45 1001 Markus Jesswein, Tanja Schuck, Andreas Engel Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Altenhoeferallee 1, 60438 Frankfurt/Main, Germany 1|HALO | GhOST-MS | mixing ratios of long-lived and very short-lived tracers measured with an in-situ GC-ECD instrument, integrated under usage of constant baseline PHILEAS 1 1 2023 08 06 2025 11 07 0 Mean sample time in UT seconds past midnight of flight date 4 1 1 1 1 99999 99999 99999 99999 Time_Start [s] Time_End [s] SF6 [ppt] CFC_12 [ppt] 25 ------------------------------------------------------------------------ Please inform the authors about the use of the data These are preliminary data and not for publication. Please adhere in all cases to the PHILEAS data protocol Contact: Andreas Engel (an.engel@iau.uni-frankfurt.de, phone +49 69 798 40259) ------------------------------------------------------------------------ Calibration Scale, Precision, Accuracy and Detection Limit are given separately for each dependent variable Primary calibration reference flasks: TO-Mutter (UEA scales), J-256 (AGAGE network) Calibration Scales SF6 CFC_12 SIO-05 SIO-05 ------------------------------------------------------------------------ Instrument precision in [%] NaN NaN NaN NaN NaN NAN NAN 0.7858 0.3282 Detection limit (S/N 3/1) in [ppt] per 100 mL air at STP NaN NaN NaN NaN NaN Values below detection limit are marked as 0.00 In case no measurements are available, the missing data value is used ------------------------------------------------------------------------ SF6 data non-linearity below measurement precision. no correction applied F12 mixing ratio data has been corrected for detector non-linearity by applying a second order polynom: k = a0 + a1 * mr_F12 + a2 * mr_F12^2 coefficients: a0 = -0.04257; a1 = 1.04244; a2 = 0.00013 ------------------------------------------------------------------------ 2 UTC Time_Start Time_End SF6 CFC_12 [s] [s] [s] [ppt] [ppt] 23979 23979 23979 11.58 484.4 24040 24040 24040 11.63 483.04 24102 24102 24102 11.51 482.22 24163 24163 24163 11.53 482.93 24225 24225 24225 11.53 482.6 24348 24348 24348 11.48 482.94 24409 24409 24409 11.38 481.24 24471 24471 24471 11.32 480.94 24532 24532 24532 11.56 483.51 24594 24594 24594 11.3 484.05 24655 24655 24655 11.3 484.69 24717 24717 24717 11.48 485.36 24778 24778 24778 11.41 485.12 24840 24840 24840 11.37 487.08 24963 24963 24963 11.51 485.5 25024 25024 25024 11.4 485.34 25086 25086 25086 11.38 484.6 25147 25147 25147 11.48 485.67 25209 25209 25209 11.22 484.37 25270 25270 25270 11.22 482.95 25332 25332 25332 11.35 486.31 25393 25393 25393 11.12 485.35 25455 25455 25455 11.4 482.6 25578 25578 25578 11.29 486.13 25639 25639 25639 11.22 484.42 25701 25701 25701 11.4 482.15 25762 25762 25762 11.4 481.68 25824 25824 25824 11.22 481.37 25885 25885 25885 11.53 485.07 25947 25947 25947 11.5 486.28 26008 26008 26008 11.47 484.98 26070 26070 26070 11.33 487.17 26193 26193 26193 11.55 488.72 26254 26254 26254 11.56 490.06 26316 26316 26316 11.22 478.93 26377 26377 26377 11.19 474.15 26439 26439 26439 10.95 466.78 26500 26500 26500 10.8 464.15 26562 26562 26562 10.86 462.23 26623 26623 26623 10.73 457.98 26685 26685 26685 10.92 464.48 26808 26808 26808 10.82 459.89 26869 26869 26869 10.73 