72 1001 Markus Jesswein, Thomas Wagenhaeuser, Timo Keber, Tanja Schuck, Andreas Engel Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Altenhoeferallee 1, 60438 Frankfurt/Main, Germany 1 | HALO | GhOST-MS | mixing ratios of long-lived and very short-lived tracers measured with an in-situ GC-MS instrument SOUTHTRAC 1 1 2019 09 30 2020 08 24 0 Mean sample time in UT seconds past midnight of flight date 25 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 C2Cl4 [ppt] C2H3Cl3 [ppt] CCl4 [ppt] CFC11 [ppt] CFC113 [ppt] CFC114 [ppt] CFC115 [ppt] CFC12 [ppt] CH2Br2 [ppt] CH2Cl2 [ppt] CH3Br [ppt] CH3Cl [ppt] CH3I [ppt] CHBr2Cl [ppt] CHBr3 [ppt] CHCl3 [ppt] H1211 [ppt] H1301 [ppt] H2402 [ppt] HCFC141b [ppt] HCFC142b [ppt] HCFC22 [ppt] HFC125 [ppt] HFC134a [s] HFC143a [s] 31 ------------------------------------------------------------------------ Please inform the authors about the use of the data Before publication, the authors of the data have to give their consent Please adhere in all cases to the SOUTHTRAC data protocol Contact: Andreas Engel (an.engel@iau.uni-frankfurt.de, phone +49 69 798 40259) ------------------------------------------------------------------------ Calibration Scale, Precision, Accuracy and Detection Limit are given separately for each dependent variable Primary calibration reference flasks: AGAGE H-218 (all other scales) Calibration Scales NOAA-2003B SIO-05 SIO-05 SIO-05 SIO-05 SIO-05 SIO-05 SIO-05 NOAA-2003 SIO-14 SIO-05 SIO-05 NOAA-2004 UEA-11 NOAA-2003 SIO-05 SIO-05 SIO-05 SIO-14 SIO-05 SIO-05 SIO-05 SIO-14 SIO-05 SIO-07 ------------------------------------------------------------------------ Instrument precision in [%] 0.0131 0.0867 0.0044 0.0022 0.0064 0.0073 0.0140 0.0030 0.0259 0.0078 0.0169 0.0039 0.0675 0.0891 0.0282 0.0095 0.0278 0.0383 0.0579 0.0082 0.0084 0.0041 0.0079 0.0049 0.0167 Instrument precision in [ppt] 0.0800 0.1527 0.3524 0.5192 0.4049 0.1199 0.1238 1.5384 0.0330 0.5550 0.1154 2.7873 0.0186 0.0677 0.0492 0.1397 0.0929 0.1349 0.0226 0.2095 0.1932 1.0807 0.3451 1.7285 0.43155 Use whatever precision is larger for each data point ------------------------------------------------------------------------ Accuracy of mixing ratios in calibration gas in [%] NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN NaN ------------------------------------------------------------------------ Detection limit (S/N 3/1) in [ppt] per 400 mL air at STP 0.11162 0.53190 0.19529 0.35685 0.18416 0.11912 0.32568 0.47153 0.11040 0.45926 0.30992 3.50523 0.07732 0.74990 0.24115 0.65568 0.25124 0.93355 0.08583 0.39324 0.4981 1.30346 0.625 0.76391 1.86463 Values below detection limit are marked as 0.00 In case no measurements are available, the missing data value is used ------------------------------------------------------------------------ Sample integration time: 147 +- 1 seconds Values of t_sample are the mean of the sampling time interval (integration time) ------------------------------------------------------------------------ Correction of analyte carry-over (memory effect): below measurement precision for all substances, no correction applied Detector non-linearity: below measurement precision for all substances, no correction applied ------------------------------------------------------------------------ 2 TIME C2Cl4 C2H3Cl3 CCl4 CFC11 CFC113 CFC114 CFC115 CFC12 CH2Br2 CH2Cl2 CH3Br CH3Cl CH3I CHBr2Cl CHBr3 CHCl3 H1211 H1301 H2402 HCFC141b HCFC142b HCFC22 HFC125 HFC134a