72 1001 Markus Jesswein, Thomas Wagenhaeuser, Timo Keber, Tanja Schuck, Andreas Engel Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Altenhoeferallee 1, 60438 Frankfurt/Main, Germany 1 | HALO | GhOST-MS | mixing ratios of long-lived and very short-lived tracers measured with an in-situ GC-MS instrument SOUTHTRAC 1 1 2019 10 07 2020 08 24 0 Mean sample time in UT seconds past midnight of flight date 25 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 C2Cl4 [ppt] C2H3Cl3 [ppt] CCl4 [ppt] CFC11 [ppt] CFC113 [ppt] CFC114 [ppt] CFC115 [ppt] CFC12 [ppt] CH2Br2 [ppt] CH2Cl2 [ppt] CH3Br [ppt] CH3Cl [ppt] CH3I [ppt] CHBr2Cl [ppt] CHBr3 [ppt] CHCl3 [ppt] H1211 [ppt] H1301 [ppt] H2402 [ppt] HCFC141b [ppt] HCFC142b [ppt] HCFC22 [ppt] HFC125 [ppt] HFC134a [s] HFC143a [s] 31 ------------------------------------------------------------------------ Please inform the authors about the use of the data Before publication, the authors of the data have to give their consent Please adhere in all cases to the SOUTHTRAC data protocol Contact: Andreas Engel (an.engel@iau.uni-frankfurt.de, phone +49 69 798 40259) ------------------------------------------------------------------------ Calibration Scale, Precision, Accuracy and Detection Limit are given separately for each dependent variable Primary calibration reference flasks: AGAGE H-218 (all other scales) Calibration Scales NOAA-2003B SIO-05 SIO-05 SIO-05 SIO-05 SIO-05 SIO-05 SIO-05 NOAA-2003 SIO-14 SIO-05 SIO-05 NOAA-2004 UEA-11 NOAA-2003 SIO-05 SIO-05 SIO-05 SIO-14 SIO-05 SIO-05 SIO-05 SIO-14 SIO-05 SIO-07 ------------------------------------------------------------------------ Instrument precision in [%] 0.0131 0.0867 0.0044 0.0022 0.0064 0.0073 0.0140 0.0030 0.0259 0.0078 0.0169 0.0039 0.0675 0.0891 0.0282 0.0095 0.0278 0.0383 0.0579 0.0082 0.0084 0.0041 0.0079 0.0049 0.0167 Instrument precision in [ppt] 0.0800 0.1527 0.3524 0.5192 0.4049 0.1199 0.1238 1.5384 0.0330 0.5550 0.1154 2.7873 0.0186 0.0677 0.0492 0.1397 0.0929 0.1349 0.0226 0.2095 0.1932 1.0807 0.3451 1.7285 0.43155 Use whatever precision is larger for each data point ------------------------------------------------------------------------ Accuracy of mixing ratios in calibration gas in [%] NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN ------------------------------------------------------------------------ Detection limit (S/N 3/1) in [ppt] per 400 mL air at STP 0.11162 0.53190 0.19529 0.35685 0.18416 0.11912 0.32568 0.47153 0.11040 0.45926 0.30992 3.50523 0.07732 0.74990 0.24115 0.65568 0.25124 0.93355 0.08583 0.39324 0.4981 1.30346 0.625 0.76391 1.86463 Values below detection limit are marked as 0.00 In case no measurements are available, the missing data value is used ------------------------------------------------------------------------ Sample integration time: 147 +- 1 seconds Values of t_sample