465.13 26931 26931 26931 10.98 462.57 26992 26992 26992 10.81 463.07 27054 27054 27054 11.0 462.37 27115 27115 27115 10.85 462.16 27177 27177 27177 11.08 462.76 27238 27238 27238 10.94 471.15 27300 27300 27300 11.17 473.92 27423 27423 27423 11.14 472.11 27484 27484 27484 11.18 475.95 27546 27546 27546 11.13 476.05 27607 27607 27607 11.15 475.09 27669 27669 27669 11.18 475.51 27730 27730 27730 11.13 474.66 27792 27792 27792 10.99 477.48 27853 27853 27853 11.11 478.45 27915 27915 27915 11.06 477.4 28038 28038 28038 11.23 476.0 28099 28099 28099 11.28 475.74 28161 28161 28161 11.12 475.39 28222 28222 28222 11.21 475.89 28284 28284 28284 11.08 475.56 28345 28345 28345 11.16 481.62 28407 28407 28407 11.36 480.07 28468 28468 28468 11.3 482.15 28530 28530 28530 11.14 482.97 28653 28653 28653 11.36 482.88 28714 28714 28714 11.4 481.83 28776 28776 28776 11.27 483.61 28837 28837 28837 11.45 482.5 28899 28899 28899 11.38 482.42 28960 28960 28960 11.42 485.55 29022 29022 29022 11.28 485.67 29083 29083 29083 11.36 485.04 29145 29145 29145 11.42 486.33 29268 29268 29268 11.42 487.0 29329 29329 29329 11.37 486.94 29391 29391 29391 11.41 488.21 29452 29452 29452 11.31 486.14 29514 29514 29514 11.43 487.25 29575 29575 29575 11.43 489.99 29637 29637 29637 11.48 489.09 29698 29698 29698 11.37 489.67 29760 29760 29760 11.49 488.03 29883 29883 29883 11.37 489.83 29944 29944 29944 11.42 490.33 30006 30006 30006 11.53 489.3 30067 30067 30067 11.33 488.88 30129 30129 30129 11.32 488.77 30190 30190 30190 11.5 489.86 30252 30252 30252 11.34 490.0 30313 30313 30313 11.32 489.8 30375 30375 30375 11.29 488.73 30498 30498 30498 11.38 488.84 30559 30559 30559 11.33 490.18 30621 30621 30621 11.28 489.89 30682 30682 30682 11.44 489.34 30744 30744 30744 11.41 490.5 30805 30805 30805 11.54 489.53 30867 30867 30867 11.53 490.63 30928 30928 30928 11.35 490.4 30990 30990 30990 11.66 489.73 31113 31113 31113 11.36 488.38 31174 31174 31174 11.55 490.4 31236 31236 31236 11.5 488.36 31297 31297 31297 11.55 490.21 31359 31359 31359 11.45 489.89 31420 31420 31420 11.45 490.57 31482 31482 31482 11.39 490.52 31543 31543 31543 11.5 489.51 31605 31605 31605 11.45 488.4 31728 31728 31728 11.48 487.7 31789 31789 31789 11.21 486.68 31851 31851 31851 11.35 486.23 31912 31912 31912 11.3 485.72 31974 31974 31974 11.45 486.41 32035 32035 32035 11.48 486.61 32097 32097 32097 11.41 486.84 32158 32158 32158 11.44 486.02 32220 32220 32220 11.32 487.18 32343 32343 32343 11.4 488.12 32404 32404 32404 11.46 488.95 32466 32466 32466 11.51 488.68 32527 32527 32527 11.55 489.01 32589 32589 32589 11.65 489.85 32650 32650 32650 11.49 488.41 32712 32712 32712 11.62 488.57 32773 32773 32773 11.55 488.74 32835 32835 32835 11.46 490.56 32958 32958 32958 11.6 489.43 33019 33019 33019 11.57 490.02 33081 33081 33081 11.57 491.13 33142 33142 33142 11.54 490.52 33204 33204 33204 11.6 489.79 33265 33265 33265 11.45 490.98 33327 33327 33327 11.62 489.04 33388 33388 33388 11.47 489.84 33450 33450 33450 11.53 491.45 33573 33573 33573 11.47 490.07 33634 33634 33634 11.57 492.02 33696 33696 33696 11.46 490.51 33757 33757 33757 11.64 492.05 33819 33819 33819 11.45 490.86 33880 33880 33880 11.4 492.21 33942 33942 33942 11.63 490.95 34003 34003 34003 11.42 492.51 34065 34065 34065 