 73926 73926 73926 11.52 493.07 73988 73988 73988 11.31 490.99 74049 74049 74049 11.48 491.39 74111 74111 74111 11.44 490.2 74234 74234 74234 11.41 487.64 74295 74295 74295 11.48 490.03 74357 74357 74357 11.31 488.31 74418 74418 74418 11.33 487.82 74480 74480 74480 11.34 489.95 74541 74541 74541 11.35 491.0 74603 74603 74603 11.37 490.57 74664 74664 74664 11.3 491.11 74726 74726 74726 11.32 489.52 74849 74849 74849 11.29 488.51 74910 74910 74910 11.25 486.01 74972 74972 74972 11.3 488.69 75034 75034 75034 11.5 487.6 75095 75095 75095 11.37 488.88 75157 75157 75157 11.43 489.68 75218 75218 75218 11.5 489.85 75280 75280 75280 11.48 490.81 75341 75341 75341 11.38 490.59 75464 75464 75464 11.47 489.79 75526 75526 75526 11.57 490.44 75587 75587 75587 11.55 489.89 75649 75649 75649 11.51 489.78 75710 75710 75710 11.66 488.76 75772 75772 75772 11.59 488.61 75833 75833 75833 11.62 490.05 75895 75895 75895 11.65 490.36 75956 75956 75956 11.75 492.59 76080 76080 76080 11.76 492.58 76141 76141 76141 11.77 490.88 76203 76203 76203 12.1 491.96 76264 76264 76264 12.26 490.72 76326 76326 76326 12.2 489.92 76388 76388 76388 12.17 491.7 76449 76449 76449 12.16 491.6 76511 76511 76511 12.18 488.39 76572 76572 76572 11.93 489.3 76695 76695 76695 11.78 491.98 76757 76757 76757 12.0 490.76 76818 76818 76818 11.75 490.74 76880 76880 76880 11.67 491.55 76941 76941 76941 11.61 489.9 77003 77003 77003 11.6 490.21 77064 77064 77064 11.63 487.87 77126 77126 77126 11.72 486.71 77187 77187 77187 11.58 486.71 77310 77310 77310 11.63 481.15 77372 77372 77372 11.56 485.21 77433 77433 77433 11.59 484.98 77495 77495 77495 11.59 486.91 77556 77556 77556 11.51 484.09 77618 77618 77618 11.66 484.95 77679 77679 77679 11.57 485.17 77741 77741 77741 11.63 486.11 77802 77802 77802 11.64 486.5 77926 77926 77926 11.79 489.05 77987 77987 77987 11.67 487.16 78049 78049 78049 11.67 484.89 78110 78110 78110 11.56 486.84 78172 78172 78172 11.58 484.94 78233 78233 78233 11.61 484.77 78295 78295 78295 11.68 487.15 78356 78356 78356 11.67 486.76 78418 78418 78418 11.67 486.91 78541 78541 78541 11.52 486.17 78602 78602 78602 11.53 487.59 78664 78664 78664 11.58 486.74 78725 78725 78725 11.61 486.69 78787 78787 78787 11.51 486.09 78848 78848 78848 11.67 486.2 78910 78910 78910 11.76 485.39 78971 78971 78971 11.67 485.93 79033 79033 79033 11.65 486.79 79156 79156 79156 11.62 488.98 79218 79218 79218 11.8 490.6 79279 79279 79279 11.89 490.88 79341 79341 79341 11.77 492.55 79402 79402 79402 11.7 491.7 79464 79464 79464 11.83 491.03 79525 79525 79525 11.54 490.51 79587 79587 79587 11.66 488.73 79648 79648 79648 11.68 486.33 79771 79771 79771 11.55 487.72 79833 79833 79833 11.64 487.18 79894 79894 79894 11.67 487.15 79956 79956 79956 11.53 485.99 80017 80017 80017 11.7 486.47 80079 80079 80079 11.51 486.73 80140 80140 80140 11.76 488.18 80202 80202 80202 11.53 486.69 80263 80263 80263 11.57 489.57 80386 80386 80386 11.63 488.03 80448 80448 80448 11.68 489.87 80509 80509 80509 11.68 489.57 80571 80571 80571 11.92 489.67 80632 80632 80632 11.95 489.55 80694 80694 80694 11.75 489.84 80755 80755 80755 11.8 490.43 80817 80817 80817 11.79 490.62 80878 80878 80878 11.81 492.31 81001 81001 81001 11.87 493.45 81063 81063 81063 12.0 491.53 81124 81124 81124 12.03 491.52 81186 81186 81186 12.03 492.83 81247 81247 81247 12.09 493.45 81309 81309 81309 12.22 493.13 81370 81370 81370 12.2 491.29 81432 81432 81432 12.07 490.06 81493 81493 81493 11.95 491.01 