HFC143a [s] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [s] [s] 57675.0 0.668 1.426 75.615 223.912 99999.000 99999.000 99999.000 501.091 1.016 22.227 8.151 590.902 0.370 0.562 1.352 9.853 3.557 3.439 0.000 22.855 21.601 234.052 28.182 101.607 99999.000 58029.0 0.481 1.152 76.978 223.711 64.332 99999.000 99999.000 503.316 0.970 20.978 6.345 550.827 0.206 0.296 0.697 6.356 3.395 3.015 0.000 23.514 21.820 236.482 28.704 101.214 99999.000 58383.0 0.459 1.099 77.413 225.703 66.146 99999.000 99999.000 504.496 0.860 21.371 6.865 564.291 0.118 0.207 0.496 6.201 3.334 3.234 0.000 23.606 21.998 237.923 28.478 101.665 99999.000 58736.0 0.469 1.114 77.528 227.715 67.621 99999.000 99999.000 505.526 0.866 22.002 6.762 558.017 0.062 0.174 0.330 5.940 3.395 3.088 0.000 22.956 22.069 242.904 28.564 102.224 99999.000 59090.0 0.493 1.130 76.961 226.717 68.719 99999.000 99999.000 502.963 0.838 21.686 6.760 564.307 0.070 0.146 0.301 5.644 3.415 3.133 0.000 23.664 21.994 240.573 29.080 102.477 99999.000 59797.0 0.387 1.144 75.905 222.700 99999.000 99999.000 99999.000 497.771 0.774 21.551 6.838 564.379 99999.000 0.140 0.313 5.587 3.299 3.013 0.000 23.525 21.778 239.709 28.500 101.325 99999.000 60151.0 0.352 1.160 75.423 218.525 68.638 99999.000 99999.000 500.198 0.736 21.680 6.827 560.122 0.066 0.136 0.288 5.712 3.477 2.953 0.000 23.372 21.794 238.603 28.027 99.945 99999.000 60505.0 0.275 1.115 75.185 219.479 68.882 99999.000 99999.000 498.850 0.716 22.070 7.056 557.583 0.090 0.129 0.264 5.115 3.273 3.119 0.000 23.290 22.110 240.855 27.567 99.528 99999.000 60860.0 0.318 1.138 75.982 221.725 69.014 99999.000 99999.000 499.934 0.725 21.714 6.973 555.164 0.070 0.132 0.279 6.070 3.147 3.001 0.000 23.372 22.032 241.061 28.478 101.623 99999.000 61213.0 0.236 1.120 73.844 217.340 68.606 99999.000 99999.000 497.536 0.647 21.518 6.979 544.722 0.061 0.088 0.206 4.724 3.052 3.081 0.000 23.090 22.154 239.531 27.360 99.425 99999.000 61567.0 0.111 1.130 71.707 212.082 67.881 99999.000 99999.000 491.238 0.552 20.952 7.043 527.939 99999.000 99999.000 0.123 4.517 2.986 3.012 0.000 22.706 22.018 236.648 26.067 96.798 99999.000 61920.0 0.112 1.134 71.351 208.433 67.525 99999.000 99999.000 487.856 0.536 21.457 6.997 530.653 99999.000 0.066 0.096 4.246 3.016 3.205 0.000 22.641 21.752 234.455 26.438 96.912 99999.000 62629.0 0.075 1.266 68.112 201.365 99999.000 99999.000 99999.000 475.282 0.483 19.832 6.579 504.039 99999.000 99999.000 0.078 3.778 2.891 2.977 0.000 21.867 21.246 231.279 25.838 94.006 99999.000 62983.0 0.094 1.188 70.584 208.392 67.050 99999.000 99999.000 488.280 0.512 21.153 6.784 518.394 0.061 0.087 0.080 4.105 3.023 3.075 0.000 22.376 21.488 233.819 25.840 96.131 99999.000 63338.0 99999.000 1.147 67.589 183.665 61.224 99999.000 99999.000 470.896 0.473 19.408 5.981 485.522 0.030 0.079 0.073 3.740 2.849 2.929 0.000 21.558 21.052 229.344 25.324 94.683 99999.000 63691.0 0.027 1.054 48.536 178.094 58.686 99999.000 99999.000 442.979 0.269 17.073 5.722 450.602 99999.000 99999.000 99999.000 3.299 99999.000 2.794 0.000 20.355 21.019 224.543 29.891 92.300 99999.000 64045.0 0.062 1.022 52.940 170.933 59.605 99999.000 99999.000 435.789 0.286 16.429 5.349 438.764 0.073 99999.000 0.026 3.303 2.794 2.651 0.000 19.924 20.752 221.353 24.121 89.717 99999.000 64398.0 0.068 0.920 49.551 158.220 56.866 99999.000 99999.000 416.904 0.275 15.307 4.825 411.295 0.071 99999.000 99999.000 2.779 2.273 2.655 0.000 18.470 20.443 215.982 23.104 86.298 