11.61 492.83 34188 34188 34188 11.46 492.93 34249 34249 34249 11.5 492.1 34311 34311 34311 11.43 491.76 34372 34372 34372 11.36 491.47 34434 34434 34434 11.43 491.52 34495 34495 34495 11.56 491.47 34557 34557 34557 11.38 491.79 34618 34618 34618 11.42 493.19 34680 34680 34680 11.36 491.6 34803 34803 34803 11.45 490.92 34864 34864 34864 11.45 490.22 34926 34926 34926 11.53 491.51 34987 34987 34987 11.46 490.89 35049 35049 35049 11.59 490.99 35110 35110 35110 11.26 491.34 35172 35172 35172 11.44 493.93 35233 35233 35233 11.58 492.31 35295 35295 35295 11.49 492.26 35418 35418 35418 11.54 492.95 35479 35479 35479 11.46 490.5 35541 35541 35541 11.64 491.43 35602 35602 35602 11.44 491.35 35664 35664 35664 11.68 491.89 35725 35725 35725 11.48 493.05 35787 35787 35787 11.66 490.0 35848 35848 35848 11.47 491.11 35910 35910 35910 11.61 490.79 36033 36033 36033 11.51 492.5 36094 36094 36094 11.41 492.82 36156 36156 36156 11.55 491.46 36217 36217 36217 11.56 490.76 36279 36279 36279 11.39 490.99 36340 36340 36340 11.4 492.55 36402 36402 36402 11.54 491.23 36463 36463 36463 11.43 492.63 36525 36525 36525 11.46 493.17 36648 36648 36648 11.44 491.95 36709 36709 36709 11.47 491.87 36771 36771 36771 11.53 490.96 36832 36832 36832 11.37 492.25 36894 36894 36894 11.43 490.41 36955 36955 36955 11.56 491.67 37017 37017 37017 11.45 490.43 37078 37078 37078 11.49 489.62 37140 37140 37140 11.41 488.12 37263 37263 37263 11.51 490.06 37324 37324 37324 11.53 489.0 37386 37386 37386 11.48 489.25 37447 37447 37447 11.6 489.73 37509 37509 37509 11.67 488.87 37570 37570 37570 11.53 490.85 37632 37632 37632 11.69 490.42 37693 37693 37693 11.71 489.86 37755 37755 37755 11.62 491.34 37878 37878 37878 11.51 492.17 37939 37939 37939 11.65 489.32 38001 38001 38001 11.37 491.29 38062 38062 38062 11.53 490.39 38124 38124 38124 11.48 491.33 38185 38185 38185 11.56 491.7 38247 38247 38247 11.35 489.27 38308 38308 38308 11.33 491.95 38370 38370 38370 11.32 490.57 38493 38493 38493 11.46 490.5 38554 38554 38554 11.37 490.88 38616 38616 38616 11.37 490.66 38677 38677 38677 11.51 489.38 38739 38739 38739 11.45 490.56 38800 38800 38800 11.54 490.14 38862 38862 38862 11.62 489.25 38923 38923 38923 11.53 488.31 38985 38985 38985 11.51 490.09 39108 39108 39108 11.58 489.9 39169 39169 39169 11.72 490.42 39231 39231 39231 11.65 488.79 39292 39292 39292 11.6 488.84 39354 39354 39354 11.64 487.85 39415 39415 39415 11.56 488.79 39477 39477 39477 11.54 489.32 39538 39538 39538 11.67 491.7 39600 39600 39600 11.53 490.87 39723 39723 39723 11.56 491.0 39784 39784 39784 11.38 491.7 39846 39846 39846 11.47 490.07 39907 39907 39907 11.49 489.6 39969 39969 39969 11.44 489.5 40030 40030 40030 11.45 488.96 40092 40092 40092 11.5 489.12 40153 40153 40153 11.53 489.19 40215 40215 40215 11.45 491.62 40338 40338 40338 11.59 490.84 40399 40399 40399 11.44 488.8 40461 40461 40461 11.6 489.6 40522 40522 40522 11.53 490.98 40584 40584 40584 11.49 491.11 40645 40645 40645 11.52 491.95 40707 40707 40707 11.53 491.64 40768 40768 40768 11.48 490.95 40830 40830 40830 11.68 490.39 40953 40953 40953 11.57 491.4 41014 41014 41014 11.59 490.28 41076 41076 41076 11.58 489.46 41137 41137 41137 11.4 489.73 41199 41199 41199 11.53 490.48 41260 41260 41260 11.57 489.82 41322 41322 41322 