81616 81616 81616 12.03 490.41 81678 81678 81678 11.82 488.41 81739 81739 81739 12.11 489.74 81801 81801 81801 12.28 487.83 81862 81862 81862 12.15 486.6 81924 81924 81924 12.04 487.74 81985 81985 81985 11.94 488.66 82047 82047 82047 11.97 488.98 82108 82108 82108 12.0 489.92 82231 82231 82231 12.17 492.02 82293 82293 82293 12.1 492.19 82354 82354 82354 11.92 491.1 82416 82416 82416 11.85 491.64 82477 82477 82477 12.05 491.75 82539 82539 82539 11.96 491.35 82600 82600 82600 11.99 490.59 82662 82662 82662 12.2 489.99 82723 82723 82723 11.89 489.16 82846 82846 82846 11.73 491.82 82908 82908 82908 11.75 489.87 82969 82969 82969 11.7 489.91 83031 83031 83031 11.72 490.62 83092 83092 83092 11.83 489.63 83154 83154 83154 11.81 491.48 83215 83215 83215 11.7 490.42 83277 83277 83277 11.65 492.26 83338 83338 83338 11.66 490.46 83461 83461 83461 11.84 490.85 83523 83523 83523 12.18 490.62 83584 83584 83584 11.9 490.74 83646 83646 83646 11.91 489.49 83707 83707 83707 11.62 490.54 83769 83769 83769 11.88 490.01 83831 83831 83831 11.95 489.28 83892 83892 83892 11.87 491.55 83954 83954 83954 12.07 490.99 84077 84077 84077 11.87 489.5 84138 84138 84138 11.87 490.69 84200 84200 84200 11.97 492.04 84261 84261 84261 12.0 490.45 84323 84323 84323 11.92 492.47 84384 84384 84384 11.78 491.44 84446 84446 84446 11.82 490.74 84507 84507 84507 11.84 491.8 84569 84569 84569 11.83 491.32 84692 84692 84692 11.99 492.17 84753 84753 84753 11.83 491.95 84815 84815 84815 11.93 490.0 84876 84876 84876 11.84 490.55 84938 84938 84938 11.71 491.08 85061 85061 85061 11.81 490.03 85123 85123 85123 11.89 492.04 85184 85184 85184 11.76 491.27 85307 85307 85307 11.82 491.2 85369 85369 85369 12.0 490.63 85431 85431 85431 12.09 491.1 85492 85492 85492 12.11 489.73 85554 85554 85554 11.87 489.42 85615 85615 85615 11.56 488.98 85677 85677 85677 11.44 488.15 85738 85738 85738 11.42 485.33 85800 85800 85800 11.32 483.15 85923 85923 85923 11.37 483.86 85984 85984 85984 11.46 484.45 86046 86046 86046 11.48 484.18 86107 86107 86107 11.29 485.26 86169 86169 86169 11.32 484.88 86230 86230 86230 11.55 485.04 86292 86292 86292 11.47 486.36 86353 86353 86353 11.53 488.43 86415 86415 86415 11.49 489.35 86538 86538 86538 11.61 488.07 86599 86599 86599 11.53 488.44 86661 86661 86661 11.61 489.69 86722 86722 86722 11.53 489.01 86784 86784 86784 11.58 489.99 86845 86845 86845 11.51 488.93 86907 86907 86907 11.51 489.34 86968 86968 86968 11.53 490.07 87030 87030 87030 11.5 491.55 87153 87153 87153 11.54 492.19 87214 87214 87214 11.54 491.0 87276 87276 87276 11.66 487.39 87337 87337 87337 11.53 492.49 87399 87399 87399 11.5 489.17 87460 87460 87460 11.55 488.66 87522 87522 87522 11.62 489.28 87584 87584 87584 11.67 490.58 87645 87645 87645 11.68 489.73 87768 87768 87768 11.51 489.65 87830 87830 87830 11.8 490.65 87891 87891 87891 11.73 489.37 87953 87953 87953 11.63 491.63 88014 88014 88014 11.74 490.41 88076 88076 88076 11.67 490.78 88137 88137 88137 11.69 490.89 88199 88199 88199 11.66 490.21 88260 88260 88260 11.67 490.89 88383 88383 88383 11.87 490.43 88445 88445 88445 11.72 491.87 88506 88506 88506 11.63 490.11 88568 88568 88568 11.75 490.46 88629 88629 88629 11.68 490.44 88691 88691 88691 11.53 489.1 88752 88752 88752 11.6 489.18 88814 88814 88814 11.4 482.41 88875 88875 88875 11.42 482.46 88998 88998 88998 11.41 481.66 89060 89060 89060 11.29 481.27 89122 89122 89122 11.19 481.71 89183 89183 89183 11.42 487.64 89245 89245 89245 11.28 