99999.000 64752.0 99999.000 0.866 45.211 143.060 54.437 99999.000 99999.000 397.393 0.225 13.692 4.563 391.345 0.056 99999.000 0.020 2.315 2.062 2.373 0.000 17.746 20.034 210.692 22.211 84.039 99999.000 65459.0 0.044 0.766 34.749 115.255 99999.000 99999.000 99999.000 358.385 0.161 10.188 3.483 328.029 0.064 99999.000 99999.000 1.366 1.705 1.919 0.000 15.656 19.099 200.459 20.370 77.964 99999.000 65813.0 0.045 0.869 43.819 138.418 53.115 99999.000 99999.000 390.731 0.230 12.480 4.163 368.773 0.081 99999.000 0.019 2.246 1.914 2.235 0.000 17.755 19.776 207.185 22.005 82.256 99999.000 66167.0 0.035 0.904 49.227 151.917 55.994 99999.000 99999.000 411.400 0.276 14.310 4.653 402.960 0.057 99999.000 99999.000 2.547 2.081 2.194 0.000 18.211 20.270 210.395 22.416 84.551 99999.000 66520.0 0.035 0.916 52.666 160.976 57.817 99999.000 99999.000 421.700 0.311 15.627 5.040 420.993 0.081 99999.000 0.026 2.796 2.310 2.549 0.000 18.955 20.303 215.066 22.892 85.775 99999.000 66874.0 99999.000 0.825 43.666 137.266 52.510 99999.000 99999.000 389.376 0.224 12.478 3.995 368.272 0.062 99999.000 0.013 2.049 1.798 2.277 0.000 17.075 19.554 206.360 21.151 80.727 99999.000 67227.0 99999.000 0.714 36.810 120.284 48.943 99999.000 99999.000 366.085 0.157 10.744 3.413 333.319 0.058 99999.000 99999.000 1.623 1.508 2.163 0.000 15.749 19.068 199.243 20.187 77.558 99999.000 67581.0 99999.000 0.715 37.033 120.840 48.886 99999.000 99999.000 367.548 0.174 10.659 3.483 336.314 0.055 99999.000 99999.000 1.779 1.672 2.116 0.000 15.762 19.096 199.299 20.350 77.799 99999.000 68287.0 99999.000 0.665 33.961 112.433 99999.000 99999.000 99999.000 355.512 0.157 9.449 3.281 322.963 99999.000 99999.000 0.024 1.276 1.622 1.713 0.000 15.351 18.898 198.352 20.371 76.771 99999.000 68641.0 99999.000 0.664 32.292 107.683 46.332 99999.000 99999.000 350.308 0.109 9.698 3.049 311.649 0.075 99999.000 99999.000 1.329 1.446 1.915 0.000 14.897 18.849 196.124 19.836 75.310 99999.000 68994.0 99999.000 0.568 30.644 104.513 45.334 99999.000 99999.000 344.259 0.131 8.844 3.032 307.010 0.071 99999.000 99999.000 1.813 1.340 1.782 0.000 14.683 18.660 195.121 19.527 76.441 99999.000 69348.0 99999.000 0.588 29.573 100.782 44.671 99999.000 99999.000 340.148 0.108 8.722 2.817 292.866 0.055 0.034 99999.000 1.286 1.321 1.744 0.000 14.123 18.543 192.806 19.064 74.849 99999.000 69701.0 99999.000 0.585 27.192 94.835 43.412 99999.000 99999.000 329.994 0.106 8.190 2.655 285.233 0.088 99999.000 99999.000 1.256 1.332 1.680 0.000 13.344 18.322 189.721 19.108 73.553 99999.000 70054.0 99999.000 0.540 23.766 84.968 41.204 99999.000 99999.000 316.772 0.089 7.380 2.429 263.602 0.081 99999.000 99999.000 0.997 1.163 1.653 0.000 13.099 17.843 186.206 18.573 72.321 99999.000 70407.0 99999.000 0.542 24.331 86.604 41.343 99999.000 99999.000 319.264 0.090 7.369 2.459 269.417 0.077 99999.000 99999.000 1.010 0.999 1.509 0.000 13.148 17.774 187.447 18.494 72.362 99999.000 71115.0 0.069 0.916 50.062 155.895 99999.000 99999.000 99999.000 415.477 0.288 15.350 4.911 413.125 0.064 99999.000 0.028 2.316 2.121 2.376 0.000 18.704 20.123 213.838 23.030 85.877 99999.000 71470.0 0.076 1.049 60.081 181.206 62.258 99999.000 99999.000 453.844 0.364 19.146 5.863 474.301 0.088 99999.000 0.022 3.731 2.558 2.828 0.000 20.567 20.966 224.316 24.905 91.629 99999.000 71822.0 0.053 1.051 60.400 183.598 62.380 99999.000 99999.000 453.802 0.381 19.931 5.884 476.618 0.075 99999.000 0.020 3.602 2.563 2.728 0.000 20.956 21.099 