90 1001
Eric Foerster (Eric.Foerster@kit.edu)
Institute of Meteorology and Climate Research (IMK), Karlsruhe Institute of Technology (KIT), 76021 Karlsruhe, P.O. Box 3640, Germany
1 | HALO | HKMS | VOC data measured with instrument HKMS (HALO Karlsruher Mass Spectrometer) a Proton Transfer Reaction - Mass Spectrometer onboard the research aircraft HALO
EM-EU-04
1 1
2017 07 13 2022 05 02
0
Time; seconds after midnight (UTC); [s]
23
1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1
-9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999
FOR; Formaldehyde, volume mixing ratio; [pptV]; quantified by signal integration on protonated FOR (m/z = 31)
FOR_prec; Formaldehyde, precision; [pptV];
FOR_lod; Formaldehyde, humidity dependent in-flight detection limit; [pptV];
MET; Methanol, volume mixing ratio; [pptV]; quantified by signal integration on protonated MET (m/z = 33.2)
MET_prec; Methanol, precision; [pptV];
MET_lod; Methanol, humidity dependent in-flight detection limit; [pptV];
ACN; Acetonitrile, volume mixing ratio; [pptV]; quantified by signal integration on protonated ACN (m/z = 42)
ACN_prec; Acetonitrile, precision; [pptV];
ACA; Acetaldehyde, volume mixing ratio; [pptV]; quantified by signal integration on protonated ACA (m/z = 45)
ACA_prec; Acetaldehyde, precision; [pptV];
ACE; Acetone, volume mixing ratio; [pptV]; quantified by signal integration on protonated ACE (m/z = 59)
ACE_prec; Acetone, precision; [pptV];
DMS; Dimethylsulfid, volume mixing ratio; [pptV]; quantified by signal integration on protonated DMS (m/z = 63)
DMS_prec; Dimethylsulfid, precision; [pptV];
DMS_lod; Dimethylsulfid, humidity dependent in-flight detection limit; [pptV];
ISO; Isoprene, volume mixing ratio; [pptV]; quantified by signal integration on protonated ISO (m/z = 69)
ISO_prec; Isoprene, precision; [pptV];
BEN; Benzene, volume mixing ratio; [pptV]; quantified by signal integration on protonated BEN (m/z = 79)
BEN_prec; Benzene, precision; [pptV];
TOL; Toluene, volume mixing ratio; [pptV]; quantified by signal integration on protonated TOL (m/z = 93)
TOL_prec; Toluene, precision; [pptV];
XYL; Xylene, volume mixing ratio; [pptV]; quantified by signal integration on protonated XYL (m/z = 107)
XYL_prec; Xylene, precision; [pptV];
12
Gas standard used for calibrations: Apel-Riemer, 2016, VOCs in synthetic air with an uncertainty of +/- 5 percent.
VOCs included in the standard: FOR, MET, ACN, ACA, ACE, DMS, ISO, MVK, MEK, BEN, TOL, XYL, Pinene.
VOC concentrations in the standard [ppbV]: 1040.3, 476.9, 514.9, 494, 483.4, 488.6, 486.3, 450.1, 512.1, 494.6, 491, 478.2, 494.1, respectively.
Compounds sensitivities obtained by detecting the respective ion count rate (counts per seconds) in gas standard dilution series.
Determination of volume mixing ratios by normalization (VMR) of ion count rates with interpolated sensitivities of several calibration experiments during the campaign.
Instruments background determined from linearly interpolated blank measurements (approx. every 30 min for 5 minutes - flagged as VMISS) and subtracted from measurement signal.
Exception for FOR, MET, DMS, MEK, BEN, TOL and XYL to previous line: Humidity dependent background determined from exponential (y = a*exp(b*x) + c*x.^d, y - background, x - humidity) or quadratic fit (y = p1*x^2 + p2*x + p3) and subtracted from measurement signal.
However, only applied to BEN, TOL and XYL if correlation coeff of background and humidity > 0.6.
From Background subtraction resulting negative values (in case of very low atmospheric concentrations below LOD) are set to VMISS.