are the mean of the sampling time interval (integration time) ------------------------------------------------------------------------ Correction of analyte carry-over (memory effect): below measurement precision for all substances, no correction applied Detector non-linearity: below measurement precision for all substances, no correction applied ------------------------------------------------------------------------ 2 TIME C2Cl4 C2H3Cl3 CCl4 CFC11 CFC113 CFC114 CFC115 CFC12 CH2Br2 CH2Cl2 CH3Br CH3Cl CH3I CHBr2Cl CHBr3 CHCl3 H1211 H1301 H2402 HCFC141b HCFC142b HCFC22 HFC125 HFC134a HFC143a [s] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [s] [s] 56569.0 0.845 1.507 76.803 222.017 99999.000 99999.000 99999.000 501.330 0.993 30.712 9.502 608.802 0.559 0.430 0.801 8.825 5.874 3.205 0.368 23.010 21.851 239.715 32.326 102.768 99999.000 56922.0 0.660 1.155 78.250 224.166 69.027 99999.000 99999.000 505.602 0.938 21.511 6.518 571.791 0.137 0.231 0.503 6.965 3.401 3.333 0.392 23.884 22.080 239.858 29.077 103.184 99999.000 57627.0 0.462 1.156 78.256 224.954 99999.000 99999.000 99999.000 508.184 0.873 22.052 6.512 553.475 0.127 0.239 0.393 99999.000 3.418 3.248 0.360 23.844 21.624 241.724 29.450 101.910 99999.000 57980.0 0.373 1.128 76.507 224.319 68.839 99999.000 99999.000 505.257 0.784 25.791 6.873 564.490 0.074 0.161 0.214 99999.000 3.434 3.174 0.369 23.562 21.893 245.028 29.779 101.875 99999.000 58333.0 0.231 1.117 72.538 210.706 65.245 99999.000 99999.000 483.528 0.640 29.947 6.802 557.165 99999.000 0.108 0.098 99999.000 3.317 3.036 0.339 23.266 21.242 241.702 27.985 97.032 99999.000 58685.0 0.176 1.013 71.230 208.935 64.406 99999.000 99999.000 477.765 0.597 28.875 6.745 547.782 99999.000 0.043 0.064 99999.000 3.234 3.026 0.329 22.866 20.900 238.726 28.699 99999.000 99999.000 59388.0 0.293 1.093 74.500 217.239 99999.000 99999.000 99999.000 495.283 0.612 31.054 6.742 546.399 0.038 99999.000 0.065 99999.000 3.340 3.223 0.376 23.734 21.657 242.913 28.461 101.562 99999.000 59741.0 0.371 1.124 78.632 228.566 70.195 99999.000 99999.000 513.506 0.714 32.843 6.945 564.753 0.032 0.126 0.089 5.478 3.333 3.171 0.385 24.783 21.928 249.009 29.119 106.421 99999.000 60093.0 0.420 1.179 78.419 227.470 69.110 99999.000 99999.000 510.069 0.741 34.171 6.996 566.918 0.054 0.151 0.079 6.054 3.308 3.144 0.392 24.058 21.501 247.778 29.085 106.221 99999.000 60447.0 0.416 1.122 77.568 225.434 69.107 99999.000 99999.000 507.841 0.721 34.206 6.896 560.118 0.058 99999.000 0.114 6.158 3.234 3.229 0.367 24.356 21.439 247.518 28.672 105.262 99999.000 61151.0 0.444 1.178 77.803 226.262 99999.000 99999.000 99999.000 506.335 0.768 31.136 7.077 565.805 0.054 0.226 0.200 4.911 3.343 3.038 0.362 23.841 21.401 246.227 29.728 104.806 99999.000 61503.0 0.479 1.151 78.068 225.955 68.600 99999.000 99999.000 505.959 0.814 29.438 7.001 571.863 99999.000 0.154 