478.88 89306 89306 89306 11.24 479.33 89368 89368 89368 11.39 478.73 89429 89429 89429 11.31 476.55 89491 89491 89491 11.1 478.19 89614 89614 89614 11.35 479.13 89676 89676 89676 11.22 477.15 89738 89738 89738 11.29 479.4 89799 89799 89799 11.36 482.3 89861 89861 89861 11.38 482.16 89922 89922 89922 11.41 483.42 89984 89984 89984 11.4 483.98 90045 90045 90045 11.43 483.86 90107 90107 90107 11.4 485.67 90230 90230 90230 11.4 487.37 90292 90292 90292 11.42 487.05 90354 90354 90354 11.5 489.15 90415 90415 90415 11.43 488.04 90477 90477 90477 11.48 488.24 90538 90538 90538 11.48 489.43 90600 90600 90600 11.48 489.53 90661 90661 90661 11.41 487.5 90723 90723 90723 11.38 487.46 90846 90846 90846 11.42 486.71 90908 90908 90908 11.46 483.1 90969 90969 90969 11.4 483.72 91031 91031 91031 11.3 481.54 91092 91092 91092 11.3 481.87 91154 91154 91154 11.25 484.36 91215 91215 91215 11.21 478.65 91277 91277 91277 11.36 480.06 91338 91338 91338 11.42 481.06 91462 91462 91462 11.33 477.73 91523 91523 91523 11.29 485.76 91585 91585 91585 11.22 482.49 91646 91646 91646 11.37 489.57 91708 91708 91708 11.24 489.44 91769 91769 91769 11.36 487.95 91831 91831 91831 11.58 487.17 91892 91892 91892 11.29 476.66 91954 91954 91954 11.25 480.63 92077 92077 92077 11.22 483.21 92138 92138 92138 11.44 485.65 92200 92200 92200 11.31 482.76 92262 92262 92262 11.11 475.69 92323 92323 92323 11.27 473.2 92385 92385 92385 11.23 473.21 92446 92446 92446 11.35 474.84 92508 92508 92508 11.05 474.12 92569 92569 92569 11.22 479.01 92692 92692 92692 11.23 475.02 92754 92754 92754 11.04 473.08 92815 92815 92815 11.13 473.62 92877 92877 92877 11.08 476.07 92938 92938 92938 11.15 477.61 93000 93000 93000 11.17 479.3 93061 93061 93061 11.16 480.09 93123 93123 93123 11.23 483.73 93184 93184 93184 11.3 487.48 93307 93307 93307 11.24 487.04 93369 93369 93369 11.39 487.92 93430 93430 93430 11.45 488.04 93492 93492 93492 11.43 486.3 93553 93553 93553 11.46 487.28 93615 93615 93615 11.45 487.1 93676 93676 93676 11.51 485.54 93738 93738 93738 11.5 486.45 93799 93799 93799 11.48 485.06 93922 93922 93922 11.56 487.19 93984 93984 93984 11.4 485.77 94045 94045 94045 11.49 487.4 94107 94107 94107 11.35 486.59 94168 94168 94168 11.44 485.0 94230 94230 94230 11.32 485.98 94291 94291 94291 11.5 484.59 94353 94353 94353 11.47 483.48 94414 94414 94414 11.51 486.05 94537 94537 94537 11.44 482.36 94599 94599 94599 11.33 484.3 94660 94660 94660 11.27 484.01 94722 94722 94722 11.25 483.64 94783 94783 94783 11.25 479.4 94845 94845 94845 11.4 483.28 94906 94906 94906 11.39 485.44 94968 94968 94968 11.57 490.58 95029 95029 95029 11.68 491.21 95153 95153 95153 11.86 490.29 95214 95214 95214 11.88 492.01 95276 95276 95276 12.05 490.33 95337 95337 95337 11.77 488.61 95399 95399 95399 11.38 491.33 95461 95461 95461 11.64 490.15 95522 95522 95522 11.53 491.07 95584 95584 95584 11.52 490.13 95645 95645 95645 11.53 488.36 95768 95768 95768 11.54 487.54 95830 95830 95830 11.4 487.86 95891 95891 95891 11.58 488.14 95953 95953 95953 11.6 487.05 96014 96014 96014 11.67 487.28 96076 96076 96076 11.55 486.64 96137 96137 96137 11.59 487.0 96199 96199 96199 11.52 485.52 96260 96260 96260 11.46 485.81 96383 96383 96383 11.36 485.61 96445 96445 96445 11.49 483.55 96506 96506 96506 11.38 484.87 96568 96568 96568 11.39 483.08 96629 96629 96629 11.54 484.55 96691 96691 96691 11.35 484.88 96752 96752 96752 11.55 484.91 96814 96814 96814 11.45 484.57 96875 96875 96875 11.41 484.99