Precision is the statistical noise of ion count rates given in columns VOC_prec.
For calibration a re-filled 2 liter bottle of the parent Apel-Riemer gas standard was used.
Filling of this 2 liter gas standard bottle caused a concentration drift of FOR and MET over time and was corrected.
41
Accuracy is affected by 5 percent uncertainty of the respective mixing ratio in the calibration gas standard plus X percent from the calibration process itself, humidity correction and - if existing - bottle drift correction (errors in X added by Gaussian error propagation).
Total relative accuracies [%] are given in the next lines for each VOC:
FOR_acc: 18
MET_acc: 11
ACN_acc: 8
ACA_acc: 9
ACE_acc: 8
DMS_acc: 9
ISO_acc: 9
BEN_acc: 9
TOL_acc: 8
XYL_acc: 8
The following lines contain the instrument detection limits given in the units of the respective VOC column.
Additionally, complete humidity dependent in-flight LODs for FOR, MET, DMS and MEK (if available) are given in the columns with VNAME "*_lod".
LODs determined in long laboratory measurements.
FOR_LOD: 178
MET_LOD: 799
ACN_LOD: 37
ACA_LOD: 147
ACE_LOD: 65
DMS_LOD: 27
ISO_LOD: 49
BEN_LOD: 29
TOL_LOD: 20
XYL_LOD: 70
Temporal resolution per VOC is ca. 1/61 Hz.
FileName: EMERGE-EU-04_2017-07-13_HKMS_10VOCs_V07.ames
Version: V07
ChangeLog1: V01->V02: 20181025, Preliminary to first final data.
ChangeLog2: V02->V03: 20190503, Updated humidity correction, calculation of precision and accuracy; Applied bottle drift correction for MET and FOR; Applied humidity dependent background subtraction of FOR; Added VOC dependent LODs.
ChangeLog3: V03->V04: 20191114, Background subtraction now after calculation of VMR; background mask enlarged to +/- 2 mass measurements (~10 s) to neglect switching from sample line <-> background line; values below zero (due to background subtraction) now set to zero (VMISS in V03); update of precision and accuracy.
ChangeLog4: V04->V05: 20200304, 1. Applied humidity (hum) dependent background (bgnd) handling of BEN, TOL, XYL, if correlation coeff of bgnd and hum > 0.6: Means of the 5-minute bgnd measurements are fitted against respective 5-minute means of hum (H3O+(H2O) water cluster on m/z = m37). Hum dependent, smoothed (Savitzky-Golay) bgnd signal calculated from fitted curve and subtracted from measurement signal.
ChangeLog4: V04->V05: 20200304, 2. Procedure of 1. is also applied to MET, but only using all bgnd measurements instead of means.
ChangeLog4: V04->V05: 20200304, 3. In this Version, also conservative in-flight detection limits are added. Furthermore, the laboratory LODs are still included. As the humdity has also an influence on the LOD of FOR and MET, for these two VOCs separate columns with LODs are added.
ChangeLog5: V05->V06: 20201027, 1. All calibrations, instrumental background subtractions and detections limits were improved and/or updated. This can slightly change the VOC concentrations.
ChangeLog5: V05->V06: 20201027, 2. Added DMS (Dimethylsulfid). Background is highly humidity dependent and thus adjusted according to same procedure as formaldehyde. Consider DMS as preliminary data with still unknown effects concerning background and humidity.
ChangeLog6: V06->V07: 20220502, 1. Instrumental background subtraction slightly adjusted, especially for benzene (BEN) and toluene (TOL). Expect minimal changes of VMRs (for BEN and TOL mostly small enlargements).
ChangeLog6: V06->V07: 20220502, 2. LODs revised. Usage of lab measurements closer to the campaign period (2017 08 03) to be more representative.
Data status is final.
