45 1001 Markus Jesswein, Tanja Schuck, Andreas Engel Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Altenhoeferallee 1, 60438 Frankfurt/Main, Germany 1|HALO | GhOST-MS | mixing ratios of long-lived and very short-lived tracers measured with an in-situ GC-ECD instrument, integrated under usage of constant baseline PHILEAS 1 1 2023 08 26 2025 11 06 0 Mean sample time in UT seconds past midnight of flight date 4 1 1 1 1 99999 99999 99999 99999 Time_Start [s] Time_End [s] SF6 [ppt] CFC_12 [ppt] 25 ------------------------------------------------------------------------ Please inform the authors about the use of the data These are preliminary data and not for publication. Please adhere in all cases to the PHILEAS data protocol Contact: Andreas Engel (an.engel@iau.uni-frankfurt.de, phone +49 69 798 40259) ------------------------------------------------------------------------ Calibration Scale, Precision, Accuracy and Detection Limit are given separately for each dependent variable Primary calibration reference flasks: TO-Mutter (UEA scales), J-256 (AGAGE network) Calibration Scales SF6 CFC_12 SIO-05 SIO-05 ------------------------------------------------------------------------ Instrument precision in [%] NaN NaN NaN NaN NaN NAN NAN 0.6642 0.3078 Detection limit (S/N 3/1) in [ppt] per 100 mL air at STP NaN NaN NaN NaN NaN Values below detection limit are marked as 0.00 In case no measurements are available, the missing data value is used ------------------------------------------------------------------------ SF6 data non-linearity below measurement precision. no correction applied F12 mixing ratio data has been corrected for detector non-linearity by applying a second order polynom: k = a0 + a1 * mr_F12 + a2 * mr_F12^2 coefficients: a0 = -0.04257; a1 = 1.04244; a2 = 0.00013 ------------------------------------------------------------------------ 2 UTC Time_Start Time_End SF6 CFC_12 [s] [s] [s] [ppt] [ppt] 64717 64717 64717 11.61 482.32 64779 64779 64779 11.43 485.52 64840 64840 64840 11.35 484.45 64902 64902 64902 11.5 484.93 64963 64963 64963 11.42 485.12 65025 65025 65025 11.48 483.35 65086 65086 65086 11.41 485.06 65148 65148 65148 11.44 485.84 65209 65209 65209 11.46 486.6 65332 65332 65332 11.58 488.79 65394 65394 65394 11.74 488.68 65455 65455 65455 11.51 489.38 65517 65517 65517 11.58 489.54 65578 65578 65578 11.92 489.07 65640 65640 65640 11.62 488.73 65701 65701 65701 12.1 488.9 65763 65763 65763 11.64 488.45 65824 65824 65824 11.87 488.05 65947 65947 65947 12.13 488.89 66009 66009 66009 11.99 490.6 66070 66070 66070 11.73 490.69 66132 66132 66132 11.72 489.49 66193 66193 66193 11.74 491.34 66255 66255 66255 11.71 490.59 66316 66316 66316 11.85 491.64 66378 66378 66378 11.85 490.14 66439 66439 66439 12.01 491.15 66562 66562 66562 12.21 489.33 66624 66624 66624 11.71 489.08 66685 66685 66685 11.69 489.36 66747 66747 66747 11.73 488.72 66808 66808 66808 11.65 487.83 66870 66870 66870 11.79 489.04 66931 66931 66931 11.87 487.21 66993 66993 66993 11.9 490.54 67054 67054 67054 11.74 