11.43 490.27 41383 41383 41383 11.65 490.68 41445 41445 41445 11.54 491.9 41568 41568 41568 11.43 492.45 41629 41629 41629 11.45 491.71 41691 41691 41691 11.34 492.98 41752 41752 41752 11.42 490.65 41814 41814 41814 11.45 491.64 41875 41875 41875 11.39 490.39 41937 41937 41937 11.41 491.57 41998 41998 41998 11.38 491.92 42060 42060 42060 11.4 492.94 42183 42183 42183 11.31 491.15 42244 42244 42244 11.48 491.0 42306 42306 42306 11.41 491.78 42367 42367 42367 11.35 490.1 42429 42429 42429 11.43 491.39 42490 42490 42490 11.43 491.36 42552 42552 42552 11.41 490.67 42613 42613 42613 11.33 491.61 42675 42675 42675 11.25 490.7 42798 42798 42798 11.41 491.3 42859 42859 42859 11.59 492.5 42921 42921 42921 11.71 492.64 42982 42982 42982 11.56 491.38 43044 43044 43044 11.39 491.86 43106 43106 43106 11.52 493.39 43167 43167 43167 11.46 491.46 43229 43229 43229 11.54 491.29 43290 43290 43290 11.69 491.64 43413 43413 43413 11.56 490.59 43475 43475 43475 11.48 492.42 43536 43536 43536 11.58 489.33 43598 43598 43598 11.58 491.53 43659 43659 43659 11.64 489.98 43721 43721 43721 11.52 489.79 43782 43782 43782 11.6 491.36 43844 43844 43844 11.54 489.74 43905 43905 43905 11.56 490.75 44028 44028 44028 11.64 490.58 44090 44090 44090 11.46 490.84 44151 44151 44151 11.51 491.79 44213 44213 44213 11.51 491.43 44274 44274 44274 11.53 490.7 44336 44336 44336 11.41 491.35 44397 44397 44397 11.59 490.93 44459 44459 44459 11.49 491.72 44521 44521 44521 11.59 492.28 44644 44644 44644 11.5 491.75 44705 44705 44705 11.52 492.45 44767 44767 44767 11.27 489.22 44828 44828 44828 11.49 491.28 44890 44890 44890 11.43 490.33 44951 44951 44951 11.52 486.03 45013 45013 45013 11.53 489.73 45074 45074 45074 11.35 488.9 45136 45136 45136 11.43 489.04 45259 45259 45259 11.65 490.26 45320 45320 45320 11.64 491.85 45382 45382 45382 11.67 491.09 45443 45443 45443 11.54 490.81 45505 45505 45505 11.56 490.23 45566 45566 45566 11.49 491.85 45628 45628 45628 11.37 491.63 45689 45689 45689 11.53 491.98 45751 45751 45751 11.39 492.7 45874 45874 45874 11.56 494.76 45935 45935 45935 11.54 494.21 45997 45997 45997 11.44 494.73 46058 46058 46058 11.49 492.69 46120 46120 46120 11.53 492.77 46181 46181 46181 11.43 493.82 46243 46243 46243 11.48 493.96 46304 46304 46304 11.46 493.43 46366 46366 46366 11.51 492.15 46489 46489 46489 11.57 492.75 46550 46550 46550 11.57 491.71 46612 46612 46612 11.72 492.38 46673 46673 46673 11.46 492.08 46735 46735 46735 11.49 492.67 46796 46796 46796 11.58 491.98 46858 46858 46858 11.5 491.9 46919 46919 46919 11.63 491.48 46981 46981 46981 11.59 491.04 47104 47104 47104 11.61 491.16 47165 47165 47165 11.54 490.77 47227 47227 47227 11.61 490.7 47288 47288 47288 11.67 491.26 47350 47350 47350 11.64 490.81 47411 47411 47411 11.68 490.56 47473 47473 47473 11.61 491.05 47534 47534 47534 11.6 492.99 47596 47596 47596 11.63 491.0 47719 47719 47719 11.61 490.36 47780 47780 47780 11.58 489.92 47842 47842 47842 11.57 490.83 47903 47903 47903 11.58 490.66 47965 47965 47965 11.6 489.91 48026 48026 48026 11.68 490.37 48088 48088 48088 11.5 491.44 48149 48149 48149 11.44 490.57 48211 48211 48211 11.43 490.23 48334 48334 48334 11.45 489.39 48395 48395 48395 11.47 490.76 48457 48457 48457 11.59 490.5 48518 48518 48518 11.4 491.03 48580 