0.242 6.199 3.377 3.016 0.363 23.906 21.429 243.814 29.316 103.832 99999.000 61856.0 0.475 1.113 77.536 226.385 68.440 99999.000 99999.000 507.388 0.868 27.618 6.876 563.268 0.058 0.219 0.333 5.607 3.292 3.047 0.362 23.474 21.383 246.906 29.914 105.014 99999.000 62209.0 0.516 1.113 78.074 227.640 68.269 99999.000 99999.000 507.027 0.875 27.269 6.924 559.724 0.031 0.224 0.370 5.865 3.320 3.167 0.371 23.863 21.941 247.483 29.991 105.214 99999.000 62912.0 0.492 1.134 78.039 225.092 99999.000 99999.000 99999.000 503.855 0.773 25.613 7.055 594.148 0.098 0.166 0.309 4.943 3.366 3.171 0.357 23.794 21.697 244.972 29.885 104.903 99999.000 63264.0 0.460 1.117 77.373 223.387 68.266 99999.000 99999.000 498.240 0.717 25.134 7.324 598.181 0.075 0.169 0.274 6.403 3.365 2.989 0.361 23.555 21.363 241.679 29.854 105.302 99999.000 63616.0 0.442 1.144 79.735 233.024 69.690 99999.000 99999.000 516.368 0.729 24.027 7.792 629.359 0.087 0.197 0.245 6.275 3.376 3.268 0.392 24.125 21.811 247.100 30.366 106.311 99999.000 63970.0 0.479 1.088 79.000 230.447 69.728 99999.000 99999.000 514.117 0.770 24.148 7.783 642.020 0.079 0.164 0.273 6.245 3.368 3.156 0.370 23.994 21.759 244.787 29.986 106.585 99999.000 64322.0 0.406 1.122 78.691 229.288 69.287 99999.000 99999.000 511.819 0.716 23.931 7.578 621.268 0.072 0.158 0.221 6.514 3.350 3.399 0.372 23.783 22.060 245.568 30.033 105.413 99999.000 64675.0 0.417 1.128 78.127 227.236 68.892 99999.000 99999.000 509.429 0.733 23.814 7.553 632.696 0.069 0.125 0.238 6.396 3.399 3.418 0.377 23.495 21.820 242.892 29.447 106.218 99999.000 65378.0 0.439 1.147 77.975 226.295 99999.000 99999.000 99999.000 505.170 0.701 23.728 7.415 618.706 0.105 0.165 0.219 6.536 3.390 3.217 0.376 23.381 21.991 242.267 29.461 104.506 99999.000 65731.0 0.453 1.109 77.597 226.879 68.228 99999.000 99999.000 507.395 0.695 23.633 7.371 612.361 0.087 0.125 0.217 6.104 3.416 3.095 0.367 23.434 21.686 243.974 29.510 104.216 99999.000 66084.0 0.425 1.125 77.613 226.250 68.300 99999.000 99999.000 506.512 0.736 23.693 7.301 638.028 0.071 0.133 0.249 6.378 3.233 2.990 0.391 23.769 21.967 243.913 29.771 104.890 99999.000 66437.0 0.424 1.123 77.668 226.008 68.221 99999.000 99999.000 503.588 0.748 23.477 7.347 648.553 0.112 0.138 0.268 6.221 3.269 3.244 0.362 23.212 22.119 243.065 29.641 105.080 99999.000 66791.0 0.424 1.117 77.637 226.591 68.236 99999.000 99999.000 505.118 0.719 23.701 7.229 637.233 0.071 0.140 0.251 6.201 3.229 3.140 0.352 23.297 21.800 244.289 29.635 104.991 99999.000 67144.0 0.436 1.143 77.919 226.344 67.995 99999.000 99999.000 507.581 0.734 23.637 7.346 635.723 0.101 0.130 0.253 6.249 3.209 3.201 0.379 23.241 21.705 245.452 29.620 105.104 99999.000 67497.0 0.430 1.138 77.988 227.184 67.853 99999.000 99999.000 506.837 0.750 23.858 7.213 631.055 0.081 0.111 0.256 6.102 3.243 3.177 0.392 23.646 21.687 244.373 29.557 104.920 