489.46 67177 67177 67177 11.65 489.54 67239 67239 67239 11.68 488.61 67300 67300 67300 11.78 490.38 67362 67362 67362 11.72 489.52 67423 67423 67423 11.74 489.33 67485 67485 67485 11.74 490.16 67546 67546 67546 11.71 491.33 67608 67608 67608 11.74 490.25 67669 67669 67669 11.7 489.84 67792 67792 67792 11.79 489.47 67854 67854 67854 11.83 489.8 67915 67915 67915 11.92 491.18 67977 67977 67977 12.16 489.95 68038 68038 68038 11.87 490.02 68100 68100 68100 11.87 489.91 68161 68161 68161 11.89 489.47 68223 68223 68223 11.77 488.03 68284 68284 68284 11.93 488.74 68407 68407 68407 11.78 488.21 68469 68469 68469 11.72 487.31 68530 68530 68530 11.56 486.43 68592 68592 68592 11.59 485.51 68653 68653 68653 11.7 488.28 68715 68715 68715 11.67 490.06 68776 68776 68776 11.49 488.74 68838 68838 68838 11.6 488.28 68899 68899 68899 11.67 487.88 69022 69022 69022 11.77 487.96 69084 69084 69084 11.66 488.06 69145 69145 69145 11.75 485.91 69207 69207 69207 11.73 484.81 69268 69268 69268 11.68 484.49 69330 69330 69330 11.79 483.05 69391 69391 69391 11.65 482.58 69453 69453 69453 11.68 480.4 69515 69515 69515 11.66 478.29 69638 69638 69638 11.85 484.61 69699 69699 69699 11.71 481.39 69761 69761 69761 11.96 483.6 69822 69822 69822 11.61 484.12 69884 69884 69884 12.2 487.21 69945 69945 69945 12.2 489.46 70007 70007 70007 12.26 488.64 70068 70068 70068 12.3 488.78 70130 70130 70130 12.1 488.02 70253 70253 70253 12.19 489.43 70314 70314 70314 12.21 490.57 70376 70376 70376 12.32 489.23 70437 70437 70437 12.25 490.26 70499 70499 70499 12.96 489.64 70560 70560 70560 12.78 489.51 70622 70622 70622 12.47 490.26 70683 70683 70683 12.64 491.46 70745 70745 70745 12.21 490.5 70868 70868 70868 12.41 491.02 70929 70929 70929 12.25 491.39 70991 70991 70991 12.18 490.02 71052 71052 71052 12.19 490.4 71114 71114 71114 12.12 490.47 71175 71175 71175 12.13 491.17 71237 71237 71237 12.2 490.97 71298 71298 71298 12.46 490.07 71360 71360 71360 12.34 490.35 71483 71483 71483 12.01 489.83 71544 71544 71544 12.26 489.17 71606 71606 71606 12.26 489.96 71667 71667 71667 11.97 490.0 71729 71729 71729 12.04 488.87 71790 71790 71790 11.99 490.45 71852 71852 71852 12.19 489.72 71913 71913 71913 12.28 488.83 71975 71975 71975 12.1 490.28 72098 72098 72098 12.26 490.68 72159 72159 72159 12.18 489.27 72221 72221 72221 12.07 490.3 72282 72282 72282 12.19 490.22 72344 72344 72344 12.07 490.14 72405 72405 72405 12.32 490.76 72467 72467 72467 12.35 490.4 72528 72528 72528 12.04 490.1 72590 72590 72590 12.24 490.37 72713 72713 72713 12.01 490.85 72774 72774 72774 11.99 490.28 72836 72836 72836 11.84 491.13 72897 72897 72897 11.93 491.33 72959 72959 72959 12.03 491.69 73020 73020 73020 11.9 490.37 73082 73082 73082 11.94 490.63 73143 73143 73143 11.95 490.98 73205 73205 73205 11.86 491.05 73328 73328 73328 11.78 493.28 73389 73389 73389 11.69 490.74 73451 73451 73451 11.89 488.14 73512 73512 73512 12.06 491.33 73574 73574 73574 12.01 490.42 73635 73635 73635 12.02 491.34 73697 73697 73697 12.01 492.19 73758 73758 73758 12.04 490.47 73820 73820 73820 