251 1001 2 | 1 | Krebsbach | Marc | Koppmann | Ralf | Krebsbach | Marc 1 | IAU-BUW (University of Wuppertal, Institute for Atmospheric and Environmental Research, Gaussstr. 20, 42119 Wuppertal, Germany) | m.krebsbach@uni-wuppertal.de | +49-202-439-3503 1 | HALO | MIRAH | Analysis Results of Whole Air Samples collected during EMeRGe-EU-09_20170728 EMeRGe-EU | EMeRGe-EU-09_20170728 1 1 2017 07 28 2020 11 03 0 START_TIME | sample start time | s | elapsed time in seconds past midnight (UTC) | in-situ | plat | S_1 | S_1 136 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. 999999. MEAN_TIME | sample mean time | s | | inst | in-situ | S_1 | S_1 END_TIME | sample end time | s | | inst | in-situ | S_1 | S_1 _1_Pentene_2_4_4_trimethyl__D13C | D13C of _1_Pentene_2_4_4_trimethyl_ | per mill | | anal | user | S_1 | S_1 _1_Pentene_2_4_4_trimethyl__D13C_ERROR | D13C_ERROR of _1_Pentene_2_4_4_trimethyl_ | per mill | | anal | user | S_1 | S_1 _1_Pentene_2_4_4_trimethyl__IRMS_CONC | IRMS_CONC of _1_Pentene_2_4_4_trimethyl_ | pptv | | anal | user | S_1 | S_1 _1_Pentene_2_4_4_trimethyl__IRMS_CONC_ERROR | IRMS_CONC_ERROR of _1_Pentene_2_4_4_trimethyl_ | pptv | | anal | user | S_1 | S_1 _1_Pentene_2_4_4_trimethyl__MSD_CONC | MSD_CONC of _1_Pentene_2_4_4_trimethyl_ _1_Pentene_2_4_4_trimethyl__MSD_CONC_ERROR | MSD_CONC_ERROR of _1_Pentene_2_4_4_trimethyl_ _1_Pentene_2_4_4_trimethyl__FLAG | FLAG of _1_Pentene_2_4_4_trimethyl_ | 1 | | anal | f_X_s | S_1 | S_1 _2_3_Butanedione_D13C | D13C of _2_3_Butanedione | per mill | | anal | user | S_1 | S_1 _2_3_Butanedione_D13C_ERROR | D13C_ERROR of _2_3_Butanedione | per mill | | anal | user | S_1 | S_1 _2_3_Butanedione_IRMS_CONC | IRMS_CONC of _2_3_Butanedione | pptv | | anal | user | S_1 | S_1 _2_3_Butanedione_IRMS_CONC_ERROR | IRMS_CONC_ERROR of _2_3_Butanedione | pptv | | anal | user | S_1 | S_1 _2_3_Butanedione_MSD_CONC | MSD_CONC of _2_3_Butanedione _2_3_Butanedione_MSD_CONC_ERROR | MSD_CONC_ERROR of _2_3_Butanedione _2_3_Butanedione_FLAG | FLAG of _2_3_Butanedione | 1 | | anal | f_X_s | S_1 | S_1 _2_Butanone_D13C | D13C of _2_Butanone | per mill | | anal | user | S_1 | S_1 _2_Butanone_D13C_ERROR | D13C_ERROR of _2_Butanone | per mill | | anal | user | S_1 | S_1 _2_Butanone_IRMS_CONC | IRMS_CONC of _2_Butanone | pptv | | anal | user | S_1 | S_1 _2_Butanone_IRMS_CONC_ERROR | IRMS_CONC_ERROR of _2_Butanone | pptv | | anal | user | S_1 | S_1 _2_Butanone_MSD_CONC | MSD_CONC of _2_Butanone _2_Butanone_MSD_CONC_ERROR | MSD_CONC_ERROR of _2_Butanone _2_Butanone_FLAG | FLAG of _2_Butanone | 1 | | anal | f_X_s | S_1 | S_1 _2_Pentanone_D13C | D13C of _2_Pentanone | per mill | | anal | user | S_1 | S_1 _2_Pentanone_D13C_ERROR | D13C_ERROR of _2_Pentanone | per mill | | anal | user | S_1 | S_1 _2_Pentanone_IRMS_CONC | IRMS_CONC of _2_Pentanone | pptv | | anal | user | S_1 | S_1 _2_Pentanone_IRMS_CONC_ERROR | IRMS_CONC_ERROR of _2_Pentanone | pptv | | anal | user | S_1 | S_1 _2_Pentanone_MSD_CONC | MSD_CONC of _2_Pentanone _2_Pentanone_MSD_CONC_ERROR | MSD_CONC_ERROR of _2_Pentanone _2_Pentanone_FLAG | FLAG of _2_Pentanone | 1 | | anal | f_X_s | S_1 | S_1 _2_Pentene_2_3_4_trimethyl__D13C | D13C of _2_Pentene_2_3_4_trimethyl_ | per mill | | anal | user | S_1 | S_1 _2_Pentene_2_3_4_trimethyl__D13C_ERROR | D13C_ERROR of _2_Pentene_2_3_4_trimethyl_ | per mill | | anal | user | S_1 | S_1 _2_Pentene_2_3_4_trimethyl__IRMS_CONC | IRMS_CONC of _2_Pentene_2_3_4_trimethyl_ | pptv | | anal | user | S_1 | S_1 _2_Pentene_2_3_4_trimethyl__IRMS_CONC_ERROR | IRMS_CONC_ERROR of _2_Pentene_2_3_4_trimethyl_ | pptv | | anal | user | S_1 | S_1 _2_Pentene_2_3_4_trimethyl__MSD_CONC | MSD_CONC of _2_Pentene_2_3_4_trimethyl_ _2_Pentene_2_3_4_trimethyl__MSD_CONC_ERROR | MSD_CONC_ERROR of _2_Pentene_2_3_4_trimethyl_ _2_Pentene_2_3_4_trimethyl__FLAG | FLAG of _2_Pentene_2_3_4_trimethyl_ | 1 | | anal | f_X_s | S_1 | S_1 _3_Heptanone_D13C | D13C of _3_Heptanone | per mill | | anal | user | S_1 | S_1 _3_Heptanone_D13C_ERROR | D13C_ERROR of _3_Heptanone | per mill | | anal | user | S_1 | S_1 _3_Heptanone_IRMS_CONC | IRMS_CONC of _3_Heptanone | pptv | | anal | user | S_1 | S_1 _3_Heptanone_IRMS_CONC_ERROR | IRMS_CONC_ERROR of _3_Heptanone | pptv | | anal | user | S_1 | S_1 _3_Heptanone_MSD_CONC | MSD_CONC of _3_Heptanone _3_Heptanone_MSD_CONC_ERROR | MSD_CONC_ERROR of _3_Heptanone _3_Heptanone_FLAG | FLAG of _3_Heptanone | 1 | | anal | f_X_s | S_1 | S_1 Acetaldehyde_D13C | D13C of Acetaldehyde | per mill | | anal | user | S_1 | S_1 Acetaldehyde_D13C_ERROR | D13C_ERROR of Acetaldehyde | per mill | | anal | user | S_1 | S_1 Acetaldehyde_IRMS_CONC | IRMS_CONC of Acetaldehyde | pptv | | anal | user | S_1 | S_1 Acetaldehyde_IRMS_CONC_ERROR | IRMS_CONC_ERROR of Acetaldehyde | pptv | | anal | user | S_1 | S_1 Acetaldehyde_MSD_CONC | MSD_CONC of Acetaldehyde Acetaldehyde_MSD_CONC_ERROR | MSD_CONC_ERROR of Acetaldehyde Acetaldehyde_FLAG | FLAG of Acetaldehyde | 1 | | anal | f_X_s | S_1 | S_1 Acetone+Propanal_D13C | D13C of Acetone+Propanal | per mill | | anal | user | S_1 | S_1 Acetone+Propanal_D13C_ERROR | D13C_ERROR of Acetone+Propanal | per mill | | anal | user | S_1 | S_1 Acetone+Propanal_IRMS_CONC | IRMS_CONC of Acetone+Propanal | pptv | | anal | user | S_1 | S_1 Acetone+Propanal_IRMS_CONC_ERROR | IRMS_CONC_ERROR of Acetone+Propanal | pptv | | anal | user | S_1 | S_1 Acetone+Propanal_MSD_CONC | MSD_CONC of Acetone+Propanal Acetone+Propanal_MSD_CONC_ERROR | MSD_CONC_ERROR of Acetone+Propanal Acetone+Propanal_FLAG | FLAG of Acetone+Propanal | 1 | | anal | f_X_s | S_1 | S_1 alpha_Methylstyrene_D13C | D13C of alpha_Methylstyrene | per mill | | anal | user | S_1 | S_1 alpha_Methylstyrene_D13C_ERROR | D13C_ERROR of alpha_Methylstyrene | per mill | | anal | user | S_1 | S_1 alpha_Methylstyrene_IRMS_CONC | IRMS_CONC of alpha_Methylstyrene | pptv | | anal | user | S_1 | S_1 alpha_Methylstyrene_IRMS_CONC_ERROR | IRMS_CONC_ERROR of alpha_Methylstyrene | pptv | | anal | user | S_1 | S_1 alpha_Methylstyrene_MSD_CONC | MSD_CONC of alpha_Methylstyrene alpha_Methylstyrene_MSD_CONC_ERROR | MSD_CONC_ERROR of alpha_Methylstyrene alpha_Methylstyrene_FLAG | FLAG of alpha_Methylstyrene | 1 | | anal | f_X_s | S_1 | S_1 Benzene_D13C | D13C of Benzene | per mill | | anal | user | S_1 | S_1 Benzene_D13C_ERROR | D13C_ERROR of Benzene | per mill | | anal | user | S_1 | S_1 Benzene_IRMS_CONC | IRMS_CONC of Benzene | pptv | | anal | user | S_1 | S_1 Benzene_IRMS_CONC_ERROR | IRMS_CONC_ERROR of Benzene | pptv | | anal | user | S_1 | S_1 Benzene_MSD_CONC | MSD_CONC of Benzene Benzene_MSD_CONC_ERROR | MSD_CONC_ERROR of Benzene Benzene_FLAG | FLAG of Benzene | 1 | | anal | f_X_s | S_1 | S_1 Benzene_1_2_4_trimethyl__D13C | D13C of Benzene_1_2_4_trimethyl_ | per mill | | anal | user | S_1 | S_1 Benzene_1_2_4_trimethyl__D13C_ERROR | D13C_ERROR of Benzene_1_2_4_trimethyl_ | per mill | | anal | user | S_1 | S_1 Benzene_1_2_4_trimethyl__IRMS_CONC | IRMS_CONC of Benzene_1_2_4_trimethyl_ | pptv | | anal | user | S_1 | S_1 Benzene_1_2_4_trimethyl__IRMS_CONC_ERROR | IRMS_CONC_ERROR of Benzene_1_2_4_trimethyl_ | pptv | | anal | user | S_1 | S_1 Benzene_1_2_4_trimethyl__MSD_CONC | MSD_CONC of Benzene_1_2_4_trimethyl_ Benzene_1_2_4_trimethyl__MSD_CONC_ERROR | MSD_CONC_ERROR of Benzene_1_2_4_trimethyl_ Benzene_1_2_4_trimethyl__FLAG | FLAG of Benzene_1_2_4_trimethyl_ | 1 | | anal | f_X_s | S_1 | S_1 Butanal_D13C | D13C