48580 48580 11.64 489.06 48641 48641 48641 11.36 485.19 48703 48703 48703 11.23 481.5 48764 48764 48764 11.23 481.77 48826 48826 48826 11.32 482.42 48949 48949 48949 11.32 485.25 49010 49010 49010 11.22 483.02 49072 49072 49072 11.36 482.84 49133 49133 49133 11.24 481.83 49195 49195 49195 11.37 484.4 49256 49256 49256 11.54 486.07 49318 49318 49318 11.4 485.04 49379 49379 49379 11.45 484.64 49441 49441 49441 11.24 484.59 49564 49564 49564 11.31 484.06 49625 49625 49625 11.41 485.53 49687 49687 49687 11.34 486.55 49748 49748 49748 11.39 486.25 49810 49810 49810 11.45 488.35 49871 49871 49871 11.48 487.85 49933 49933 49933 11.38 489.51 49994 49994 49994 11.57 488.4 50056 50056 50056 11.52 490.13 50179 50179 50179 11.6 487.96 50241 50241 50241 11.4 488.16 50302 50302 50302 11.48 489.37 50364 50364 50364 11.37 488.19 50425 50425 50425 11.42 488.06 50487 50487 50487 11.38 489.59 50548 50548 50548 11.31 489.16 50610 50610 50610 11.36 490.5 50671 50671 50671 11.35 488.48 50794 50794 50794 11.31 490.3 50856 50856 50856 11.21 489.42 50917 50917 50917 11.35 488.27 50979 50979 50979 11.21 489.03 51040 51040 51040 11.36 488.24 51102 51102 51102 11.25 485.87 51163 51163 51163 11.24 487.32 51225 51225 51225 11.4 488.1 51286 51286 51286 11.25 488.18 51409 51409 51409 11.29 487.52 51471 51471 51471 11.29 488.01 51532 51532 51532 11.38 486.76 51594 51594 51594 11.45 486.84 51655 51655 51655 11.38 485.63 51717 51717 51717 11.46 487.0 51778 51778 51778 11.45 486.8 51840 51840 51840 11.45 483.22 51901 51901 51901 11.37 483.12 52024 52024 52024 11.27 483.52 52086 52086 52086 11.3 483.79 52147 52147 52147 11.43 482.75 52209 52209 52209 11.45 485.43 52270 52270 52270 11.51 484.55 52332 52332 52332 11.34 484.4 52393 52393 52393 11.53 484.03 52455 52455 52455 11.45 484.08 52516 52516 52516 11.36 484.29 52639 52639 52639 11.41 483.87 52701 52701 52701 11.35 481.98 52762 52762 52762 11.47 483.91 52824 52824 52824 11.41 482.74 52885 52885 52885 11.34 484.03 52947 52947 52947 11.37 484.38 53008 53008 53008 11.27 483.5 53070 53070 53070 11.37 484.35 53131 53131 53131 11.25 483.09 53254 53254 53254 11.3 483.76 53316 53316 53316 11.21 484.34 53377 53377 53377 11.29 482.85 53439 53439 53439 11.25 482.96 53500 53500 53500 11.24 483.47 53562 53562 53562 11.34 484.87 53623 53623 53623 11.23 485.38 53685 53685 53685 11.29 483.14 53746 53746 53746 11.29 484.82 53869 53869 53869 11.22 482.36 53931 53931 53931 11.43 482.69 53992 53992 53992 11.21 482.68 54054 54054 54054 11.14 481.12 54115 54115 54115 11.35 482.92 54177 54177 54177 11.08 477.63 54238 54238 54238 11.1 473.47 54300 54300 54300 11.18 478.28 54361 54361 54361 11.34 479.76 54484 54484 54484 11.26 485.99 54546 54546 54546 11.39 488.25 54607 54607 54607 11.36 487.18 54669 54669 54669 11.39 486.36 54730 54730 54730 11.32 484.66 54792 54792 54792 11.23 480.7 54853 54853 54853 11.32 483.33 54915 54915 54915 11.26 472.82 54976 54976 54976 11.36 478.82 55099 55099 55099 11.63 488.4 55161 55161 55161 11.55 488.99 55222 55222 55222 11.67 490.6 55284 55284 55284 11.6 489.24 55345 55345 55345 11.76 487.17 55407 55407 55407 11.54 484.83 55468 55468 55468 11.63 486.58 55530 55530 55530 11.78 488.89 55591 55591 55591 11.66 487.34 55714 55714 55714 11.74 488.38 55776 55776 55776 11.44 488.11