12.12 491.03 73943 73943 73943 12.02 489.51 74004 74004 74004 12.07 490.62 74066 74066 74066 12.09 491.26 74127 74127 74127 12.09 491.21 74189 74189 74189 12.15 489.85 74250 74250 74250 12.1 491.6 74312 74312 74312 12.15 491.13 74373 74373 74373 12.24 490.56 74435 74435 74435 12.23 489.31 74558 74558 74558 12.29 489.23 74619 74619 74619 12.16 488.84 74681 74681 74681 12.37 490.07 74742 74742 74742 12.15 488.94 74804 74804 74804 12.21 491.11 74865 74865 74865 12.22 490.7 74927 74927 74927 12.18 490.78 74988 74988 74988 12.1 491.79 75050 75050 75050 12.1 491.74 75173 75173 75173 12.18 490.38 75234 75234 75234 12.09 490.06 75296 75296 75296 12.13 489.64 75357 75357 75357 12.13 487.96 75419 75419 75419 12.07 490.4 75480 75480 75480 12.26 488.27 75542 75542 75542 12.14 489.83 75603 75603 75603 12.12 489.36 75665 75665 75665 12.2 489.94 75788 75788 75788 12.25 488.56 75849 75849 75849 12.21 489.69 75911 75911 75911 12.13 488.65 75972 75972 75972 12.07 489.95 76034 76034 76034 12.02 488.03 76095 76095 76095 12.13 488.84 76157 76157 76157 12.12 488.86 76219 76219 76219 12.05 490.94 76280 76280 76280 12.08 490.98 76403 76403 76403 12.14 491.91 76711 76711 76711 11.18 481.99 76772 76772 76772 11.1 479.34 76834 76834 76834 11.09 479.17 76895 76895 76895 11.16 479.42 77018 77018 77018 11.02 478.32 77080 77080 77080 11.01 476.77 77141 77141 77141 11.26 478.54 77203 77203 77203 11.29 479.23 77264 77264 77264 11.17 479.79 77326 77326 77326 11.32 480.13 77387 77387 77387 11.31 480.68 77449 77449 77449 11.14 481.43 77510 77510 77510 11.36 480.5 77633 77633 77633 11.33 476.11 77695 77695 77695 11.27 477.07 77756 77756 77756 11.51 484.91 77818 77818 77818 11.54 488.75 77879 77879 77879 11.51 489.57 77941 77941 77941 11.16 479.05 78002 78002 78002 11.44 485.55 78064 78064 78064 11.11 470.42 78125 78125 78125 11.31 476.35 78248 78248 78248 11.29 481.25 78310 78310 78310 11.19 478.18 78371 78371 78371 11.03 474.61 78433 78433 78433 11.21 476.69 78494 78494 78494 11.3 481.01 78556 78556 78556 11.19 478.19 78617 78617 78617 11.31 478.09 78679 78679 78679 11.24 475.45 78740 78740 78740 11.36 479.13 78863 78863 78863 11.36 475.63 78925 78925 78925 11.05 473.5 78986 78986 78986 11.17 477.03 79048 79048 79048 11.31 479.29 79109 79109 79109 11.22 475.43 79171 79171 79171 11.03 469.01 79232 79232 79232 10.99 468.46 79294 79294 79294 11.08 470.42 79355 79355 79355 11.18 479.79 79478 79478 79478 10.89 467.83 79540 79540 79540 11.25 471.81 79601 79601 79601 11.19 473.62 79663 79663 79663 10.96 469.31 79724 79724 79724 11.05 470.72 79786 79786 79786 11.04 474.71 79847 79847 79847 11.15 482.35 79909 79909 79909 11.23 481.39 79970 79970 79970 11.16 484.18 80093 80093 80093 11.27 488.82 80155 80155 80155 11.25 484.46 80216 80216 80216 11.11 478.17 80278 80278 80278 11.18 478.25 80339 80339 80339 11.04 470.78 80401 80401 80401 11.04 471.58 80462 80462 80462 11.17 476.04 80524 80524 80524 11.19 480.4 80585 80585 80585 11.39 486.18 80708 80708 80708 11.45 487.06 80770 80770 80770 11.54 488.07 80831 80831 80831 11.57 490.43 80893 