99999.000 68202.0 0.447 1.128 77.958 226.076 99999.000 99999.000 99999.000 506.586 0.744 23.681 7.207 634.868 0.095 0.110 0.259 6.247 3.267 3.145 0.388 23.167 22.054 245.277 29.533 105.430 99999.000 68555.0 0.426 1.191 78.744 225.923 67.566 99999.000 99999.000 502.241 0.770 23.203 7.195 636.031 0.111 0.143 0.267 5.916 3.222 3.154 0.377 23.051 24.869 242.438 30.079 105.548 99999.000 68908.0 0.435 1.165 77.564 225.766 67.325 99999.000 99999.000 504.155 0.706 24.504 7.322 618.957 0.063 0.164 0.210 6.322 3.182 3.131 0.382 23.058 21.837 245.220 29.945 104.838 99999.000 69260.0 0.434 1.188 77.370 225.087 67.165 99999.000 99999.000 503.499 0.731 24.610 7.280 619.631 0.087 0.138 0.239 6.486 3.329 3.135 0.401 22.890 21.578 243.769 29.453 105.071 99999.000 69614.0 0.477 1.197 77.144 225.392 66.546 99999.000 99999.000 504.129 0.698 24.211 7.168 621.045 0.049 0.152 0.259 6.130 3.271 3.159 0.378 23.135 21.695 243.808 29.658 104.628 99999.000 69967.0 0.494 1.195 77.176 225.988 66.579 99999.000 99999.000 506.180 0.740 24.269 7.342 630.156 0.086 0.128 0.248 6.114 3.297 3.146 0.363 22.808 21.592 243.509 29.149 105.227 99999.000 70319.0 0.448 1.168 77.252 225.888 66.034 99999.000 99999.000 504.497 0.725 24.217 7.442 619.333 0.063 0.136 0.233 6.309 3.278 3.303 0.383 23.030 21.534 242.895 29.232 104.813 99999.000 71024.0 0.452 1.230 78.137 226.369 99999.000 99999.000 99999.000 505.082 0.794 27.193 7.288 604.895 0.052 0.156 0.275 6.101 3.392 3.308 0.390 22.982 21.799 241.616 29.045 104.780 99999.000 71377.0 0.457 1.237 77.458 225.765 66.649 99999.000 99999.000 508.602 0.750 28.043 7.367 627.666 0.051 0.158 0.271 6.235 3.381 3.137 0.371 23.129 21.818 242.236 28.890 104.523 99999.000 71730.0 0.670 1.163 77.372 226.458 66.224 99999.000 99999.000 506.722 0.758 35.841 7.405 603.510 0.039 0.221 0.253 6.599 3.427 3.324 0.356 23.223 22.011 246.482 29.843 106.502 99999.000 72082.0 0.700 1.212 77.294 226.860 65.503 99999.000 99999.000 507.728 0.771 37.311 7.699 606.928 0.057 0.185 0.317 6.893 3.327 3.220 0.365 23.360 21.936 248.299 29.994 107.355 99999.000 72434.0 0.715 1.179 77.338 227.070 65.465 99999.000 99999.000 508.161 0.792 39.113 7.836 618.334 0.052 0.220 0.321 7.097 3.394 3.164 0.364 23.179 22.118 249.148 30.356 107.101 99999.000 72788.0 0.662 1.122 77.409 226.710 65.524 99999.000 99999.000 506.277 0.785 36.060 7.631 607.140 0.055 0.167 0.268 6.990 3.320 3.225 0.385 23.302 22.188 249.122 30.399 107.031 99999.000 73141.0 0.656 1.233 77.304 226.125 65.089 99999.000 99999.000 508.231 0.783 36.401 7.405 604.487 0.034 0.193 0.265 6.418 3.436 3.086 0.365 23.050 22.045 247.343 29.886 107.214 99999.000 73845.0 0.708 1.174 77.052 226.588 99999.000 99999.000 99999.000 506.746 0.788 38.405 7.696 609.644 0.039 0.213 0.334 7.078 3.345 3.028 0.361 23.560 22.059 249.391 30.054 106.711 99999.000 74198.0 0.620 1.110 77.421 227.452 65.273 99999.000 99999.000 