of Butanal | per mill | | anal | user | S_1 | S_1 Butanal_D13C_ERROR | D13C_ERROR of Butanal | per mill | | anal | user | S_1 | S_1 Butanal_IRMS_CONC | IRMS_CONC of Butanal | pptv | | anal | user | S_1 | S_1 Butanal_IRMS_CONC_ERROR | IRMS_CONC_ERROR of Butanal | pptv | | anal | user | S_1 | S_1 Butanal_MSD_CONC | MSD_CONC of Butanal Butanal_MSD_CONC_ERROR | MSD_CONC_ERROR of Butanal Butanal_FLAG | FLAG of Butanal | 1 | | anal | f_X_s | S_1 | S_1 Formicacid_butylester_D13C | D13C of Formicacid_butylester | per mill | | anal | user | S_1 | S_1 Formicacid_butylester_D13C_ERROR | D13C_ERROR of Formicacid_butylester | per mill | | anal | user | S_1 | S_1 Formicacid_butylester_IRMS_CONC | IRMS_CONC of Formicacid_butylester | pptv | | anal | user | S_1 | S_1 Formicacid_butylester_IRMS_CONC_ERROR | IRMS_CONC_ERROR of Formicacid_butylester | pptv | | anal | user | S_1 | S_1 Formicacid_butylester_MSD_CONC | MSD_CONC of Formicacid_butylester Formicacid_butylester_MSD_CONC_ERROR | MSD_CONC_ERROR of Formicacid_butylester Formicacid_butylester_FLAG | FLAG of Formicacid_butylester | 1 | | anal | f_X_s | S_1 | S_1 Heptanal_D13C | D13C of Heptanal | per mill | | anal | user | S_1 | S_1 Heptanal_D13C_ERROR | D13C_ERROR of Heptanal | per mill | | anal | user | S_1 | S_1 Heptanal_IRMS_CONC | IRMS_CONC of Heptanal | pptv | | anal | user | S_1 | S_1 Heptanal_IRMS_CONC_ERROR | IRMS_CONC_ERROR of Heptanal | pptv | | anal | user | S_1 | S_1 Heptanal_MSD_CONC | MSD_CONC of Heptanal Heptanal_MSD_CONC_ERROR | MSD_CONC_ERROR of Heptanal Heptanal_FLAG | FLAG of Heptanal | 1 | | anal | f_X_s | S_1 | S_1 Hexanal_D13C | D13C of Hexanal | per mill | | anal | user | S_1 | S_1 Hexanal_D13C_ERROR | D13C_ERROR of Hexanal | per mill | | anal | user | S_1 | S_1 Hexanal_IRMS_CONC | IRMS_CONC of Hexanal | pptv | | anal | user | S_1 | S_1 Hexanal_IRMS_CONC_ERROR | IRMS_CONC_ERROR of Hexanal | pptv | | anal | user | S_1 | S_1 Hexanal_MSD_CONC | MSD_CONC of Hexanal Hexanal_MSD_CONC_ERROR | MSD_CONC_ERROR of Hexanal Hexanal_FLAG | FLAG of Hexanal | 1 | | anal | f_X_s | S_1 | S_1 Hexanal_2_ethyl__D13C | D13C of Hexanal_2_ethyl_ | per mill | | anal | user | S_1 | S_1 Hexanal_2_ethyl__D13C_ERROR | D13C_ERROR of Hexanal_2_ethyl_ | per mill | | anal | user | S_1 | S_1 Hexanal_2_ethyl__IRMS_CONC | IRMS_CONC of Hexanal_2_ethyl_ | pptv | | anal | user | S_1 | S_1 Hexanal_2_ethyl__IRMS_CONC_ERROR | IRMS_CONC_ERROR of Hexanal_2_ethyl_ | pptv | | anal | user | S_1 | S_1 Hexanal_2_ethyl__MSD_CONC | MSD_CONC of Hexanal_2_ethyl_ Hexanal_2_ethyl__MSD_CONC_ERROR | MSD_CONC_ERROR of Hexanal_2_ethyl_ Hexanal_2_ethyl__FLAG | FLAG of Hexanal_2_ethyl_ | 1 | | anal | f_X_s | S_1 | S_1 m_p_Xylene_D13C | D13C of m_p_Xylene | per mill | | anal | user | S_1 | S_1 m_p_Xylene_D13C_ERROR | D13C_ERROR of m_p_Xylene | per mill | | anal | user | S_1 | S_1 m_p_Xylene_IRMS_CONC | IRMS_CONC of m_p_Xylene | pptv | | anal | user | S_1 | S_1 m_p_Xylene_IRMS_CONC_ERROR | IRMS_CONC_ERROR of m_p_Xylene | pptv | | anal | user | S_1 | S_1 m_p_Xylene_MSD_CONC | MSD_CONC of m_p_Xylene m_p_Xylene_MSD_CONC_ERROR | MSD_CONC_ERROR of m_p_Xylene m_p_Xylene_FLAG | FLAG of m_p_Xylene | 1 | | anal | f_X_s | S_1 | S_1 Pentanal_D13C | D13C of Pentanal | per mill | | anal | user | S_1 | S_1 Pentanal_D13C_ERROR | D13C_ERROR of Pentanal | per mill | | anal | user | S_1 | S_1 Pentanal_IRMS_CONC | IRMS_CONC of Pentanal | pptv | | anal | user | S_1 | S_1 Pentanal_IRMS_CONC_ERROR | IRMS_CONC_ERROR of Pentanal | pptv | | anal | user | S_1 | S_1 Pentanal_MSD_CONC | MSD_CONC of Pentanal Pentanal_MSD_CONC_ERROR | MSD_CONC_ERROR of Pentanal Pentanal_FLAG | FLAG of Pentanal | 1 | | anal | f_X_s | S_1 | S_1 Toluene_D13C | D13C of Toluene | per