80893 80893 11.52 489.13 80954 80954 80954 11.56 489.64 81016 81016 81016 11.45 490.02 81077 81077 81077 11.39 481.61 81139 81139 81139 11.34 475.84 81200 81200 81200 11.25 473.1 81323 81323 81323 11.29 475.95 81385 81385 81385 11.11 478.16 81446 81446 81446 11.33 479.5 81508 81508 81508 11.4 484.43 81569 81569 81569 11.4 480.72 81631 81631 81631 11.31 483.52 81692 81692 81692 11.48 483.83 81754 81754 81754 11.35 485.47 81816 81816 81816 11.51 484.78 81939 81939 81939 11.77 488.32 82000 82000 82000 11.55 486.54 82062 82062 82062 11.54 488.49 82124 82124 82124 11.57 491.39 82185 82185 82185 11.53 486.92 82247 82247 82247 11.53 486.89 82308 82308 82308 11.5 486.48 82370 82370 82370 11.36 486.59 82431 82431 82431 11.48 487.48 82554 82554 82554 11.69 487.55 82616 82616 82616 11.4 486.43 82677 82677 82677 11.35 487.09 82739 82739 82739 11.33 487.88 82800 82800 82800 11.42 489.31 82862 82862 82862 11.54 488.08 82923 82923 82923 11.53 487.78 82985 82985 82985 11.66 488.95 83046 83046 83046 11.53 489.42 83169 83169 83169 11.47 490.61 83231 83231 83231 11.44 489.51 83292 83292 83292 11.63 489.59 83354 83354 83354 11.58 491.14 83415 83415 83415 11.56 493.0 83477 83477 83477 11.77 490.83 83538 83538 83538 11.53 491.69 83600 83600 83600 11.6 491.45 83661 83661 83661 11.48 492.52 83784 83784 83784 11.61 492.61 83846 83846 83846 11.5 491.99 83907 83907 83907 11.59 491.54 83969 83969 83969 11.67 492.38 84030 84030 84030 11.71 491.73 84092 84092 84092 11.67 490.78 84153 84153 84153 11.84 491.81 84215 84215 84215 11.58 488.67 84276 84276 84276 11.49 485.71 84399 84399 84399 11.51 484.03 84461 84461 84461 11.52 486.4 84522 84522 84522 11.59 487.31 84584 84584 84584 11.56 486.55 84645 84645 84645 11.65 489.44 84707 84707 84707 11.66 490.19 84768 84768 84768 11.61 489.24 84830 84830 84830 11.55 489.07 84891 84891 84891 11.56 488.79 85014 85014 85014 11.66 489.6 85076 85076 85076 11.64 489.72 85137 85137 85137 11.6 490.1 85199 85199 85199 11.74 490.2 85260 85260 85260 11.71 490.32 85322 85322 85322 11.69 489.91 85383 85383 85383 11.72 490.42 85445 85445 85445 11.56 490.31 85506 85506 85506 11.65 489.48 85629 85629 85629 11.54 490.25 85691 85691 85691 11.61 489.48 85752 85752 85752 11.54 489.95 85814 85814 85814 11.58 489.5 85875 85875 85875 11.55 490.15 85937 85937 85937 11.59 490.31 85998 85998 85998 11.53 489.72 86060 86060 86060 11.54 491.5 86121 86121 86121 11.63 491.55 86244 86244 86244 11.51 490.08 86306 86306 86306 11.46 489.93 86367 86367 86367 11.43 489.12 86429 86429 86429 11.47 490.49 86490 86490 86490 11.39 490.79 86552 86552 86552 11.35 484.73 86613 86613 86613 11.5 489.88 86675 86675 86675 11.47 489.87 86736 86736 86736 11.46 488.02 86859 86859 86859 11.52 490.07 86921 86921 86921 11.55 488.96 86982 86982 86982 11.5 489.59 87044 87044 87044 11.47 490.27 87105 87105 87105 11.4 487.34 87167 87167 87167 11.41 487.85 87228 87228 87228 11.46 487.14 87290 87290 87290 11.28 487.72 87351 87351 87351 11.43 488.83 87474 87474 87474 11.29 487.7 87536 87536 87536 11.28 486.09 87597 87597 87597 11.39 487.89 87659 