[s]	[pptV]	[pptV]	[pptV]	[pptV]	[pptV]	[pptV]	[pptV]	[pptV]	[pptV]	[pptV]	[pptV]	[pptV]	[pptV]	[pptV]	[pptV]	[pptV]	[pptV]	[pptV]	[pptV]	[pptV]	[pptV]	[pptV]	[pptV]
Time	FOR	FOR_prec	FOR_lod	MET	MET_prec	MET_lod	ACN	ACN_prec	ACA	ACA_prec	ACE	ACE_prec	DMS	DMS_prec	DMS_lod	ISO	ISO_prec	BEN	BEN_prec	TOL	TOL_prec	XYL	XYL_prec
38430	1200	128	325	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38436	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38441	-9999	-9999	-9999	-9999	-9999	-9999	89	19	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38445	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	533	78	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38451	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	1542	46	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38456	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	117	34	96	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38462	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	118	28	-9999	-9999	-9999	-9999	-9999	-9999
38469	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	63	15	-9999	-9999	-9999	-9999
38476	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	54	13	-9999	-9999
38482	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38490	1185	122	310	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38496	-9999	-9999	-9999	4574	266	740	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38501	-9999	-9999	-9999	-9999	-9999	-9999	95	19	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38505	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	660	79	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38511	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	1560	46	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38516	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	95	34	96	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38522	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	100	27	-9999	-9999	-9999	-9999	-9999	-9999
38529	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	42	14	-9999	-9999	-9999	-9999
38536	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	50	11	-9999	-9999
38542	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	96	38
38550	1064	108	277	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38556	-9999	-9999	-9999	4245	263	737	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38561	-9999	-9999	-9999	-9999	-9999	-9999	113	20	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38565	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	238	74	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38571	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	1391	44	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38576	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	10	35	105	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38582	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	67	26	-9999	-9999	-9999	-9999	-9999	-9999
38589	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	38	13	-9999	-9999	-9999	-9999
38596	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	38	10	-9999	-9999
38602	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	70	37
38610	605	99	270	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38616	-9999	-9999	-9999	3625	265	752	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38621	-9999	-9999	-9999	-9999	-9999	-9999	88	19	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38625	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	262	75	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38631	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	1362	44	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38636	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	2	36	108	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38642	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	57	26	-9999	-9999	-9999	-9999	-9999	-9999
38649	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	27	12	-9999	-9999	-9999	-9999
38656	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	46	10	-9999	-9999
38662	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	43	38
38670	455	87	243	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38676	-9999	-9999	-9999	3557	271	770	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38682	-9999	-9999	-9999	-9999	-9999	-9999	99	19	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38686	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	264	75	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38691	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	1447	45	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38696	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	87	47	136	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38702	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	73	27	-9999	-9999	-9999	-9999	-9999	-9999
38709	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	23	12	-9999	-9999	-9999	-9999
38716	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	22	8	-9999	-9999
38722	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	196	44
38730	494	85	240	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38736	-9999	-9999	-9999	3786	280	794	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38742	-9999	-9999	-9999	-9999	-9999	-9999	103	20	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38746	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	207	75	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38751	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	1403	45	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38756	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38762	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	86	27	-9999	-9999	-9999	-9999	-9999	-9999
38769	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	15	11	-9999	-9999	-9999	-9999
38777	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	31	9	-9999	-9999
38783	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	96	45
38790	507	81	226	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38796	-9999	-9999	-9999	3119	280	804	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38802	-9999	-9999	-9999	-9999	-9999	-9999	110	20	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38806	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	127	75	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38811	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	1297	44	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38816	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38822	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	93	28	-9999	-9999	-9999	-9999	-9999	-9999
38829	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	34	12	-9999	-9999	-9999	-9999
38837	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	21	8	-9999	-9999
38843	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	42	46
38850	571	81	225	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38856	-9999	-9999	-9999	2722	285	823	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38862	-9999	-9999	-9999	-9999	-9999	-9999	82	19	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38866	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	141	75	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38871	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	1400	45	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38876	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
38882	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	69	27	-9999	-9999	-9999	-9999	-9999	-9999
38889	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	25	11	-9999	-9999	-9999	-9999
38897	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	27	9	-9999	-9999
38903	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	14	47
38910	490	81	227	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999	-9999
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