507.186 0.719 34.891 7.457 599.311 0.037 0.229 0.265 6.529 3.311 3.243 0.358 22.690 21.997 245.461 29.688 106.173 99999.000 74551.0 0.581 1.177 77.177 227.393 64.101 99999.000 99999.000 506.255 0.759 34.122 7.464 603.394 99999.000 0.181 0.271 6.417 3.368 3.238 0.357 23.006 22.034 246.552 30.129 106.464 99999.000 74904.0 0.603 1.149 76.778 227.252 63.198 99999.000 99999.000 507.904 0.740 36.069 7.623 608.651 0.040 0.229 0.257 6.529 3.308 3.274 0.352 22.484 22.158 248.302 30.363 107.648 99999.000 75256.0 0.715 1.182 76.420 227.074 62.416 99999.000 99999.000 505.752 0.802 40.797 8.129 622.202 0.033 0.242 0.341 6.918 3.284 3.126 0.346 22.732 22.217 247.881 30.513 106.541 99999.000 75608.0 0.714 1.136 76.564 227.988 62.514 99999.000 99999.000 507.454 0.793 41.312 7.869 629.565 0.044 0.206 0.340 8.502 3.328 3.273 0.359 22.675 22.206 249.508 30.389 107.528 99999.000 75960.0 0.656 1.162 76.686 226.418 61.448 99999.000 99999.000 506.322 0.763 38.174 7.721 612.853 0.062 0.231 0.302 6.256 3.308 3.435 0.352 22.330 22.123 247.059 30.273 106.562 99999.000 76661.0 0.698 1.161 76.256 226.302 99999.000 99999.000 99999.000 504.843 0.770 40.591 7.761 607.467 0.056 0.187 0.315 6.638 3.292 3.208 0.349 22.786 22.388 247.908 30.296 106.697 99999.000 77014.0 0.690 1.129 76.284 226.570 60.632 99999.000 99999.000 503.899 0.775 39.978 7.632 610.421 0.053 0.212 0.281 6.755 3.311 3.413 0.356 21.908 22.061 248.676 30.377 107.047 99999.000 77368.0 0.733 1.154 76.357 225.740 59.962 99999.000 99999.000 505.027 0.785 42.747 7.781 607.008 0.052 0.211 0.300 6.833 3.292 3.167 0.351 22.040 21.867 249.964 30.784 106.563 99999.000 77720.0 0.787 1.133 76.163 226.035 60.161 99999.000 99999.000 503.038 0.772 44.861 7.869 604.289 0.066 0.221 0.302 99999.000 3.346 3.412 0.330 22.641 22.010 248.214 30.401 108.069 99999.000 78073.0 0.786 1.128 76.485 226.163 59.246 99999.000 99999.000 506.365 0.772 45.164 7.868 610.518 0.042 0.223 0.307 7.768 3.353 3.083 0.350 22.065 22.152 252.109 30.618 107.662 99999.000 78425.0 0.779 1.192 76.707 226.260 58.990 99999.000 99999.000 505.067 0.768 43.299 7.942 608.832 0.078 0.180 0.319 99999.000 3.331 3.444 0.335 21.756 22.243 250.257 30.371 108.298 99999.000 78778.0 0.832 1.151 76.789 226.155 58.833 99999.000 99999.000 505.571 0.776 42.309 7.807 610.742 0.052 0.216 0.304 99999.000 3.349 3.313 0.339 21.956 22.094 251.413 30.620 107.450 99999.000 79480.0 0.823 1.142 76.709 226.583 99999.000 99999.000 99999.000 503.000 0.797 42.370 7.794 601.052 0.072 0.253 0.356 7.960 3.382 3.365 0.341 23.000 21.890 248.856 30.545 107.038 99999.000 79833.0 0.802 1.067 76.043 227.107 57.597 99999.000 99999.000 506.141 0.775 42.763 7.930 606.890 0.080 0.249 0.310 7.225 3.360 3.291 0.342 22.022 21.922 251.020 30.682 108.996 99999.000 80186.0 0.859 1.149 76.299 225.700 56.479 99999.000 99999.000 504.631 0.811 47.081 8.188 606.988 0.079 0.251 0.316 