87659 87659 11.3 486.99 87720 87720 87720 11.33 487.73 87782 87782 87782 11.48 485.9 87843 87843 87843 11.46 487.89 87905 87905 87905 11.46 487.38 87966 87966 87966 11.38 488.75 88089 88089 88089 11.37 488.27 88151 88151 88151 11.43 488.04 88212 88212 88212 11.51 487.91 88274 88274 88274 11.35 486.98 88335 88335 88335 11.42 487.71 88397 88397 88397 11.44 487.64 88458 88458 88458 11.49 488.36 88520 88520 88520 11.43 486.01 88581 88581 88581 11.48 485.61 88704 88704 88704 11.26 479.11 88766 88766 88766 11.16 476.66 88827 88827 88827 11.17 478.77 88889 88889 88889 10.96 463.37 88950 88950 88950 10.91 463.89 89012 89012 89012 10.91 460.67 89073 89073 89073 10.95 462.91 89135 89135 89135 11.11 474.22 89196 89196 89196 11.04 470.1 89319 89319 89319 11.13 477.95 89381 89381 89381 11.11 479.55 89442 89442 89442 11.31 481.3 89504 89504 89504 11.23 481.04 89565 89565 89565 11.17 478.02 89627 89627 89627 11.16 469.34 89688 89688 89688 11.2 473.86 89750 89750 89750 11.26 479.36 89811 89811 89811 11.2 470.92 89934 89934 89934 10.97 456.18 89996 89996 89996 11.0 469.6 90058 90058 90058 10.96 458.39 90119 90119 90119 10.83 460.61 90181 90181 90181 11.1 459.28 90242 90242 90242 11.15 463.42 90304 90304 90304 11.07 466.09 90365 90365 90365 11.07 468.54 90427 90427 90427 11.14 469.65 90550 90550 90550 11.49 485.02 90611 90611 90611 11.39 483.53 90673 90673 90673 11.47 484.52 90734 90734 90734 11.25 485.15 90796 90796 90796 11.32 485.1 90857 90857 90857 11.51 484.15 90919 90919 90919 11.36 482.9 90980 90980 90980 11.38 485.67 91042 91042 91042 11.35 483.64 91165 91165 91165 11.44 486.09 91226 91226 91226 11.44 485.44 91288 91288 91288 11.4 484.64 91349 91349 91349 11.3 485.53 91411 91411 91411 11.43 485.14 91472 91472 91472 11.44 485.38 91534 91534 91534 11.45 484.19 91595 91595 91595 11.46 485.73 91657 91657 91657 11.55 485.88 91780 91780 91780 11.44 485.77 91841 91841 91841 11.44 485.93 91903 91903 91903 11.54 487.33 91964 91964 91964 11.53 486.03 92026 92026 92026 11.33 486.39 92087 92087 92087 11.43 485.08 92149 92149 92149 11.38 485.36 92210 92210 92210 11.46 484.59 92272 92272 92272 11.48 486.12 92395 92395 92395 11.35 487.07 92456 92456 92456 11.36 484.87 92518 92518 92518 11.43 484.06 92579 92579 92579 11.5 485.22 92641 92641 92641 11.38 486.17 92702 92702 92702 11.47 484.6 92764 92764 92764 11.33 475.31 92825 92825 92825 10.99 466.61 92887 92887 92887 11.33 472.49 93010 93010 93010 11.82 489.24 93071 93071 93071 11.94 490.02 93133 93133 93133 12.25 489.49 93194 93194 93194 12.3 491.25 93256 93256 93256 11.72 488.97 93317 93317 93317 11.62 490.27 93379 93379 93379 11.77 490.09 93440 93440 93440 11.64 489.23 93502 93502 93502 11.47 489.0 93625 93625 93625 11.54 490.04 93686 93686 93686 11.62 489.24 93748 93748 93748 11.63 489.83 93809 93809 93809 11.57 487.18 93871 93871 93871 11.46 485.23 93932 93932 93932 11.44 487.02 93994 93994 93994 11.4 485.67 94055 94055 94055 11.41 484.89 94117 94117 94117 11.39 484.06 94240 94240 94240 11.38 483.91 94301 94301 94301 11.31 483.74 94363 94363 94363 11.4 483.69