mill | | anal | user | S_1 | S_1 Toluene_D13C_ERROR | D13C_ERROR of Toluene | per mill | | anal | user | S_1 | S_1 Toluene_IRMS_CONC | IRMS_CONC of Toluene | pptv | | anal | user | S_1 | S_1 Toluene_IRMS_CONC_ERROR | IRMS_CONC_ERROR of Toluene | pptv | | anal | user | S_1 | S_1 Toluene_MSD_CONC | MSD_CONC of Toluene Toluene_MSD_CONC_ERROR | MSD_CONC_ERROR of Toluene Toluene_FLAG | FLAG of Toluene | 1 | | anal | f_X_s | S_1 | S_1 CYLINDER | CYLINDER 100 data status: preliminary Meaning of compound flag is: 0: not further specified 1: separate peak 2: separate small peak 3: overlapping peak 4: overlapping small peak 5: downslope shoulder peak 6: small downslope shoulder peak 7: upslope shoulder peak 8: small upslope shoulder peak 9: rounded peak 10: small rounded peak 11: fronting peak 12: small fronting peak 13: tailing peak 14: small tailing peak 15: double peak 16: small double peak 17: multiple peak group 18: small multiple peak group 19: invalid peak >100: unconfident (= 100 + flag-ID) (in case of double peak IRMS_CONC is unfaithful and MSD_CONC should be used if available) Level of Detection (1-Pentene, 2,4,4-trimethyl-, IRMS) = -999999. in pptV Level of Determination (1-Pentene, 2,4,4-trimethyl-, IRMS) = -999999. in pptV Level of Detection (2,3-Butanedione, IRMS) = -999999. in pptV Level of Determination (2,3-Butanedione, IRMS) = -999999. in pptV Level of Detection (2-Butanone, IRMS) = -999999. in pptV Level of Determination (2-Butanone, IRMS) = -999999. in pptV Level of Detection (2-Pentanone, IRMS) = -999999. in pptV Level of Determination (2-Pentanone, IRMS) = -999999. in pptV Level of Detection (2-Pentene, 2,3,4-trimethyl-, IRMS) = -999999. in pptV Level of Determination (2-Pentene, 2,3,4-trimethyl-, IRMS) = -999999. in pptV Level of Detection (3-Heptanone, IRMS) = -999999. in pptV Level of Determination (3-Heptanone, IRMS) = -999999. in pptV Level of Detection (Acetaldehyde, IRMS) = 76.93 in pptV for quantile 0.100 (90.0%) Level of Determination (Acetaldehyde, IRMS) = 147.67 in pptV for quantile 0.100 (90.0%) Level of Detection (Acetone+Propanal, IRMS) = -999999. in pptV Level of Determination (Acetone+Propanal, IRMS) = -999999. in pptV Level of Detection (alpha-Methylstyrene, IRMS) = -999999. in pptV Level of Determination (alpha-Methylstyrene, IRMS) = -999999. in pptV Level of Detection (Benzene, IRMS) = 15.49 in pptV for quantile 0.100 (90.0%) Level of Determination (Benzene, IRMS) = 29.52 in pptV for quantile 0.100 (90.0%) Level of Detection (Benzene, 1,2,4-trimethyl-, IRMS) = -999999. in pptV Level of Determination (Benzene, 1,2,4-trimethyl-, IRMS) = -999999. in pptV Level of Detection (Butanal, IRMS) = 29.24 in pptV for quantile 0.100 (90.0%) Level of Determination (Butanal, IRMS) = 56.39 in pptV for quantile 0.100 (90.0%) Level of Detection (Formic acid, butyl ester, IRMS) = -999999. in pptV Level of Determination (Formic acid, butyl ester, IRMS) = -999999. in pptV Level of Detection (Heptanal, IRMS) = -999999. in pptV Level of Determination (Heptanal, IRMS) = -999999. in pptV Level of Detection (Hexanal, IRMS) = 42.46 in pptV for quantile 0.100 (90.0%) Level of Determination (Hexanal, IRMS) = 79.30 in pptV for quantile 0.100 (90.0%) Level of Detection (Hexanal, 2-ethyl-, IRMS) = -999999. in pptV Level of Determination (Hexanal, 2-ethyl-, IRMS) = -999999. in pptV Level of Detection (m/p-Xylene, IRMS) = -999999. in pptV Level of Determination (m/p-Xylene, IRMS) = -999999. in pptV Level of Detection (Pentanal, IRMS) = 45.45 in pptV for quantile 0.100 (90.0%) Level of Determination (Pentanal, IRMS) = 86.09 in pptV for quantile 0.100 (90.0%) Level of Detection (Toluene, IRMS) = 21.86 in pptV for quantile 0.100 (90.0%) Level of Determination (Toluene, IRMS) = 40.37 in pptV for quantile 0.100 (90.0%) Level of Detection (1-Pentene, 2,4,4-trimethyl-, MSD) = -999999. in pptV Level of Determination (1-Pentene, 2,4,4-trimethyl-, MSD) = -999999. in pptV Level of Detection (2,3-Butanedione, MSD) = -999999. in pptV Level of Determination (2,3-Butanedione, MSD) = -999999. in pptV Level of Detection (2-Butanone, MSD) = -999999. in pptV Level of Determination (2-Butanone, MSD) = -999999. in pptV Level of Detection (2-Pentanone, MSD) = -999999. in pptV Level of Determination (2-Pentanone, MSD) = -999999. in pptV Level of Detection (2-Pentene, 2,3,4-trimethyl-, MSD) = -999999. in pptV Level of Determination (2-Pentene, 2,3,4-trimethyl-, MSD) = -999999. in pptV Level of Detection (3-Heptanone, MSD) = -999999. in pptV Level of Determination (3-Heptanone, MSD) = -999999. in pptV Level of Detection (Acetaldehyde, MSD) = 172.97 in pptV for quantile 0.100 (90.0%) Level of Determination (Acetaldehyde, MSD) = 315.80 in pptV for quantile 0.100 (90.0%) Level of Detection (Acetone+Propanal, MSD) = -999999. in pptV Level of Determination (Acetone+Propanal, MSD) = -999999. in pptV Level of Detection (alpha-Methylstyrene, MSD) = -999999. in pptV Level of Determination (alpha-Methylstyrene, MSD) = -999999. in pptV Level of Detection (Benzene, MSD) = 24.02 in pptV for quantile 0.100 (90.0%) Level of Determination (Benzene, MSD) = 44.55 in pptV for quantile 0.100 (90.0%) Level of Detection (Benzene, 1,2,4-trimethyl-, MSD) = -999999. in pptV Level of Determination (Benzene, 1,2,4-trimethyl-, MSD) = -999999. in pptV Level of Detection (Butanal, MSD) = 52.51 in pptV for quantile 0.100 (90.0%) Level of Determination (Butanal, MSD) = 98.36 in pptV for quantile 0.100 (90.0%) Level of Detection (Formic acid, butyl ester, MSD) = -999999. in pptV Level of Determination (Formic acid, butyl ester, MSD) = -999999. in pptV Level of Detection (Heptanal, MSD) = -999999. in pptV Level of Determination (Heptanal, MSD) = -999999. in pptV Level of Detection (Hexanal, MSD) = 57.19 in pptV for quantile 0.100 (90.0%) Level of Determination (Hexanal, MSD) = 104.34 in pptV for quantile 0.100 (90.0%) Level of Detection (Hexanal, 2-ethyl-, MSD) = -999999. in pptV Level of Determination (Hexanal, 2-ethyl-, MSD) = -999999. in pptV Level of Detection (m/p-Xylene, MSD) = -999999. in pptV Level of Determination (m/p-Xylene, MSD) = -999999. in pptV Level of Detection (Pentanal, MSD) = 72.35 in pptV for quantile 0.100 (90.0%) Level of Determination (Pentanal, MSD) = 132.73 in pptV for quantile 0.100 (90.0%) Level of Detection (Toluene, MSD) = 26.14 in pptV for quantile 0.100 (90.0%) Level of Determination (Toluene, MSD) = 47.48 in pptV for quantile 0.100 (90.0%) 1 START_TIME MEAN_TIME END_TIME _1_Pentene_2_4_4_trimethyl__D13C _1_Pentene_2_4_4_trimethyl__D13C_ERROR _1_Pentene_2_4_4_trimethyl__IRMS_CONC _1_Pentene_2_4_4_trimethyl__IRMS_CONC_ERROR _1_Pentene_2_4_4_trimethyl__MSD_CONC _1_Pentene_2_4_4_trimethyl__MSD_CONC_ERROR _1_Pentene_2_4_4_trimethyl__FLAG _2_3_Butanedione_D13C _2_3_Butanedione_D13C_ERROR _2_3_Butanedione_IRMS_CONC _2_3_Butanedione_IRMS_CONC_ERROR _2_3_Butanedione_MSD_CONC _2_3_Butanedione_MSD_CONC_ERROR _2_3_Butanedione_FLAG _2_Butanone_D13C _2_Butanone_D13C_ERROR _2_Butanone_IRMS_CONC _2_Butanone_IRMS_CONC_ERROR _2_Butanone_MSD_CONC _2_Butanone_MSD_CONC_ERROR _2_Butanone_FLAG _2_Pentanone_D13C _2_Pentanone_D13C_ERROR _2_Pentanone_IRMS_CONC _2_Pentanone_IRMS_CONC_ERROR _2_Pentanone_MSD_CONC _2_Pentanone_MSD_CONC_ERROR _2_Pentanone_FLAG _2_Pentene_2_3_4_trimethyl__D13C _2_Pentene_2_3_4_trimethyl__D13C_ERROR _2_Pentene_2_3_4_trimethyl__IRMS_CONC _2_Pentene_2_3_4_trimethyl__IRMS_CONC_ERROR _2_Pentene_2_3_4_trimethyl__MSD_CONC _2_Pentene_2_3_4_trimethyl__MSD_CONC_ERROR _2_Pentene_2_3_4_trimethyl__FLAG _3_Heptanone_D13C _3_Heptanone_D13C_ERROR _3_Heptanone_IRMS_CONC _3_Heptanone_IRMS_CONC_ERROR _3_Heptanone_MSD_CONC _3_Heptanone_MSD_CONC_ERROR _3_Heptanone_FLAG Acetaldehyde_D13C Acetaldehyde_D13C_ERROR Acetaldehyde_IRMS_CONC Acetaldehyde_IRMS_CONC_ERROR Acetaldehyde_MSD_CONC Acetaldehyde_MSD_CONC_ERROR Acetaldehyde_FLAG Acetone+Propanal_D13C Acetone+Propanal_D13C_ERROR Acetone+Propanal_IRMS_CONC Acetone+Propanal_IRMS_CONC_ERROR Acetone+Propanal_MSD_CONC Acetone+Propanal_MSD_CONC_ERROR Acetone+Propanal_FLAG alpha_Methylstyrene_D13C alpha_Methylstyrene_D13C_ERROR alpha_Methylstyrene_IRMS_CONC alpha_Methylstyrene_IRMS_CONC_ERROR alpha_Methylstyrene_MSD_CONC alpha_Methylstyrene_MSD_CONC_ERROR alpha_Methylstyrene_FLAG Benzene_D13C Benzene_D13C_ERROR Benzene_IRMS_CONC Benzene_IRMS_CONC_ERROR Benzene_MSD_CONC Benzene_MSD_CONC_ERROR Benzene_FLAG Benzene_1_2_4_trimethyl__D13C Benzene_1_2_4_trimethyl__D13C_ERROR Benzene_1_2_4_trimethyl__IRMS_CONC Benzene_1_2_4_trimethyl__IRMS_CONC_ERROR Benzene_1_2_4_trimethyl__MSD_CONC Benzene_1_2_4_trimethyl__MSD_CONC_ERROR Benzene_1_2_4_trimethyl__FLAG Butanal_D13C Butanal_D13C_ERROR Butanal_IRMS_CONC Butanal_IRMS_CONC_ERROR Butanal_MSD_CONC Butanal_MSD_CONC_ERROR Butanal_FLAG Formicacid_butylester_D13C Formicacid_butylester_D13C_ERROR Formicacid_butylester_IRMS_CONC Formicacid_butylester_IRMS_CONC_ERROR Formicacid_butylester_MSD_CONC Formicacid_butylester_MSD_CONC_ERROR Formicacid_butylester_FLAG Heptanal_D13C Heptanal_D13C_ERROR Heptanal_IRMS_CONC Heptanal_IRMS_CONC_ERROR Heptanal_MSD_CONC Heptanal_MSD_CONC_ERROR Heptanal_FLAG Hexanal_D13C Hexanal_D13C_ERROR Hexanal_IRMS_CONC Hexanal_IRMS_CONC_ERROR Hexanal_MSD_CONC Hexanal_MSD_CONC_ERROR Hexanal_FLAG Hexanal_2_ethyl__D13C Hexanal_2_ethyl__D13C_ERROR Hexanal_2_ethyl__IRMS_CONC Hexanal_2_ethyl__IRMS_CONC_ERROR Hexanal_2_ethyl__MSD_CONC Hexanal_2_ethyl__MSD_CONC_ERROR Hexanal_2_ethyl__FLAG m_p_Xylene_D13C m_p_Xylene_D13C_ERROR m_p_Xylene_IRMS_CONC m_p_Xylene_IRMS_CONC_ERROR m_p_Xylene_MSD_CONC m_p_Xylene_MSD_CONC_ERROR m_p_Xylene_FLAG Pentanal_D13C Pentanal_D13C_ERROR Pentanal_IRMS_CONC Pentanal_IRMS_CONC_ERROR Pentanal_MSD_CONC Pentanal_MSD_CONC_ERROR Pentanal_FLAG Toluene_D13C Toluene_D13C_ERROR Toluene_IRMS_CONC Toluene_IRMS_CONC_ERROR Toluene_MSD_CONC Toluene_MSD_CONC_ERROR Toluene_FLAG CYLINDER 39811. 39876. 39940. -25.9 0.2 999999.0 999999.0 999999.0 999999.0 1 -25.2 0.6 999999.0 999999.0 999999.0 999999.0 18 -32.6 0.2 935.1 25.7 985.1 66.5 1 -30.9 0.5 999999.0 999999.0 999999.0 999999.0 4 -26.6 0.3 999999.0 999999.0 999999.0 999999.0 4 -30.7 0.2 999999.0 999999.0 999999.0 999999.0 2 -36.8 0.2 35183.8 1631.3 30952.5 3417.6 3 -17.7 0.7 999999.0 999999.0 999999.0 999999.0 17 -22.0 0.2 999999.0 999999.0 999999.0 999999.0 1 -28.8 1.4 74.0 12.0 94.5 17.1 4 -30.4 0.8 999999.0 999999.0 999999.0 999999.0 4 -33.5 0.2 1688.7 49.7 1601.5 85.5 1 -35.0 0.4 999999.0 999999.0 999999.0 999999.0 2 -30.1 0.4 999999.0 999999.0 999999.0 999999.0 2 -30.0 0.2 520.1 21.4 579.6 32.1 1 -29.1 0.5 999999.0 999999.0 999999.0 999999.0 2 -24.7 1.9 21.6 29.9 57.8 26.0 4 -32.2 0.2 853.9 27.2 883.6 46.8 1 -29.7 0.3 257.9 12.2 349.3 22.6 103 85 41012. 41057. 