226.372 25.256 91.812 99999.000 72176.0 0.075 1.005 61.118 183.750 62.262 99999.000 99999.000 454.547 0.404 20.040 5.882 477.569 0.065 99999.000 0.024 3.406 2.564 2.710 0.000 20.591 20.933 225.849 25.371 92.323 99999.000 72530.0 0.060 1.007 60.500 182.832 61.858 99999.000 99999.000 450.127 0.386 20.471 5.822 478.621 0.086 99999.000 0.034 3.451 2.477 3.033 0.000 20.669 21.164 226.347 25.628 92.533 99999.000 72884.0 99999.000 0.779 44.552 141.004 53.681 99999.000 99999.000 396.535 0.229 13.801 4.330 380.009 0.082 0.028 99999.000 2.242 1.824 2.369 0.000 17.717 19.933 210.549 22.175 84.143 99999.000 73237.0 0.067 0.949 57.820 176.743 60.587 99999.000 99999.000 441.378 0.353 19.888 5.556 461.049 0.070 99999.000 99999.000 3.247 2.433 2.849 0.000 20.312 20.813 223.022 24.758 90.557 99999.000 73944.0 0.078 0.966 53.534 165.197 99999.000 99999.000 99999.000 427.438 0.315 17.135 5.213 438.214 0.050 99999.000 0.033 2.794 2.340 2.774 0.000 19.504 20.807 218.356 23.990 88.109 99999.000 74298.0 0.067 0.999 62.666 187.660 63.027 99999.000 99999.000 459.369 0.369 21.002 6.051 490.432 0.070 99999.000 0.017 3.558 2.570 2.830 0.000 21.228 21.214 227.703 25.613 94.088 99999.000 74650.0 99999.000 0.815 49.315 152.861 55.813 99999.000 99999.000 411.327 0.260 15.304 4.843 411.265 0.081 0.029 99999.000 2.614 2.000 2.651 0.000 18.301 20.356 213.374 23.135 85.519 99999.000 75003.0 99999.000 0.836 52.119 160.900 57.278 99999.000 99999.000 422.180 0.304 15.770 5.118 426.509 0.069 99999.000 99999.000 2.732 2.095 2.542 0.000 19.207 20.332 216.942 23.844 87.276 99999.000 75356.0 99999.000 0.677 39.601 126.372 50.212 99999.000 99999.000 375.767 0.168 11.709 3.976 353.796 0.081 99999.000 99999.000 2.020 1.644 2.137 0.000 16.514 19.417 203.094 21.127 80.074 99999.000 75710.0 99999.000 0.577 26.909 94.220 42.967 99999.000 99999.000 329.149 0.105 7.778 2.874 288.289 0.063 99999.000 99999.000 1.313 1.145 1.720 0.000 13.584 18.050 191.182 19.103 73.790 99999.000 76063.0 99999.000 0.526 25.475 89.577 42.152 99999.000 99999.000 323.285 0.069 7.088 2.711 279.038 0.064 99999.000 99999.000 1.008 1.070 1.694 0.000 13.477 17.871 189.133 18.661 73.068 99999.000 76769.0 99999.000 0.599 20.210 75.156 99999.000 99999.000 99999.000 302.076 0.036 6.120 2.388 251.668 99999.000 99999.000 0.022 0.810 1.272 1.345 0.000 12.304 17.604 183.494 17.974 70.621 99999.000 77122.0 0.061 0.943 59.335 178.750 60.262 99999.000 99999.000 444.954 0.353 18.062 5.565 458.364 0.093 99999.000 0.031 3.251 2.413 2.825 0.000 20.727 20.687 225.343 24.439 91.051 99999.000 77476.0 0.240 1.106 73.244 213.812 67.681 99999.000 99999.000 491.490 0.676 21.587 7.164 545.092 0.087 0.122 0.198 5.257 3.101 3.035 0.000 23.067 21.670 236.086 27.232 96.943 99999.000 77829.0 0.468 1.133 77.072 221.738 69.311 99999.000 99999.000 503.071 0.958 20.443 6.482 553.044 0.181 0.219 0.669 7.181 3.290 3.141 0.000 23.445 21.787 240.141 28.133 98.450 99999.000 78182.0 0.481 1.192 77.941 223.966 70.074 99999.000 99999.000 504.213 0.998 20.746 6.514 550.779 0.132 0.226 0.720 6.476 3.334 3.138 0.000 24.026 21.807 240.883 28.548 100.803 99999.000 78536.0 0.465 1.220 78.587 226.481 69.807 99999.000 99999.000 505.234 1.047 19.547 6.112 543.328 0.168 0.347 1.248 7.663 3.363 3.108 0.000 23.841 21.804 240.202 28.635 101.107 99999.000 78891.0 0.478 1.233 77.776 225.373 69.554 99999.000 99999.000 505.584 0.969 19.704 6.104 537.653 0.164 0.308 1.101 6.969 3.300 3.203 0.000 23.482 21.599 240.833 29.178 101.165 99999.000