99999.000 3.394 3.090 0.356 21.732 21.950 251.004 30.583 108.536 99999.000 80538.0 0.876 1.100 76.618 226.097 56.599 99999.000 99999.000 507.404 0.781 44.339 7.758 614.163 0.082 0.245 0.342 7.918 3.378 3.252 0.342 21.689 22.034 251.335 30.127 107.970 99999.000 80890.0 0.832 1.125 76.665 227.071 56.461 99999.000 99999.000 506.244 0.755 41.491 7.930 613.668 0.126 0.230 0.376 8.018 3.327 3.114 0.339 21.324 21.985 248.693 30.164 107.598 99999.000 81242.0 0.859 1.173 76.242 227.254 56.418 99999.000 99999.000 505.614 0.798 42.723 7.943 613.749 0.103 0.257 0.329 6.250 3.268 3.426 0.327 21.595 22.226 250.553 30.168 107.735 99999.000 81594.0 0.781 1.083 76.674 226.619 55.499 99999.000 99999.000 505.750 0.764 39.132 7.792 607.057 0.137 0.262 0.390 6.462 3.232 3.211 0.323 21.204 21.965 250.259 30.603 107.181 99999.000 83349.0 2.250 1.263 78.120 226.280 99999.000 99999.000 99999.000 505.595 0.758 39.395 8.828 648.625 0.261 1.649 0.685 14.159 3.445 3.178 0.384 25.175 22.237 248.851 30.756 108.571 99999.000 83702.0 0.896 1.183 79.519 227.817 71.188 99999.000 99999.000 507.963 0.761 40.919 7.919 596.898 0.144 0.333 0.385 8.069 3.428 3.367 0.387 25.241 22.320 251.316 31.034 108.499 99999.000 84055.0 0.898 1.186 79.869 228.134 71.257 99999.000 99999.000 506.533 0.765 42.195 7.912 601.197 0.121 0.322 0.352 8.212 3.405 3.379 0.395 25.072 22.372 251.042 30.896 108.659 99999.000 84408.0 0.891 1.121 79.039 226.740 71.074 99999.000 99999.000 504.976 0.724 41.347 8.063 591.292 0.096 0.316 0.332 8.150 3.376 3.344 0.388 24.999 22.234 250.476 30.803 109.518 99999.000 85112.0 0.892 1.157 78.762 226.767 99999.000 99999.000 99999.000 502.659 0.668 40.064 7.806 576.354 0.087 0.288 0.353 8.093 3.333 3.503 0.363 24.572 22.479 252.042 31.260 110.327 99999.000 85465.0 0.834 1.199 78.673 225.473 70.478 99999.000 99999.000 504.400 0.759 37.265 7.672 561.779 0.151 0.277 0.463 7.814 3.364 3.426 0.359 24.688 22.216 251.117 30.939 109.396 99999.000 85819.0 0.828 1.170 78.502 224.676 70.651 99999.000 99999.000 498.972 0.792 36.197 7.336 554.571 0.202 0.376 0.547 8.184 3.324 3.238 0.370 24.788 22.099 249.421 31.018 107.519 99999.000 86172.0 0.909 1.166 78.145 223.207 69.809 99999.000 99999.000 499.747 0.707 38.433 7.228 545.054 0.138 0.536 0.408 8.954 3.393 3.313 0.355 24.551 22.222 249.196 31.294 109.613 99999.000 86526.0 1.238 1.150 78.318 223.502 69.567 99999.000 99999.000 501.875 0.715 43.589 7.000 517.942 0.145 0.445 0.449 9.808 3.215 3.441 0.371 25.410 22.639 251.148 31.571 111.031 99999.000 86880.0 0.918 1.156 78.952 225.883 69.045 99999.000 99999.000 501.838 0.685 38.896 7.175 527.026 0.174 0.345 0.447 9.073 3.285 3.295 0.343 24.357 22.280 250.341 31.183 111.509 99999.000 87234.0 1.079 1.136 77.958 225.109 68.097 99999.000 99999.000 500.722 0.721 41.555 6.732 505.721 0.117 0.314 0.525 9.053 3.222 3.321 0.358 24.759 22.171 250.859 31.874 111.911 99999.000