41102. -26.6 0.2 999999.0 999999.0 999999.0 999999.0 1 -999999.0 999999.0 999999.0 999999.0 999999.0 999999.0 118 -31.0 0.3 537.2 12.9 559.4 30.7 2 -30.9 0.6 999999.0 999999.0 999999.0 999999.0 4 -27.5 0.3 999999.0 999999.0 999999.0 999999.0 4 -31.0 0.3 999999.0 999999.0 999999.0 999999.0 2 -32.3 0.2 19038.1 851.6 18061.9 1931.9 3 -21.7 0.4 999999.0 999999.0 999999.0 999999.0 17 -22.4 0.1 999999.0 999999.0 999999.0 999999.0 1 -31.8 1.5 59.6 12.7 81.2 18.0 4 -25.4 1.3 999999.0 999999.0 999999.0 999999.0 4 -32.6 0.2 1034.5 23.9 942.4 38.5 1 -35.8 0.4 999999.0 999999.0 999999.0 999999.0 2 -28.6 0.6 999999.0 999999.0 999999.0 999999.0 2 -29.9 0.2 445.4 20.6 472.0 28.0 1 -29.9 0.5 999999.0 999999.0 999999.0 999999.0 2 -24.5 2.7 18.3 30.4 55.2 26.4 4 -31.7 0.2 539.8 22.7 546.6 35.6 1 -30.1 0.3 180.8 10.7 234.5 13.4 103 86 41836. 41878. 41920. -26.7 0.2 999999.0 999999.0 999999.0 999999.0 1 -21.3 1.5 999999.0 999999.0 999999.0 999999.0 118 -32.9 0.3 681.1 16.1 669.5 37.3 2 -32.8 1.0 999999.0 999999.0 999999.0 999999.0 4 -27.2 0.3 999999.0 999999.0 999999.0 999999.0 4 -30.7 0.3 999999.0 999999.0 999999.0 999999.0 4 -31.2 0.2 64205.5 3032.4 54068.2 6082.8 3 -16.0 1.1 999999.0 999999.0 999999.0 999999.0 17 -23.2 0.2 999999.0 999999.0 999999.0 999999.0 1 -30.4 1.3 76.2 11.9 81.9 18.0 4 -23.0 3.6 999999.0 999999.0 999999.0 999999.0 4 -32.5 0.2 2404.0 79.9 2309.4 140.6 1 -33.4 0.4 999999.0 999999.0 999999.0 999999.0 2 -31.1 0.2 999999.0 999999.0 999999.0 999999.0 1 -30.1 0.2 1863.0 120.1 1988.2 181.0 1 -31.0 0.4 999999.0 999999.0 999999.0 999999.0 2 -29.9 21.8 15.6 30.8 53.9 26.6 104 -32.2 0.2 2042.5 96.6 2061.0 161.8 1 -30.4 0.6 127.7 12.6 174.1 12.7 104 87 46714. 46773. 46832. -26.3 0.2 999999.0 999999.0 999999.0 999999.0 1 -23.0 0.9 999999.0 999999.0 999999.0 999999.0 18 -33.5 0.3 636.3 14.8 602.6 32.9 2 -31.1 0.8 999999.0 999999.0 999999.0 999999.0 4 -27.0 0.3 999999.0 999999.0 999999.0 999999.0 4 -30.4 0.3 999999.0 999999.0 999999.0 999999.0 4 -34.0 0.2 31783.1 1466.4 27756.7 3049.2 3 -19.4 0.6 999999.0 999999.0 999999.0 999999.0 17 -22.3 0.1 999999.0 999999.0 999999.0 999999.0 1 -34.3 2.1 49.9 13.1 67.0 19.0 104 -29.5 0.7 999999.0 999999.0 999999.0 999999.0 4 -33.0 0.2 1197.6 29.9 971.7 40.3 1 -36.0 0.5 999999.0 999999.0 999999.0 999999.0 2 -29.4 0.3 999999.0 999999.0 999999.0 999999.0 2 -29.9 0.2 500.5 21.0 499.4 28.6 1 -31.1 0.3 999999.0 999999.0 999999.0 999999.0 2 -32.6 2.3 19.8 30.2 56.0 26.3 4 -32.5 0.2 637.4 22.2 583.6 35.2 1 -32.3 0.7 113.5 13.4 151.0 13.5 104 88 49703. 49768. 49833. -25.9 0.2 999999.0 999999.0 999999.0 999999.0 1 -28.3 0.5 999999.0 999999.0 999999.0 999999.0 18 -32.1 0.2 1199.0 37.2 1325.0 102.8 1 -30.3 0.5 999999.0 999999.0 999999.0 999999.0 4 -26.2 0.3 999999.0 999999.0 999999.0 999999.0 4 -31.4 0.4 999999.0 999999.0 999999.0 999999.0 4 -36.3 0.2 49800.3 2336.8 42812.1 4784.9 3 -19.6 0.7 999999.0 999999.0 999999.0 999999.0 17 -22.2 0.2 999999.0 999999.0 999999.0 999999.0 1 -30.9 1.2 69.8 12.2 86.7 17.6 4 -27.8 3.6 999999.0 999999.0 999999.0 999999.0 4 -33.0 0.2 1956.9 60.9 1875.5 106.6 1 -34.5 0.6 999999.0 999999.0 999999.0 999999.0 2 -27.3 0.6 999999.0 999999.0 999999.0 999999.0 2 -29.6 0.2 571.8 22.9 639.1 36.0 1 -33.5 1.4 999999.0 999999.0 999999.0 999999.0 104 -26.3 6.1 14.6 30.9 53.5 26.6 4 -31.7 0.2 978.0 32.6 1018.7 57.5 1 -30.4 0.6 100.9 14.2 149.8 13.6 104 89 50685. 50730. 50775. -26.6 0.2 999999.0 999999.0 999999.0 999999.0 1 -25.4 0.5 999999.0 999999.0 999999.0 999999.0 18 -29.0 0.5 661.9 15.5 713.3 40.7 2 -30.3 0.5 999999.0 999999.0 999999.0 999999.0 4 -26.1 0.3 999999.0 999999.0 999999.0 999999.0 103 -29.3 0.5 999999.0 999999.0 999999.0 999999.0 18 -32.6 0.2 28044.3 1286.6 24379.4 2659.9 3 -20.2 0.5 999999.0 999999.0 999999.0 999999.0 17 -21.8 0.2 999999.0 999999.0 999999.0 999999.0 1 -28.9 1.2 71.2 12.2 75.6 18.4 4 -999999.0 999999.0 999999.0 999999.0 999999.0 999999.0 104 -31.8 0.3 1176.8 29.1 1064.5 46.3 1 -34.5 1.4 999999.0 999999.0 999999.0 999999.0 2 -29.3 0.6 999999.0 999999.0 999999.0 999999.0 2 -29.8 0.2 545.8 22.1 606.9 33.8 1 -30.1 1.1 999999.0 999999.0 999999.0 999999.0 2 -999999.0 999999.0 13.0 31.1 52.4 26.8 104 -31.7 0.2 747.8 23.9 771.8 39.9 1 -31.0 0.6 103.6 14.0 150.9 13.5 104 90 51096. 51141. 51186. -26.3 0.2 999999.0 999999.0 999999.0 999999.0 1 -29.0 0.4 999999.0 999999.0 999999.0 999999.0 18 -32.0 0.2 911.8 24.7 968.4 64.8 1 -30.0 0.5 999999.0 999999.0 999999.0 999999.0 2 -25.2 0.3 999999.0 999999.0 999999.0 999999.0 4 -29.9 0.4 999999.0 999999.0 999999.0 999999.0 4 -34.9 0.2 34652.8 1604.8 29433.1 3242.4 3 -19.4 0.6 999999.0 999999.0 999999.0 999999.0 17 -22.0 0.2 999999.0 999999.0 999999.0 999999.0 1 -28.8 2.0 40.6 13.6 63.1 19.3 4 -34.0 5.5 999999.0 999999.0 999999.0 999999.0 4 -32.8 0.2 1522.6 42.8 1367.3 67.9 1 -34.5 0.4 999999.0 999999.0 999999.0 999999.0 2 -29.4 0.7 999999.0 999999.0 999999.0 999999.0 2 -29.8 0.2 435.5 20.6 455.3 27.9 1 -31.4 0.9 999999.0 999999.0 999999.0 999999.0 2 -999999.0 999999.0 12.8 31.2 52.2 26.8 104 -31.8 0.2 700.6 22.9 684.4 36.4 1 -32.5 1.0 69.3 16.4 107.9 16.2 104 91 51685. 51727. 51768. -26.2 0.2 999999.0 999999.0 999999.0 999999.0 1 -26.2 0.6 999999.0 999999.0 999999.0 999999.0 18 -32.5 0.3 929.9 25.7 863.5 54.5 2 -31.6 0.9 999999.0 999999.0 999999.0 999999.0 2 -27.3 0.3 999999.0 999999.0 999999.0 999999.0 4 -27.6 0.6 999999.0 999999.0 999999.0 999999.0 18 -35.7 0.2 41352.7 1939.0 35432.1 3943.5 3 -20.4 0.6 999999.0 999999.0 999999.0 999999.0 17 -22.2 0.2 999999.0 999999.0 999999.0 999999.0 1 -25.0 1.8 78.5 11.9 86.9 17.6 4 -29.8 1.4 999999.0 999999.0 999999.0 999999.0 104 -32.5 0.3 1508.7 42.6 1217.4 57.2 1 -33.7 0.5 999999.0 999999.0 999999.0 999999.0 2 -28.8 1.2 999999.0 999999.0 999999.0 999999.0 2 -30.4 0.2 622.7 25.3 598.5 33.3 1 -999999.0 999999.0 999999.0 999999.0 999999.0 999999.0 102 -25.4 2.6 23.3 29.7 56.6 26.2 4 -31.5 0.2 814.3 26.0 702.5 37.1 1 -29.0 0.9 91.9 14.8 122.9 15.2 104 92 54422. 54464. 54506. -25.5 0.2 999999.0 999999.0 999999.0 999999.0 1 -28.4 0.6 999999.0 999999.0 999999.0 999999.0 18 -32.0 0.3 690.8 16.5 697.4 39.5 2 -31.6 0.6 999999.0 999999.0 999999.0 999999.0 2 -27.1 0.3 999999.0 999999.0 999999.0 999999.0 4 -30.4 0.9 999999.0 999999.0 999999.0 999999.0 18 -34.3 0.2 28346.7 1303.5 24084.8 2628.2 3 -17.8 0.8 999999.0 999999.0 999999.0 999999.0 17 -21.9 0.2 999999.0 999999.0 999999.0 999999.0 1 -27.9 1.9 39.7 13.6 58.6 19.7 4 -999999.0 999999.0 999999.0 999999.0 999999.0 999999.0 102 -31.2 0.2 1921.8 59.6 1683.7 92.0 1 -33.7 0.4 999999.0 999999.0 999999.0 999999.0 2 -29.2 1.2 999999.0 999999.0 999999.0 999999.0 2 -27.7 0.2 575.8 23.1 627.9 35.2 1 -999999.0 999999.0 999999.0 999999.0 999999.0 999999.0 102 -999999.0 999999.0 12.3 31.2 51.9 26.9 104 -31.8 0.2 1454.7 59.7 1473.8 101.0 1 -29.8 1.1 75.5 16.0 108.9 16.2 104 93 55204. 55254. 55304. -25.8 0.2 999999.0 999999.0 999999.0 999999.0 1 -25.8 0.7 999999.0 999999.0 999999.0 999999.0 18 -31.1 0.3 814.1 20.8 862.2 54.2 1 -30.1 0.4 999999.0 999999.0 999999.0 999999.0 2 -26.0 0.3 999999.0 999999.0 999999.0 999999.0 4 -29.1 0.6 999999.0 999999.0 999999.0 999999.0 18 -32.6 0.2 29965.3 1379.1 25441.6 2782.3 3 -21.4 0.4 999999.0 999999.0 999999.0 999999.0 17 -21.9 0.2 999999.0 999999.0 999999.0 999999.0 1 -27.0 1.4 51.1 13.1 71.6 18.7 4 -22.5 6.7 999999.0 999999.0 999999.0 999999.0 4 -32.2 0.2 1180.2 29.2 1041.8 44.8 1 -35.0 0.5 999999.0 999999.0 999999.0 999999.0 2 -27.6 0.9 999999.0 999999.0 999999.0 999999.0 2 -29.5 0.2 440.5 20.6 485.8 28.3 1 -27.8 2.2 999999.0 999999.0 999999.0 999999.0 104 -999999.0 999999.0 12.9 31.2 52.2 26.8 104 -31.4 0.2 611.1 22.2 633.1 35.4 1 -26.4 0.9 84.8 15.3 123.4 15.1 104 94 57428. 57490. 57551. -25.6 0.2 999999.0 999999.0 999999.0 999999.0 1 -999999.0 999999.0 999999.0 999999.0 999999.0 999999.0 118 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